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131 Sentences With "oxidise"

How to use oxidise in a sentence? Find typical usage patterns (collocations)/phrases/context for "oxidise" and check conjugation/comparative form for "oxidise". Mastering all the usages of "oxidise" from sentence examples published by news publications.

"They oxidise badly or they end up looking grey," Anabelle agreed.
These substances oxidise and destroy organic compounds, turning them into small molecules such as carbon dioxide and water.
More of them are forced to harvest at night, to ensure the heat of summer days does not cause grapes to oxidise.
Most tellingly, Mr Larsen's samples contained iron and nickel alloys common in micrometeorites, but rare in Earth-bound rocks because these metals oxidise rapidly.
Cold-pressed juice doesn't oxidise nearly as quickly and has a shelf life of up to three days, which makes much more sense for a serious juice drinker who would like to do some meal prepping.
The allowable threshold for powder contaminants has been set at a draconian 2300 percent of total weight, even though ISRI has pointed out that certain types of copper oxidise into cupric oxide powders that are still copper and satisfy ISRI specifications.
PCC, when used in an organic solvent, can be used to oxidise a secondary alcohol into a ketone. It has the advantage of doing so selectively without the tendency to over-oxidise.
The wine-must has tendency to oxidise quickly, a characteristic that can be ignored when used for sherry production.
Aluminium conductors must be installed with compatible connectors and special care must be taken to ensure the contact surface does not oxidise.
It is also used in molecular biology as an oxidising agent, for example to oxidise free thiols to form disulfide bonds in proteins.
Herminiimonas arsenicoxydans is a species of ultramicrobacteria. First reported in 2006, it was isolated from industrial sludge and is able to oxidise the toxic chemical element arsenic.
If this occurs, the oil will oxidise and has to be replaced, if a fire occurs the smoke and residue may contaminate other parts of the system.
Dioxygenyl hexafluoroplatinate is a compound with formula O2PtF6. It is a hexafluoroplatinate of the unusual dioxygenyl cation, O2+, and is the first known compound containing this cation. It can be produced by the reaction of dioxygen with platinum hexafluoride. The fact that is strong enough to oxidise , whose first ionization potential is 12.2 eV, led Neil Bartlett to correctly surmise that it might be able to oxidise xenon (first ionization potential 12.13 eV).
These actions inactivate the virus. Hydroxyl radicals also pass through the outer cell wall structures of bacteria and oxidise the membrane responsible for electron transport, making the organism non-viable.
W, Nb), are liquids at or near room temperature (e.g. Hg, Ga), are brittle (e.g. Os, Bi), not easily machined (e.g. Ti, Re), or are noble (hard to oxidise, e.g.
Cytochrome c oxidase is an enzyme embedded in the inner membrane of mitochondria. Its main function is to oxidise the Cytochrome c protein. Cytochrome c oxidase contains several metal active sites.
They can both oxidise arabinose, but only S. liquefaciens can ferment arabinose in peptone water. The virulence of Serratia strains can also be identifiable by type 4 fimbriae, small hair-like projections.
Trifluoroperacetic acid (trifluoroperoxyacetic acid, TFPAA) is an organofluorine compound, the peroxy acid analog of trifluoroacetic acid, with the condensed structural formula . It is a strong oxidizing agent for organic oxidation reactions, such as in Baeyer–Villiger oxidations of ketones. It is the most reactive of the organic peroxy acids, allowing it to successfully oxidise relatively unreactive alkenes to epoxides where other peroxy acids are ineffective. It can also oxidise the chalcogens in some functional groups, such as by transforming selenoethers to selones.
If aerated, e.g. by energetic dilution, its lactic acid content will oxidise to pyruvate, rendering it less dangerous to plants. Other uses are either potentially damaging (e.g. feeding plants with acidic water) or wasteful (e.g.
Starkeya novella is a chemolithoautotrophic and methylotrophic bacteria from the family of Xanthobacteraceae which has been isolated from soil. Starkeya novella has the ability to oxidise thiosulfate. The complete genome of Starkeya novella is sequenced.
Thiomonas islandica is a Gram-negative, rod-shaped, motile bacterium from the genus Thiomonas, which has the ability to oxidise sulfur compounds and hydrogen. It was isolated from a hot spring in Graendalur in southwestern Iceland.
It also has such a strong tendency to oxidise that its powders are pyrophoric. These characteristics make thorium unsuitable in ion-deposition experiments. See also Isotopes of bismuth, Isotopes of gold and Isotopes of thorium. See also Table of nuclides.
Krypton difluoride is primarily a powerful oxidising and fluorinating agent: for example, it can oxidise gold to its highest-known oxidation state, +5. It is more powerful even than elemental fluorine due to the even lower bond energy of Kr–F compared to F–F, with a redox potential of +3.5 V for the KrF2/Kr couple, making it the most powerful known oxidising agent, though could be even stronger: : 7 (g) + 2 Au (s) → 2 KrFAuF (s) + 5 Kr (g) KrFAuF decomposes at 60 °C into gold(V) fluoride and krypton and fluorine gases: : KrFAuF → (s) + Kr (g) + (g) can also directly oxidise xenon to xenon hexafluoride: : 3 + Xe -> \+ 3 Kr is used to synthesize the highly reactive BrF cation. reacts with to form the salt KrFSbF; the KrF cation is capable of oxidising both and to BrF and ClF, respectively. is able to oxidise silver to its +3 oxidation state, reacting with elemental silver or with to produce .
The ruff stores fat as a fuel, but unlike mammals, uses lipids as the main energy source for exercise (including migration) and, when necessary, keeps warm by shivering; however, little research has been conducted on the mechanisms by which they oxidise lipids.
PAOs in plants, bacteria and protozoa oxidise spermidine and spermine to an aminobutyral, diaminopropane and hydrogen peroxide and are involved in the catabolism of polyamines. Other members of this family include tryptophan 2-monooxygenase, putrescine oxidase, corticosteroid-binding proteins, and antibacterial glycoproteins.
Periodates are powerful oxidising agents. They can oxidise catechol to 1,2-benzoquinone and hydroquinone to 1,4-benzoquinone. Sulfides can be effectively oxidised to sulfoxides. Periodates are sufficiently powerful to generate other strong inorganic oxidisers such as permanganate, osmium tetroxide and ruthenium tetroxide.
Pedomicrobium is a ubiquitous bacterium dominant in biofilms of man-made aquatic environments such as water distribution systems and bioreactors. Due to their abilities to oxidise manganese (Mn), they are found to be the main culprits of Mn related “dirty water” (Sly et al., 1988a).
In 2011 a new, more effective synthesis was discovered: perbromate ions were formed through the reaction of hypobromite and bromate ions in an alkaline sodium hypobromite solution. Diperiodatonickelate anions in alkaline solution can oxidise bromate to perbromate. This is a relatively lower cost and fluorine free synthesis.
Strong oxidants oxidise them to sulfates and strong reducing agents reduce them to sulfites and dithionites. Aqueous solutions of dithionates are quite stable and can be boiled without decomposition. The γ-irradiation of crystalline dithionates produces radical ions.Radiation Chemistry of Dithionates G.S. Murthy, R.L. Eager, and K.J. McCallum Can.
When the back washing process is complete the filter is bought back into service. Ozone gas is then added to the water to oxidise contaminants such as pesticides and organic material. The process of ozonization also kills bacteria. Water then flows to the next stage Slow Sand Filtration.
The word 'Chromaffin' comes from a portmanteau of chromium and affinity. They are named as such because they can be visualised by staining with chromium salts. Chromium salts oxidise and polymerise catecholamines to form a brown color, most strongly in the cells secreting noradrenaline. Chromaffin cells are also called pheochromocytes.
TlI can be formed in aqueous solution by metathesis of any soluble thallium salt with iodide ion. It is also formed as a by-product in thallium-promoted iodination of phenols with thallium(I) acetate. Attempts to oxidise TlI to thallium(III) iodide fail, since oxidation produces the thallium(I) triiodide, .
The grapevine fungal pathogen Botrytis cinerea is able to oxidise resveratrol into metabolites showing attenuated antifungal activities. Those include the resveratrol dimers restrytisol A, B, and C, resveratrol trans-dehydrodimer, leachinol F, and pallidol. The soil bacterium Bacillus cereus can be used to transform resveratrol into piceid (resveratrol 3-O-beta-D-glucoside).
Growth can only occur on reduced inorganic sulfur compounds (thiosulfate, polythionates from trithionate to octathionate pace pentathionate, sulfide) and elementary sulfur, but unlike some species in other genus of the same family, Acidithiobacillus, Thermithiobacillus spp. are unable to oxidise ferrous iron or iron-containing minerals. The genome sequence was completed in 2016.
Also oxidation of sulfacetamide by diperiodatocuperate(lll) in an aqueous alkaline medium can occur. Copper(lll) is used, as it is involved in many biological electron transfer reactions. The sulphanilamide can oxidise to a blue product with a first order reaction and it can form azo dye with a second order reaction.
Lanthanide hypochlorites are also unstable; however, they have been reported as being more stable in their anhydrous forms than in the presence of water. Hypochlorite has been used to oxidise cerium from its +3 to +4 oxidation state. Hypochlorous acid itself is not stable in isolation as it decomposes to form chlorine.
They do not contain activated charcoal or similar adsorbent materials, as most respirators do. A drawback to these respirators is that they rely on atmospheric oxygen in order for the catalyst to oxidise the carbon monoxide. This makes them unusable after some types of accident, and so the oxygen-source rescuer is used instead.
The Sharpless epoxidation has been used for the total synthesis of various saccharides, terpenes, leukotrienes, pheromones, and antibiotics. The main drawback of this protocol is the necessity of the presence of an allylic alcohol. The Jacobsen epoxidation, an alternative method to enantioselectively oxidise alkenes, overcomes this issue and tolerates a wider array of functional groups.
The sap relies on wild yeast to turn the sugars into ethanol. This turns the sap into a traditional palm toddy called tubâ. Leaving it to ferment further, however, allows Acetobacter from the air to oxidise the ethanol to acetic acid. It is harvested once the level of acidity reaches four or five percent.
Once the root run has been completed, it is possible to stop the purging process unless the welding engineer has specified that purging should be continued for the second and third passes for example in case the root weld becomes hot enough to oxidise in the air that will have replaced the purge gas.
Copper(I) fluoride or cuprous fluoride is an inorganic compound with the chemical formula CuF. Its existence is uncertain. It was reported in 1933 to have a sphalerite-type crystal structure. Modern textbooks state that CuF is not known, since fluorine is so electronegative that it will always oxidise copper to its +2 oxidation state.
Many hypophosphate salts are known, for example, K4P2O6·8H2O, Ca2P2O6·2H2O, K3HP2O6·3H2O, K2H2P2O6·2H2O, KH3P2O6. On standing in air, hypophosphates tend to oxidise to pyrophosphates containing the ion where P has a formal oxidation state of +5. Hypophosphates are stable to alkali hydroxides. In fused sodium hydroxide they convert rapidly to the orthophosphate containing .
Oxidative sewage treatment processes rely on microorganisms to oxidise organic constituents. Anaerobic microorganisms reduce sludge solids producing methane gas and a sterile mineralised residue. In potable water treatment, one method, the slow sand filter, employs a complex gelatinous layer composed of a wide range of microorganisms to remove both dissolved and particulate material from raw water.
These reoxidants do not react with the alkenes on their own. Other osmium compounds can be used as catalysts, including osmate(VI) salts ([OsO2(OH)4)]2−, and osmium trichloride hydrate (OsCl3·xH2O). These species oxidise to osmium(VIII) in the presence of such oxidants. Lewis bases such as tertiary amines and pyridines increase the rate of dihydroxylation.
Readily soluble in water, SnF2 is hydrolysed. At low concentration, it forms species such as SnOH+, Sn(OH)2 and Sn(OH)3−. At higher concentrations, predominantly polynuclear species are formed, including Sn2(OH)22+ and Sn3(OH)42+. Aqueous solutions readily oxidise to form insoluble precipitates of SnIV, which are ineffective as a dental prophylactic.
Wastewater treatment plants rely largely on microorganisms to oxidise organic matter. These depend for their ability to clean up water contaminated with organic material on microorganisms that can respire dissolved substances. Respiration may be aerobic, with a well-oxygenated filter bed such as a slow sand filter. Anaerobic digestion by methanogens generate useful methane gas as a by-product.
Regeneration-metal was melted into the crucible to replace lost tin and antimony through the dross. Every time type metal is remelted, tin and antimony oxidise. These oxides form on the surface of the crucible and must be removed. After stirring the molten metal, grey powder forms on the surface, the dross, needing to be skimmed.
"Purging the System." LNG Industry Autumn (2012). Print. Purge gases must be of a certain quality, in order that the welds are made correctly. Because welds in Argon or Helium which have more than 0.05% (500 ppm) of oxygen will oxidise and discolour, welding engineers will include the mention of the correct gas quality in their welding procedures.
Acedtic acid adds complexity but it can spoil the wine if allowed to become too high. Extreme care also has to be taken to ensure the wine does not oxidise. Once fermentation is completed the wines are clarified, stabilized, and then aged in new French oak barriques for an average of 12 months before blending and bottling.
Water gas is a mixture of carbon monoxide and hydrogen produced from synthesis gas. Synthesis gas is a useful product, but requires careful handling due to its flammability and the risk of carbon monoxide poisoning. The water-gas shift reaction can be used to oxidise the carbon monoxide while producing additional hydrogen, resulting in water gas.
Without copper(II) chloride as an oxidizing agent, Pd(0) metal (resulting from beta-hydride elimination of Pd(II) in the final step) would precipitate, stopping the reaction after one cycle. This stoichiometric reaction was discovered in 1894. Air, pure oxygen, or a number of other reagents can then oxidise the resultant CuCl-chloride mixture back to CuCl2, allowing the cycle to continue.
It is filtered, washed, dried and weighed. This chemical test works equally well for the determination of sulfur but without addition of silver nitrate. The sulfuric acid intermediate formed after reaction of sulfur with fuming nitric acid forms insoluble barium sulfate on addition of barium chloride. The purpose of adding the nitric acid is to oxidise the carbon and hydrogen.
Bathymodiolus thermophilus has chemosymbiotic bacteria in its gills which oxidise hydrogen sulfide. The mussel absorbs nutrients synthesized by these bacteria and is not reliant on photosynthetically produced organic matter. However it also feeds by extracting suspended food particles from the surrounding water through its gills. Mostly these are the bacteria that live around the vent, often forming a dense mat.
HClO may oxidise cysteines and methionines via their sulfhydryl groups and sulfur groups respectively. The former leads to the formation of disulfide bonds, inducing protein crosslinking. Both oxidations result in protein aggregation, and ultimately, cell death. Sulfhydryl groups can be oxidised up to three times by three HClO molecules, forming sulfenic acids, sulfinic acids and R–SO3H, which are increasingly irreversible and bactericidal.
Although dibromine is a strong oxidising agent with a high first ionisation energy, very strong oxidisers such as peroxydisulfuryl fluoride (S2O6F2) can oxidise it to form the cherry-red cation. A few other bromine cations are known, namely the brown and dark brown .Greenwood and Earnshaw, pp. 842–4 The tribromide anion, , has also been characterised; it is analogous to triiodide.
Magnesium is sold in stores in shaved or bar form. Shavings burn white-hot, are impossible to smother with carbon dioxide or sand, and can ignite even wet kindling. Solid bars are impossible to ignite under normal conditions (and difficult even with a welding torch), and are thus very safe to carry. Magnesium powder and shavings are pyrophoric (they oxidise rapidly when exposed to the air).
There is also enzymatic degradation of the catecholamines by two main enzymes - monoamine oxidase and catechol-o-methyl transferase. Respectively, these enzymes oxidise monoamines (including catecholamines) and methylate the hydroxal groups of the phenyl moiety of catecholamines. These enzymes can be targeted pharmacologically. Inhibitors of these enzymes act as indirect agonists of adrenergic receptors as they prolong the action of catecholamines at the receptors.
Dissimilatory nitrate reduction to ammonium (DNRA), or nitrate/nitrite ammonification, is an anaerobic respiration process. Microbes which undertake DNRA oxidise organic matter and use nitrate as an electron acceptor, reducing it to nitrite, then ammonium (NO3−→NO2−→NH4+). Both denitrifying and nitrate ammonification bacteria will be competing for nitrate in the environment, although DNRA acts to conserve bioavailable nitrogen as soluble ammonium rather than producing dinitrogen gas.
Before the Great Oxygenation Event, copper was not readily available for living organisms. Most early copper was Cu+ and Cu. This oxidation state of copper is not very soluble in water. One billion years ago, after the great oxidation event the oxygen pressure rose sufficiently to oxidise Cu+ to Cu2+, increasing its solubility in water. As a result, the copper became much more available for living organisms.
Nearly every metal ion and quaternary ammonium ions can form a salt with flourosulfate. Different ways to make these salts include treating a metal chloride with anhydrous fluorosulfuric acid, which releases hydrogen chloride gas. Double decomposition methods with a metal sulfate with barium fluorosulfate, or a metal chloride with silver fluorosulfate, leave the metal salt in solution. The fluorosulfate anion is weakly coordinating, and is difficult to oxidise.
2,3,4-Pentanetrione can be made by oxidizing 2,4-pentanedione with selenium dioxide. Ludwig Wolff made the 2,3 oxime by reacting hydroxylamine with isonitrosoacetylacetone in cold, aqueous, concentrated solution. Yet other ways to make triones start from a β-dione, and oxidise the carbon at the α position, between the two ketone groups. Different methods include reaction with bromine to make a dibromide, and then reacting with acetaldehyde and hydrolysing.
Hydroxyl radicals go on to oxidise the side chains of amino acids and provide solvent accessibility of proteins within a cell. FPOP can provide information on the sites of ligand binding, protein interaction and protein conformational changes in vivo. Her group has continued to develop the FPOP technique, extending it with a no-flow platform for high-throughput in-cell measurements. In 2019, she received the Biophysical Society's Junior Faculty Award.
Methylotrophs such as Methylophilus oxidize compounds such as methanol into carbon dioxide and are key to the carbon cycle. Gallionella and Ferriphaselus oxidise ferric iron (Fe3+) ions into ferric hydroxide (Fe(OH)3) during autotrophic growth, and thus have roles in the carbon cycle and the iron cycle. As such, the Nitrosomonadales are critical to biogeochemical cycling of the elements and many species have key roles in principal biochemical processes.
Ubiquinol oxidases () are enzymes in the bacterial electron transport chain that oxidise ubiquinol into ubiquinone and reduce oxygen to water. These enzymes are one set of the many alternative terminal oxidases in the branched prokaryotic electron transport chain. The overall structure of the E. coli ubiquinol oxidase is similar to that of the mammalian Cytochrome c oxidase, with the addition of a polar ubiquinol-binding site embedded in the membrane.
Minteer became interested in extending the lifetimes of fuels and improving the efficiency of oxidation. She demonstrated the first room temperature enzyme-based fuel cells in 2014. The fuel cells use JP-8, a kerosene based fuel cells used by the United States Armed Forces, as well as enzymes as catalysts to oxidise the JP-8. She was the first to demonstrate paper-based batteries using an electrode coated in bacteria.
They have chemosymbiotic bacteria in their gills that oxidise hydrogen sulphide, and the molluscs absorb nutrients synthesized by these bacteria. The saddle oyster, Enigmonia aenigmatica, is a marine species that could be considered amphibious. It lives above the high tide mark in the tropical Indo-Pacific on the underside of mangrove leaves, on mangrove branches, and on sea walls in the splash zone. Some freshwater bivalves have very restricted ranges.
Furthermore, in the same year it was shown that TDG excises both 5fC and 5caC. The site left behind remains abasic until it is repaired by the base excision repair system. The biochemical process was further described in 2016 by evidence of base excision repair coupled with TET and TDG. In simple terms, TET–TDG–BER produces demethylation; TET proteins oxidise 5mC to create the substrate for TDG-dependent excision.
The element is liberated by halogen exchange, using chlorine gas to oxidise Br− to Br2. This is then removed with a blast of steam or air, and is then condensed and purified. Today, bromine is transported in large-capacity metal drums or lead- lined tanks that can hold hundreds of kilograms or even tonnes of bromine. The bromine industry is about one-hundredth the size of the chlorine industry.
Not all humans produce flatus that contains methane. For example, in one study of the faeces of nine adults, only five of the samples contained archaea capable of producing methane. The prevalence of methane over hydrogen in human farts may correlate with obesity, constipation and irritable bowel syndrome, as archaea that oxidise hydrogen into methane promote the metabolism's ability to absorb fatty acids from food. The remaining trace (<1% volume) compounds give flatus its smell.
APX enzymes show high specificity for ascorbate as an electron donor, but most APXs will also oxidise other organic substrates that are more characteristic of the class III peroxidases (such as horseradish peroxidase), in some cases at rates comparable to that of ascorbate itself. This means that defining an enzyme as an APX is not straightforward, but is usually applied when the specific activity for ascorbate is higher than that for other substrates.
Leaving it to ferment further, however, allows Acetobacter from the air to oxidise the ethanol into acetic acid. It is harvested once the level of acidity reaches four or five percent. The length of time it takes to produce nipa palm vinegar ranges from two to three weeks, though it is faster if a starter culture of yeast is used. Nipa palm sap has a relatively high sugar content, containing 15 to 22% sugar.
In the classical procedure for extracting uranium, pitchblende is broken up and mixed with sulfuric and nitric acids. The uranium dissolves to form uranyl sulfate and sodium carbonate is added to precipitate impurities. If the uranium in the ore is in the tetravalent oxidation state, an oxidiser is added to oxidise it to the hexavalent oxidation state, and sodium hydroxide is then added to make the uranium precipitate as sodium diuranate.Purification of sodium diuranate.
Diagram of intercalation of Li into a titanium disulfide cathode. One axis of the TiS2 crystal swells, and charge transfers from Li to Ti. Treating graphite with strong acids in the presence of oxidizing agents causes the graphite to oxidise. Graphite bisulfate, [C24]+[HSO4]−, is prepared by this approach using sulfuric acid and a little nitric acid or chromic acid. The analogous graphite perchlorate can be made similarly by reaction with perchloric acid.
It can dissolve in water in alkaline conditions. An equilibrium between several ions is produced, depending on pH and concentration: [Ni(OH)2[IO3(OH)3]2]2−, [Ni(OH)2[IO3(OH)3][IO4(OH)2 3−. The ability to oxidise bromate to perbromate is unusual, and very few reagents can do this. The reaction occurs by Ni(IV) changing to Ni(III) with the release of hydroxyl radical which can react with bromate.
This reaction is studied as a way to convert sulfur dioxide into sulfur and oxygen using only heat. Another thermochemical reaction for cerium sulfite sulfate hydrate involves using iodine to oxidise the sulfite to sulfate, producing hydrogen iodide which can then be used to make hydrogen gas and iodine. When combined with the previous high temperature process, water can be split into oxygen and hydrogen using heat only. This is termed the GA sulfur-iodine water splitting cycle.
Post-deposition annealing of contacts is useful for relieving stress as well as for inducing any desirable reactions between the metal and the semiconductor. Because deposited metals can themselves oxidise in ambient conditions, to the detriment of the contacts' electrical properties, it is common to form ohmic contacts with layered structures. The bottom layer, in contact with the semiconductor, is chosen for its ability to induce ohmic behaviour. The top layer is chosen for its low reactivity.
1,1-Ethanedithiol has several reactions known that are important in white wine flavours. In the presence of oxygen, 1,1-ethanedithiol is converted to cis/trans-3,6-dimethyl-1,2,4,5-tetrathiane which has a rubbery aroma. This molecule has a ring with four sulfur atoms and two carbons, two 1,1-ethanedithiol molecules become linked at their sulfur atoms with the loss of hydrogen. This can further oxidise to cis/trans-3,6-dimethyl-1,2,5-trithiolane which has a meat-like odour.
A modification has also been reported in which DEAD can be used in catalytic versus stoichiometric quantities, however this procedure requires the use of stoichiometric (diacetoxyiodo)benzene to oxidise the hydrazine by-product back to DEAD. Denton and co-workers have reported a redox-neutral variant of the Mitsunobu reaction which employs a phosphorus(III) catalyst to activate the substrate, ensuring inversion in the nucleophilic attack, and uses a Dean-Stark trap to remove the water by- product.
Chemistry of the Elements (2nd Edn.), Oxford:Butterworth- Heinemann. . Unlike osmium tetroxide, ruthenium tetroxide is less stable and is strong enough as an oxidising agent to oxidise dilute hydrochloric acid and organic solvents like ethanol at room temperature, and is easily reduced to ruthenate () in aqueous alkaline solutions; it decomposes to form the dioxide above 100 °C. Unlike iron but like osmium, ruthenium does not form oxides in its lower +2 and +3 oxidation states.Greenwood and Earnshaw, pp.
Neil Bartlett demonstrated that dioxygenyl hexafluoroplatinate (O2PtF6), containing the dioxygenyl cation, can be prepared at room temperature by direct reaction of oxygen gas (O2) with platinum hexafluoride (PtF6): :O2 \+ PtF6 → The compound can also be prepared from a mixture of fluorine and oxygen gases in the presence of a platinum sponge at 450 °C, and from oxygen difluoride () above 400 °C: :6 \+ 2 Pt → 2 \+ At lower temperatures (around 350 °C), platinum tetrafluoride is produced instead of dioxygenyl hexafluoroplatinate. Dioxygenyl hexafluoroplatinate played a pivotal role in the discovery of noble gas compounds. The observation that PtF6 is a powerful enough oxidising agent to oxidise O2 (which has a first ionization potential of 12.2 eV) led Bartlett to reason that it should also be able to oxidise xenon (first ionization potential 12.13 eV). His subsequent investigation yielded the first compound of a noble gas, xenon hexafluoroplatinate. is also found in similar compounds of the form O2MF6, where M is arsenic (As), antimony (Sb), gold (Au), niobium (Nb), ruthenium (Ru), rhenium (Re), rhodium (Rh), vanadium (V), or phosphorus (P).
In the finery, a workman known as the "finer" remelted pig iron so as to oxidise the carbon (and silicon). This produced a lump of iron (with some slag) known as a bloom. This was consolidated using a water- powered hammer (see trip hammer) and returned to the finery. The next stages were undertaken by the "hammerman", who in some iron-making areas such as South Yorkshire was also known as the "stringsmith", who heated his iron in a string-furnace.
Canadian Copper Company, at Greater Sudbury, in 1913. These converters refined a matte with 36% Ni+Cu, in a matte containing 80% Ni+Cu. The Manhès–David process is a refining process of the copper mattes, invented in 1880 by the French industrialist Pierre Manhès and his engineer . Inspired by the Bessemer process, it consists of the use of a converter to oxidise with air the undesirable chemical elements (mainly iron and sulfur) contained in the matte, to transform it into copper.
The nitric acid process produces nitric acid for use in making ammonium nitrate fertiliser. Using the Ostwald process, ammonia is vaporised and then oxidised over a 95% platinum and 5% rhodium catalyst at and to form nitric oxide and superheated steam. The reaction gases are cooled to before absorption by various heat recovery mechanisms. The cooled reaction gases are then passed through the bottom of an absorption column where a stream of air is added to oxidise nitric oxide to nitrogen dioxide.
Hydroxyl radicals have been shown to modify the IgE-binding capacity in pollens, spores and pet dander through the degradation and modification of the tertiary structure and/or the induction of protein denaturation and/or aggregation, resulting in a modified allergen structure. Hydroxyl radicals instantly denature Der p1 and Der f1 (house dust mites). Hydroxyl radicals oxidise their protein structures, for example causing protein backbone damage due primarily to a hydrogen abstraction or oxygen addition. Both hydroxyl radical initiated oxidation mechanisms result in a modified allergen structure.
The early Etrurian examples merely imitated the red-figure technique. Similar to a rare and early Attic technique (see Six's technique), the whole vessel was covered with black glossy clay and figures were applied afterwards using mineral colours that would oxidise red or white. Thus, in contrast to contemporary Attic vase painting, the red colour was not achieved by leaving areas unpainted but by adding paint to the black prime layer. Like in black-figure vases, internal detail was not painted on, but incised into the figures.
Sponge iron is not useful by itself, but can be processed to create wrought iron or steel. The sponge is removed from the furnace, called a bloomery, and repeatedly beaten with heavy hammers and folded over to remove the slag, oxidise any carbon or carbide and weld the iron together. This treatment usually creates wrought iron with about three percent slag and a fraction of a percent of other impurities. Further treatment may add controlled amounts of carbon, allowing various kinds of heat treatment (e.g. "steeling").
Many of the boranes readily oxidise on contact with air, some violently. The parent member BH3 is called borane, but it is known only in the gaseous state, and dimerises to form diborane, B2H6. The larger boranes all consist of boron clusters that are polyhedral, some of which exist as isomers. For example, isomers of B20H26 are based on the fusion of two 10-atom clusters. The most important boranes are diborane B2H6 and two of its pyrolysis products, pentaborane B5H9 and decaborane B10H14.
Osmond iron consisted of balls of wrought iron, produced by melting pig iron and catching the droplets on a staff, which was spun in front of a blast of air so as to expose as much of it as possible to the air and oxidise its carbon content.H. R. Schubert, History of the British Iron and Steel Industry from 450 BC to AD 1775 (Routledge and Kegan Paul, London 1957), 299–304. The resultant ball was often forged into bar iron in a hammer mill.
The "Indian Red" paint as produced in the railway's workshop and tended to oxidise over time. Recently repainted locomotives would be a deep red colour with a hint of orange; those that had not visited the paint shop in some time would be a reddish brown. This was lined out white-black-white, and remained standard until the 1967 re-opening when Lord Ailsa had service locomotives repainted into a fresh "spring" green livery. This was very similar to London and North Eastern Railway apple green.
The oxidation of estradiol by lactoperoxidase is a possible source of oxidative stress in breast cancer. The ability of lactoperoxidase to propagate a chain reaction leading to oxygen consumption and intracellular hydrogen peroxide accumulation could explain the hydroxyl radical-induced DNA base lesions recently reported in female breast cancer tissue. Lactoperoxidase may be involved in breast carcinogenesis, because of its ability to interact with estrogenic hormones and oxidise them through two one-electron reaction steps. Lactoperoxidase reacts with the phenolic A-ring of estrogens to produce reactive free radicals.
Thayer-Martin agar is selective for growth of Neisseria species. Further testing (oxidase, Gram stain, carbohydrate use) is needed to differentiate N. gonorrhoeae from N. meningitidis Carbohydrate utilization of Neisseria gonorrhoeae: N. gonorrhoeae will oxidise glucose, not maltose, sucrose, or lactose; N. meningitidis ferments glucose and maltose. N. gonorrhoeae is usually isolated on Thayer-Martin agar (or VPN) agar in an environment enriched with 3-7% carbon dioxide. Thayer-Martin agar is a chocolate agar plate (heated blood agar) containing nutrients and antimicrobials (vancomycin, colistin, nystatin, and trimethoprim).
Desmophyllum have been observed at the Lost City field Lost City and other hydrothermal vent systems support vastly different lifeforms due to Lost City's unique chemistry. A variety of microorganisms live in, on, and around the vents. Methanosarcinales-like archaea form thick biofilms inside the vents where they subsist on hydrogen and methane; bacteria related to the Firmicutes also live inside the vents. External to the vents, archaea, including the newly described ANME-1, and bacteria, including proteobacteria, oxidise methane and sulfur as their primary sources of energy.
In the process of crushing, tearing and pelletising the tea leaves, pressures and stresses occur which break down the cells, releasing large amounts of the phytins that normally oxidise to produce black tea's mahogany colour. Since, regardless of origin, CTC teas in their dry form are generically "tea-like" in aroma, and of similar pelletized appearance, it is easy to adulterate a more expensive CTC-type tea with inexpensive and generally mild lowland teas of the same process. Whole and broken leaf teas by contrast are quite varied in appearance, making adulteration more difficult.
The bacterial oxidation process comprises contacting refractory sulfide ROM ore or concentrate with a strain of the bacterial culture for a suitable treatment period under an optimum operating environment. The bacteria oxidise the sulfide minerals, thus liberating the occluded gold for subsequent recovery via cyanidation. The BIOX® process is a proprietary technology owned by Biomin South Africa and used under licence by a number of operating mines. The BIOX® process involves bacterial oxidation in agitated tanks for pre-treatment of refractory ores and concentrates ahead of conventional cyanide leach for gold recovery.
Superheated water, along with supercritical water, has been used to oxidise hazardous material in the wet oxidation process. Organic compounds are rapidly oxidised without the production of toxic materials sometimes produced by combustion. However, when the oxygen levels are lower, organic compounds can be quite stable in superheated water. As the concentration of hydronium () and hydroxide () ions are 100 times larger than in water at 25 °C, superheated water can act as a stronger acid and a stronger base, and many different types of reaction can be carried out.
American Cancer Society 2008; National Capital Poison Center 2010 Soils contaminated by heavy metals can be remediated by one or more of the following technologies: isolation; immobilization; toxicity reduction; physical separation; or extraction. Isolation involves the use of caps, membranes or below-ground barriers in an attempt to quarantine the contaminated soil. Immobilization aims to alter the properties of the soil so as to hinder the mobility of the heavy contaminants. Toxicity reduction attempts to oxidise or reduce the toxic heavy metal ions, via chemical or biological means into less toxic or mobile forms.
Pyocyanin (PCN−) is one of the many toxins produced and secreted by the Gram negative bacterium Pseudomonas aeruginosa. Pyocyanin is a blue, secondary metabolite with the ability to oxidise and reduce other molecules and therefore kill microbes competing against P. aeruginosa as well as mammalian cells of the lungs which P. aeruginosa has infected during cystic fibrosis. Since pyocyanin is a zwitterion at blood pH, it is easily able to cross the cell membrane. There are three different states in which pyocyanin can exist: oxidized, monovalently reduced or divalently reduced.
It reacts explosively with water and hydrocarbons, but is a less violent fluorinating reagent than chlorine trifluoride. It reacts vigorously with boron, carbon, silicon, arsenic, antimony, iodine, and sulfur to give fluorides, and also reacts with most metals and their oxides: as such, it is used to oxidise uranium to uranium hexafluoride in the nuclear industry. Refractory oxides tend to be only partially fluorinated, but here the derivatives KBrF4 and BrF2SbF6 remain reactive. Bromine trifluoride is a useful nonaqueous ionising solvent, since it readily dissociates to form and and thus conducts electricity.
Xenon trioxide is a strong oxidising agent and can oxidise most substances that are at all oxidisable. However, it is slow-acting and this reduces its usefulness. Above 25 °C, xenon trioxide is very prone to violent explosion: :2 XeO3 → 2 Xe + 3 O2 (ΔHf = −402 kJ/mol) When it dissolves in water, an acidic solution of xenic acid is formed: :XeO3(aq) + H2O → H2XeO4 H+ \+ This solution is stable at room temperature and lacks the explosive properties of xenon trioxide. It oxidises carboxylic acids quantitatively to carbon dioxide and water.
The chalky buttercup has a symbiotic relationship with certain bacteria that live in its gills. These can oxidise methane and hydrogen sulphide, both of which are found in the low-oxygen, silty sand and mud in which this mollusc burrows. The chalky buttercup uses the energy produced by the bacteria and this enables it to live in an environment that would otherwise be too low in food particles. A similar mutually beneficial arrangement is found among deep-water clams which harbour bacteria that flourish beside the thermal vents where the molluscs live.
When exposed to the air, such as may occur in a time of severe drought, the sulphides oxidise, producing sulphuric acid. The barrages now prevent the seawater inflows that had formerly prevented this phenomenon in every drought since the last ice age. A weir was proposed near Pomanda Point where the river entered the lake, in order to protect upriver and Adelaide's water supplies should it become necessary to open the barrages, but this plan was dropped by the South Australian government after a campaign by the River, Lakes and Coorong Action Group highlighted the many environmental problems such a weir would cause.
At pH 7, glucose exists in solution in cyclic hemiacetal form as 63.6% β-D-glucopyranose and 36.4% α-D-glucopyranose, the proportion of linear and furanose form being negligible. The glucose oxidase binds specifically to β-D-glucopyranose and does not act on α-D-glucose. It is able to oxidise all of the glucose in solution because the equilibrium between the α and β anomers is driven towards the β side as it is consumed in the reaction. Glucose oxidase catalyzes the oxidation of β-D-glucose into D-glucono-1,5-lactone, which then hydrolyzes to gluconic acid.
Athena and Poseidon on a volute krater by the Nazzano Painters, circa 360 BC Early vessels of this style merely imitated the red-figure technique. As on some early Attic vases, this was achieved by covering the whole vase body in black shiny slip, then adding figures on top, using paints that would oxidise into red or white during firing. In true red-figure, the red areas were left free of slip. In pseudo-red-figure, internal details were marked by incision, similar to the usual practice in black-figure vase painting, rather than painted on, as in true red-figure.
These will convert polymer hydroperoxides to alcohols, becoming oxidized to organophosphates in the process: :ROOH + P(OR')3 → OP(OR')3 \+ ROH Transesterification can then take place, in which the hydroxylated polymer is exchanged for a phenol: :ROH + OP(OR')3 → R'OH + OP(OR')2OR This exchange further stabilizes the polymer by releasing a primary antioxidant, because of this phosphites are sometimes considered multi-functional antioxidants as they can combine both types of activity. Organosulfur compounds are also efficient hydroperoxide decomposers, with thioethers being particularly effective against long-term thermal aging, they are ultimately oxidise up to sulfoxides and sulfones.
Whereas promiscuity is mainly studied in terms of standard enzyme kinetics, drug binding and subsequent reaction is a promiscuous activity as the enzyme catalyses an inactivating reaction towards a novel substrate it did not evolve to catalyse. This could be because of the demonstration that there are only a small number of distinct ligand binding pockets in proteins. Mammalian xenobiotic metabolism, on the other hand, was evolved to have a broad specificity to oxidise, bind and eliminate foreign lipophilic compounds which may be toxic, such as plant alkaloids, so their ability to detoxify anthropogenic xenobiotics is an extension of this.
A cask of fino is considered to be amontillado if the layer of flor fails to develop adequately, is intentionally killed by additional fortification, or is allowed to die off through non-replenishment. Without the layer of flor, amontillado must be fortified to approximately 17.5% alcohol so that it does not oxidise too quickly. After the additional fortification, Amontillado oxidises slowly, exposed to oxygen through the slightly porous American or Canadian oak casks, and gains a darker colour and richer flavour than fino. Amontillado is characterized by nutty aromas, tobacco, aromatic herbs and often ethereal, polished notes of oak.
They do not develop flor and so oxidise slightly as they age, giving them a darker colour. Because the fortification takes place after fermentation, most sherries are initially dry, with any sweetness being added later. In contrast, port wine is fortified halfway through its fermentation, which stops the process so that not all of the sugar is turned into alcohol. Wines from different years are aged and blended using a solera system before bottling, so that bottles of sherry will not usually carry a specific vintage year and can contain a small proportion of very old wine.
New plants were set up to concentrate and retreat the tailings from the mills. Six pyrites works are shown on Robert Logan Jack's 1878 plan of the Charters Towers Goldfield. Chlorination, which was introduced in the mid 1880s, involved first roasting the concentrates slowly in a large reverberatory furnace to expel the sulphur from the pyrites and to oxidise their base metals so as to reduce the amount of chlorine they could absorb. Salt was then added to satisfy copper, zinc and other metals whose oxides have a tendency to form chlorides when chlorine is presented to them in a free state.
This crystallises trisodium phosphate decahydrate when cooled below 60 °C; uranium impurities in this product increase with the amount of silicon dioxide in the reaction mixture, necessitating recrystallisation before commercial use. The hydroxides are dissolved at 80 °C in 37% hydrochloric acid. Filtration of the remaining precipitates followed by addition of 47% sodium hydroxide results in the precipitation of thorium and uranium at about pH 5.8. Complete drying of the precipitate must be avoided, as air may oxidise cerium from the +3 to the +4 oxidation state, and the cerium(IV) formed can liberate free chlorine from the hydrochloric acid.
Iodine trifluoride (IF3) is an unstable yellow solid that decomposes above −28 °C. It is thus little-known. It is difficult to produce because fluorine gas would tend to oxidise iodine all the way to the pentafluoride; reaction at low temperature with xenon difluoride is necessary. Iodine trichloride, which exists in the solid state as the planar dimer I2Cl6, is a bright yellow solid, synthesised by reacting iodine with liquid chlorine at −80 °C; caution is necessary during purification because it easily dissociates to iodine monochloride and chlorine and hence can act as a strong chlorinating agent.
The interactions between the different dipoles of each molecule cause a net attraction force. Oxides, such as iron oxide or rust, , form when oxygen combines with other elements Due to its electronegativity, oxygen forms chemical bonds with almost all other free elements at elevated temperatures to give corresponding oxides. However, some elements, such as iron which oxidises to iron oxide, or rust, , readily oxidise at standard conditions for temperature and pressure (STP). The surface of metals like aluminium and titanium are oxidized in the presence of air and become coated with a thin film of oxide that passivates the metal and slows further corrosion.
The Thioalkalibacteraceae are a family of extremophiles, namely halophilic, alkaliphilic or alkalitolerant, mesophilic to thermophilic obligately chemolithoautotrophic organisms in the Chromatiales comprising the genus Thioalkalibacter and Guyparkeria. The family is closely related to the family Halothiobacillaceae of halotolerant, mesophilic obligate autotrophs. The type genus of the family is Thioalkalibacter, and both genera in the family are obligate autotrophs that fix carbon dioxide into biological material using the Calvin-Benson-Bassham cycle (using form IAc RuBisCO) and oxidise sulfur oxyanions, sulfide and elementary sulfur as their electron donor. All genera use ubiquinone-8 as their major respiratory quinone and have a G+C fraction of 54-68 mol%.
Further attack occurs in the freshly exposed crack surfaces and the crack grows steadily until it completes a circuit and the product separates or fails. In the case of a seal or a tube, failure occurs when the wall of the device is penetrated. EDX spectrum of crack surface EDX spectrum of unaffected rubber surface The carbonyl end groups that are formed are usually aldehydes or ketones, which can oxidise further to carboxylic acids. The net result is a high concentration of elemental oxygen on the crack surfaces, which can be detected using Energy- dispersive X-ray spectroscopy in the environmental SEM, or ESEM.
The oxidation of metal sulfide (by oxygen) is slow without colonization by acidophiles, particularly Acidithiobacillus ferrooxidans (synonym Thiobacillus ferrooxidans). These bacteria can accelerate pyritic oxidation by 106 times. In that study, a proposal for the rate at which A.ferrooxidans can oxidise pyrite is the ability to use ferrous iron to generate a ferric iron catalyst : :Fe2+ \+ 1/4O2 \+ H+ → Fe3+ \+ 1/2H2O Under the above acidic conditions, ferric iron (Fe3+) is a more potent oxidant than oxygen, resulting in faster pyrite oxidation rates. A.ferrooxidans is a chemolithoautotrophic bacteria, due to the oligotrophic nature (low dissolved organic carbon concentration) of acidic environments, and their lack of illumination for phototrophy.
A small Stretford reactor for scrubbing H2S from geothermal steam The Stretford process was developed during the late 1950s to remove hydrogen sulfide (H2S) from town gas. It was the first liquid phase, oxidation process for converting H2S into sulfur to gain widespread commercial acceptance. Developed by Tom Nicklin of the North Western Gas Board (NWGB) and the Clayton Aniline Company, in Manchester, England, the name of the process was derived from the location of the NWGB's laboratories, in Stretford. The process uses reduction-oxidation (redox) chemistry to oxidise the H2S into elemental sulfur, in an alkaline solution containing vanadium as an oxygen carrier.
The cyanide that remain in tails streams from gold plants is potentially hazardous. Therefore, some operations process the cyanide-containing waste streams in a detoxification step. This step lowers the concentrations of these cyanide compounds. The INCO-licensed process and the Caro's acid process oxidise the cyanide to cyanate, which is not as toxic as the cyanide ion, and which can then react to form carbonates and ammonia: : + [O] → : + 2 → + The Inco process can typically lower cyanide concentrations to below 50 mg/L, whereas the Caro's acid process can lower cyanide levels to between 10 and 50 mg/L, with the lower concentrations achievable in solution streams rather than slurries.
Further attack occurs in the freshly exposed crack surfaces and the crack grows steadily until it completes a circuit and the product separates or fails. In the case of a seal or a tube, failure occurs when the wall of the device is penetrated. EDX spectrum of crack surface EDX spectrum of unaffected rubber surface The carbonyl end groups which are formed are usually aldehydes or ketones, which can oxidise further to carboxylic acids. The net result is a high concentration of elemental oxygen on the crack surfaces, which can be detected using Energy- dispersive X-ray spectroscopy in the environmental SEM, or ESEM.
Food waste remains primarily disposed to landfill (54 per cent of total municipal waste was disposed of in this way in 2007/8), although year-on-year the amount being sent to landfill is decreasing. Composting, the purposeful biodegradation of organic matter by microorganisms, is among the most simple ways of treating food waste and thereby preventing it being sent to landfill. Since all biodegradable materials will eventually oxidise to become compost, the process can be undertaken at home with no running costs, although equipment can accelerate the process. Most components of food waste are putrescibles and will be broken down in a compost, however some exceptions will not (e.g.
Methemoglobinaemia is a form of abnormal hemoglobin where the iron centre has been oxidised from the ferrous +2 oxidation state (the normal form) to the ferric +3 state. This causes a leftward shift in the oxygen hemoglobin dissociation curve, as any residual heme with oxygenated ferrous iron (+2 state) is unable to unload its bound oxygen into tissues (because 3+ iron impairs hemoglobin's cooperativity), thereby increasing its affinity with oxygen. However, methemoglobin has increased affinity for cyanide, and is therefore useful in the treatment of cyanide poisoning. In cases of accidental ingestion, administration of a nitrite (such as amyl nitrite) can be used to deliberately oxidise hemoglobin and raise methemoglobin levels, restoring the functioning of cytochrome oxidase.
The acidic nature of soot deposits caused materials like iron and bronze to oxidise faster, while stone, mortar, and brick deteriorated at a noticeably faster rate. In response, terra cotta and other kiln-fired tiles became popular facings for buildings in the 1880s and 1890s, because they resisted soot and damp and also provided welcome colour to buildings that were otherwise drab. Concerns over smoke pollution gave rise to private Smoke Abatement societies in London and throughout Britain, which championed different measures for controlling smoke pollution. One of these measures was smoke-prevention technology - an exhibition of such devices was staged in London over an 11-week period by the Smoke Abatement Committee in 1881.
Sherry ( ) is a fortified wine made from white grapes that are grown near the city of Jerez de la Frontera in Andalusia, Spain. Sherry is produced in a variety of styles made primarily from the Palomino grape, ranging from light versions similar to white table wines, such as Manzanilla and fino, to darker and heavier versions that have been allowed to oxidise as they age in barrel, such as Amontillado and oloroso. Sweet dessert wines are also made from Pedro Ximénez or Moscatel grapes, and are sometimes blended with Palomino-based sherries. Under the official name of Jerez-Xérès-Sherry, it is one of Spain's wine regions, a Denominación de Origen Protegida (DOP).
This layer slightly increases the mass of the sphere, an effect that must be accounted for when polishing the sphere to its finished size. Oxidation is not an issue with platinum and iridium, both of which are noble metals that are roughly as cathodic as oxygen and therefore don't oxidise unless coaxed to do so in the laboratory. The presence of the thin oxide layer on a silicon-sphere mass prototype places additional restrictions on the procedures that might be suitable to clean it to avoid changing the layer's thickness or oxide stoichiometry. All silicon-based approaches would fix the Avogadro constant but vary in the details of the definition of the kilogram.
Like other types of Go stones, yunzi are washed and dried using a gentle soap solution to remove any dust from the packaging/manufacturing process. Although a light coat of oil, wiped clean, will help yunzi stones appear at their best, care must be taken in oiling yunzi. Because vegetable oils, such as olive or canola oil, will oxidise and become rancid over time, they should not be applied to yunzi to avoid developing an unpleasant odor. Instead, common practice is to use an unscented mineral oil to oil yunzi; alternatively, stones may be washed but remain unoiled; over time, the natural oils incurred by human touch will polish yunzi to a sheen.
Its reaction with hydrazine to form hydrogen fluoride, nitrogen, and chlorine gases was used in experimental rocket motors, but has problems largely stemming from its extreme hypergolicity resulting in ignition without any measurable delay. Today, it is mostly used in nuclear fuel processing, to oxidise uranium to uranium hexafluoride for its enriching and to separate it from plutonium. It can act as a fluoride ion donor or acceptor (Lewis base or acid), although it does not dissociate appreciably into and ions.Greenwood and Earnshaw, pp. 828–31 Chlorine pentafluoride (ClF5) is made on a large scale by direct fluorination of chlorine with excess fluorine gas at 350 °C and 250 atm, and on a small scale by reacting metal chlorides with fluorine gas at 100–300 °C.
The very loosely defined "species" Thiobacillus trautweinii was where sulfur oxidising heterotrophs and chemolithoheterotrophs were assigned in the 1910-1960s era, most of which were probably Pseudomonas species. Many species named in this genus were never deposited in service collections and have been lost. All species are obligate autotrophs (using the transaldolase form of the Calvin-Benson-Bassham cycle) using elementary sulfur, thiosulfate, or polythionates as energy sources - the former Thiobacillus aquaesulis can grow weakly on complex media as a heterotroph, but has been reclassified to Annwoodia aquaesulis. Some strains (E6 and Tk-m) of the type species Thiobacillus thioparus can use the sulfur from dimethylsulfide, dimethyldisulfide, or carbon disulfide to support autotrophic growth - they oxidise the carbon from these species into carbon dioxide and assimilate it.
ER oxidoreductin 1 (Ero1) is an oxidoreductase enzyme that catalyses the formation and isomerization of protein disulfide bonds in the endoplasmic reticulum (ER) of eukaryotes. ER Oxidoreductin 1 (Ero1) is a conserved, luminal, glycoprotein that is tightly associated with the ER membrane, and is essential for the oxidation of protein dithiols. Since disulfide bond formation is an oxidative process, the major pathway of its catalysis has evolved to utilise oxidoreductases, which become reduced during the thiol- disulfide exchange reactions that oxidise the cysteine thiol groups of nascent polypeptides. Ero1 is required for the introduction of oxidising equivalents into the ER and their direct transfer to protein disulfide isomerase (PDI), thereby ensuring the correct folding and assembly of proteins that contain disulfide bonds in their native state.
In the DSM process, cyclohexane was heated to about 155 °C (311 °F) before passing into a series of six reactors. The reactors were constructed from mild steel with a stainless steel lining; when operating they held in total about 145 tonnes of flammable liquid at a working pressure of 8.6 bar gauge (0.86 MPa gauge; 125 psig). In each of the reactors, compressed air was passed through the cyclohexane, causing a small percentage of the cyclohexane to oxidise and produce cyclohexanone, some cyclohexanol also being produced. Each reactor was slightly (approximately 14 inches, 350 mm) lower than the previous one, so that the reaction mixture flowed from one to the next by gravity through nominal 28-inch bore (700mm DN) stub pipes with inset bellows.
Chocolates in aluminium foil packaging Aluminium is used for packaging as it is highly malleable: it can be easily converted to thin sheets and folded, rolled or packed. Aluminium foil acts as a total barrier to light and oxygen (which cause fats to oxidise or become rancid), odours and flavours, moistness, and germs, and so it is used broadly in food and pharmaceutical packaging, including long-life packs (aseptic packaging) for drinks and dairy goods, which allows storing without refrigeration. Aluminium foil containers and trays are used to bake pies and to pack takeaway meals, ready snacks and long life pet foods. Aluminium foil is widely sold into the consumer market, often in rolls of width and several metres in length.
The water carried to the boiler was totally pure and circulated in a closed circuit. Contrary to what one might think, the power station did not use the river water for vaporisation, but water from the urban water network (including a well on the plant's premises). Firstly, it was stored in the water tower – a large reservoir located on the roof of the high pressure boiler building – and was then treated in the Water Room, where three main functions were carried out: water treatment, pre- heating and pumping. The treatment was of utmost importance since the water's own impurities and excess oxygen could perforate the tubing/turbines and oxidise the tubes, adding to the incrustation and accumulation of small particles in the iron and steel, thereby corroding the equipment and reducing its performance.
It is not possible to remove a multi-pin part by melting solder on the pins sequentially, as one joint will solidify as the next is melted; pumps and solder wick are among methods to remove solder from all joints, leaving the part free to be removed. Suction pumps are also used with a suction head appropriate for each part to pick up and remove tiny surface mount devices once solder has melted, and to place parts. Hot air pumps blow air hot enough to melt all the solder around a small surface mounted part, and can be used for soldering parts in place, and for desoldering followed by removal before the solder solidifies by a vacuum pump or with tweezers. Hot air has a tendency to oxidise metals; a non-oxidising gas, usually nitrogen, can be used instead of air, at increased cost of equipment and consumables.
This is because the P=S compound is not active as an acetylcholinesterase inhibitor in either mammals or insects, in mammals the animals metabolism tends to remove lipophilic side groups from the phosphorus atom while an insect tends to oxidise the compound so removing the terminal sulfur and replacing it with a terminal oxygen which causes the compound to be more able to act as an acetylcholinesterase inhibitor. The structure of the PSC compound The dithiophosphine ylides of LR and related compounds can react with strained alkenes, for example the bicyclic norbornadiene reacts with FcPS to form a compound with a PSC ring. Unlike small rings containing only first row elements such as carbon, nitrogen and oxygen the small rings containing more heavy elements such as sulfur and selenium are more stable with regards to ring opening. Hence, the rings such as PSC are much more stable than things like epoxides.

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