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117 Sentences With "precipitate out"

How to use precipitate out in a sentence? Find typical usage patterns (collocations)/phrases/context for "precipitate out" and check conjugation/comparative form for "precipitate out". Mastering all the usages of "precipitate out" from sentence examples published by news publications.

That caused dissolved minerals to precipitate out of the water as a rock called dolomite.
Then these droplets need to grow to a size where they precipitate out of the cloud, finally falling where and when required.
Carbonate minerals, which precipitate out of seawater, form the basis of limestone, coral skeletons, and the shells of a wide variety of crustaceans and mollusks here on Earth.
Ice surface temperatures below -22 °C start to precipitate out sodium chloride and even lower temperatures other ions will precipitate out, but with surface ice temperature that low frost flowers cannot form, so it is unlikely that there will be depleted sodium chloride.
A precipitin is an antibody which can precipitate out of a solution upon antigen binding.
Ethanol precipitation works by using ethanol as an antisolvent of DNA, causing it to precipitate out of solution. The soluble fraction is discarded to remove other biomolecules.
It can be also made by passing acetylene through solutions of hypochlorous acid. As a laboratory reagent, both DCA and TCA are used as precipitants to prompt macromolecules such as proteins to precipitate out of solution.
Potassium bitartrate in an empty white wine bottle Potassium bitartrate has a low solubility in water. It crystallizes in wine casks during the fermentation of grape juice, and can precipitate out of wine in bottles. The crystals (wine diamonds) will often form on the underside of a cork in wine-filled bottles that have been stored at temperatures below , and will seldom, if ever, dissolve naturally into the wine. These crystals also precipitate out of fresh grape juice that has been chilled or allowed to stand for some time.
Gypsum desert rose The sulfate minerals all contain the sulfate anion, [SO4]2−. They tend to be transparent to translucent, soft, and many are fragile., p. 453 Sulfate minerals commonly form as evaporites, where they precipitate out of evaporating saline waters.
Sylvite has a salty taste with a distinct bitterness. Sylvite is one of the last evaporite minerals to precipitate out of solution. As such, it is only found in very dry saline areas. Its principal use is as a potassium fertilizer.
As the holons combine to form greater wholes via alphabetic combination, such holarchies also tend to become problem archetypes, which often precipitate out of natural phenomena modeling. Examples are boundary-value problems, solved by the combination of correlation and simulation holons.
Carbonates, sulfates, and silica should precipitate out ahead of them. Sulfates and silica have been found by the Mars rovers on the surface. Places with chloride minerals may have once held various life forms. Furthermore, such areas could preserve traces of ancient life.
Tellurium tetrafluoride will react with water or silica and forms tellurium oxides. Copper, silver, gold or nickel will react with tellurium tetrafluoride at 185 °C. It does not react with platinum. It is soluble in SbF5 and will precipitate out the complex TeF4SbF5.
A picture below shows some deposits within the Phaethontis quadrangle. Evidence suggests that the deposits were formed from the evaporation of mineral- enriched waters. Lakes may have been scattered over large areas of the Martian surface. Carbonates, sulfates, and silica should precipitate out ahead of them.
A variety of minerals precipitate out of the springs including gypsum, and at Colour Peak crystals of the metastable mineral ikaite (·6) which decomposes rapidly when removed from freezing water.Impey, Chris, Jonathan Lunine, and José Funes, eds. Frontiers of astrobiology (page 161). Cambridge University Press, 2012.
In a number of analytical procedures one of the roles of phosphotungstic acid is to precipitate out proteins. It has been termed a "universal" precipitant for polar proteins. Further studies showed that no precipitation occurred with α-amino groups but did occur with guanidino, ε-amino and imidazole groups.
When hydrogen moves out of solution with iron it reverts to elemental hydrogen (). When iron hydrides with more than 2 ppm hydrogen are cooled, the hydrogen no longer fits within the crystalline structures, resulting in an excess of hydrogen. The way for hydrogen to leave the crystalline phases is for it to precipitate out of solution as elemental hydrogen, leaving behind a surrounding phase of BCC iron called ferrite with a small proportion of hydrogen in solution. In a supersaturated composition (greater than 2 ppm hydrogen), the hydrogen will precipitate out as large inclusions of elemental hydrogen at the grain boundaries until the proportion of hydrogen in the grains has decreased to the saturated composition (2 ppm).
Previous attempts at purification of insulin attempted to keep the insulin in solution and precipitate out the contaminating proteins. Walden found that if he adjusted the pH to produce the maximum precipitation, the precipitate contained highly purified insulin. His process yielded insulin that was 10 to 100 times more pure than previous batches.
The water is evaporated, usually over a series of ponds, to the point where sodium chloride and other salts precipitate out of the saturated brine, allowing pure salts to be harvested. Where complete evaporation in this fashion was not routinely achievable due to weather, salt was produced from the concentrated brine by boiling the brine.
Calcium carbonate dissolved into water may precipitate out where the water discharges some of its dissolved carbon dioxide. Rivers which emerge from springs may produce tufa terraces, consisting of layers of calcite deposited over extended periods of time. In caves, a variety of features collectively called speleothems are formed by deposition of calcium carbonate and other dissolved minerals.
Several other minerals, such as the gemstone topaz, contain fluoride. Fluoride is not significant in seawater or brines, unlike the other halides, because the alkaline earth fluorides precipitate out of water. Commercially insignificant quantities of organofluorines have been observed in volcanic eruptions and in geothermal springs. Their ultimate origin (from biological sources or geological formation) is unclear.
Dazomet is synthesized from carbon disulfide (CS2) and diluted methylamine (CH3NH2). After stirring for 1-2 hours, an oily substance is formed, which is the intermediate methylcarbamodithioic acid (HS2CNHCH3). Then, formaldehyde (CH2O) is added to the intermediate to form and precipitate out the dazomet .Cao, Y.; Lu, Y. Process for preparing dazomet dustless stable fine granules.
Tufa columns at Mono Lake, California Tufa is a variety of limestone formed when carbonate minerals precipitate out of ambient temperature water. Geothermally heated hot springs sometimes produce similar (but less porous) carbonate deposits, which are known as travertine. Tufa is sometimes referred to as (meteogene) travertine. It should not be confused with hot spring (thermogene) travertine.
Deep-sea vent biogeochemical cycle diagram Sound recording from a black smoker. Some hydrothermal vents form roughly cylindrical chimney structures. These form from minerals that are dissolved in the vent fluid. When the superheated water contacts the near-freezing sea water, the minerals precipitate out to form particles which add to the height of the stacks.
The cold allows for the separation of compounds by differences in their melting and precipitation points. In the cooling process, the fats and waxes with higher melting points will precipitate out and can then be removed by filtration, centrifugation, decantation, or other separation processes. A pure, liquid oil extract is left behind, ready to be further processed for consumer use.
The incoming air is forced over the mountains, causing moisture to precipitate out. This causes greater annual precipitation in this area than in the surrounding regions, and can exceed 1500 millimeters annually in some places. In addition, relative humidity can average as high as 75% on an annual basis. The region also loses more water to evapotranspiration than surrounding areas.
Stirring of a given sample of amylose is said to form fibrillar crystals which are said to precipitate out of the mother liquor. These long fibrils can be imaged using electron microscopy revealing transverse striations resembling a shish-kebab. Amylose fibrils are categorized with having one of two morphologies: ones with small rodlike fibrils and others with lath-shaped crystals.
Cold water extraction (also called CWE) is the process whereby a substance is extracted from a mixture via cold water. It is a type of fractional crystallization. The process generally involves taking a mixture of substances, dissolving them in warm water, and then rapidly cooling the mixture. The insoluble compounds precipitate out of the water, while the soluble ones stay dissolved.
Whisky is often "chill filtered": chilled to precipitate out fatty acid esters and then filtered to remove them. Most whiskies are bottled this way, unless specified as unchillfiltered or non-chill filtered. This is done primarily for cosmetic reasons. Unchillfiltered whiskies often turn cloudy when stored at cool temperatures or when cool water is added to them, and this is perfectly normal.
In polymer chemistry MALDI can be used to determine the molar mass distribution. Polymers with polydispersity greater than 1.2 are difficult to characterize with MALDI due to the signal intensity discrimination against higher mass oligomers. A good matrix for polymers is dithranol or AgTFA. The sample must first be mixed with dithranol and the AgTFA added afterwards; otherwise the sample would precipitate out of solution.
The reaction mixture is then rotary evaporated to dryness and the residue is dissolved in methanol. Undissolved cisplatin is filtered out and diethyl ether is added to the filtrate to precipitate out phenanthriplatin crystals. Phenanthriplatin is then collected by filtration, washed twice with diethyl ether before dissolving it in methanol. The drug is precipitated by adding it dropwise to a vigorously stirred solution of diethyl ether.
Oolithes spheroides Egg taphonomy is the study of the decomposition and fossilization of eggs. The processes of egg taphonomy begin when the egg either hatches or dies. Eggshell fragments are robust and can often travel great distances before burial. More complete egg specimens gradually begin to fill with sediment, which hardens as minerals precipitate out of water percolating through pores or cracks in the shell.
Calcium is a necessary ion in the formation of the mitotic spindle. Without the mitotic spindle, cellular division cannot occur. Although young leaves have a higher need for calcium, older leaves contain higher amounts of calcium because calcium is relatively immobile through the plant. It is not transported through the phloem because it can bind with other nutrient ions and precipitate out of liquid solutions.
In addition to ethane, Titan's atmosphere produces a wide range of more complex photochemical products, such as nitriles and benzene. These are believed to precipitate out and flow into Titan's seas. Radar data suggests that Ligeia Mare's seabed is likely covered in a thick layer of these organic compounds. Temperature readings from the shoreline of Ligeia Mare suggest that it is porous and highly saturated with hydrocarbons.
Permanent hardness (mineral content) is generally difficult to remove by boiling. If this occurs, it is usually caused by the presence of calcium sulfate/calcium chloride and/or magnesium sulfate/magnesium chloride in the water, which do not precipitate out as the temperature increases. Ions causing permanent hardness of water can be removed using a water softener, or ion exchange column. :permanent hardness = permanent calcium hardness + permanent magnesium hardness.
The ore deposits at the Elizabeth Mine represent classic examples of sedimentary exhalative type deposition where hydrothermal fluids enter the marine environment and precipitate out minerals in a strataform ore body. The ores are hosted in the strongly deformed Lower Devonian Guile Mountain Formation (a grey to dark grey mica schist). The ore body at the Elizabeth Mine is a massive sulfide deposit consisting primarily of pyrrhotite and chalcopyrite.
In processes that begin during fermentation and continue after bottling, these compounds bind together and aggregate. Eventually these particles reach a certain size where they are too large to stay suspended in the solution and precipitate out. The presence of visible sediment in a bottle will usually indicate a mature wine. The resulting wine, with this loss of tannins and pigment, will have a paler color and taste softer, less astringent.
Whisky can be "chill filtered": chilled to precipitate out fatty acid esters and then filtered to remove them. Most whiskies are bottled this way, unless specified as unchillfiltered or non chill filtered. Unchillfiltered whisky will often turn cloudy when stored at cool temperatures or when cool water is added to them, and this is perfectly normal. This cloudy appearance is aesthetic only and does not negatively impact the spirit.
Silver chromate is produced by the salt metathesis reaction of potassium chromate and silver nitrate in purified water - the silver chromate will precipitate out of the aqueous reaction mixture. The solubility of silver chromate is very low (Ksp = 1.1×10−12 or 6.5×10−5 mol/L). It crystallzes in the orthorhombic space group Pnma, with two distinct coordination environments for the silver ions, one tetragonal bipyramidal and the other distorted tetrahedral.
Enough oxygen had accumulated in seawater so that dissolved iron was oxidized; iron reacts with oxygen to form compounds that precipitate out - including hematite, limonite and siderite. These iron compounds precipitated from the seawater in varying proportions with chert, producing banded-iron formations. These iron formations are abundant in the Lake Superior region. The Sudbury Impact event occurred 1,850 million years ago; it is theorized that this caused the end of the banded-iron deposits.
Metal hydride for hydrogen storage applications Interstitial hydrides most commonly exist within metals or alloys. They are traditionally termed "compounds" even though they do not strictly conform to the definition of a compound, more closely resembling common alloys such as steel. In such hydrides, hydrogen can exist as either atomic or diatomic entities. Mechanical or thermal processing, such as bending, striking, or annealing, may cause the hydrogen to precipitate out of solution by degassing.
Once pore waters have permeated the surface and return to the surface, aragonite, brucite, and calcite chimneys are formed as calcium carbonates precipitate out of solution. Younger chimneys are primarily brucite and aragonite, being white and flaky in appearance. As vents mature, porosity decreases as precipitates clog fluid pathways. Mineral compositions change with aragonite succeeded by calcite and brucite being removed through dissolution, and the chimneys darken to a grey or brown color.
This is an example of Le Châtelier's principle in action: Increasing the concentration of the hydroxide ion causes more aluminium hydroxide to precipitate, which removes hydroxide from the solution. When the hydroxide concentration becomes sufficiently high the soluble aluminate, , is formed. Another common instance where precipitation occurs is when a metal cation interacts with an anionic ligand to form an electrically neutral complex. If the complex is hydrophobic, it will precipitate out of water.
The winemaking process naturally produces sediments that can precipitate out of the wine. In winemaking, clarification and stabilization are the processes by which insoluble matter suspended in the wine is removed before bottling. This matter may include dead yeast cells (lees), bacteria, tartrates, proteins, pectins, various tannins and other phenolic compounds, as well as pieces of grape skin, pulp, stems and gums.J. Robinson (ed) "The Oxford Companion to Wine" Third Edition, pp.
The solubility of proteins varies according to the ionic strength of the solution, thus according to the salt concentration. At low ion concentrations (<0.5 M), the solubility of proteins increases with increasing salt concentration, an effect termed "salting in". As the salt concentration is further increased, the solubility of the protein begins to decrease. At a sufficiently high ionic strength, the protein will precipitate out of the solution, an effect termed "salting out".
Bioaerosols introduced to the atmosphere can form clouds, which are then blown to other geographic locations and precipitate out as rain, hail, or snow. Increased levels of bioaerosols have been observed in rain forests during and after rain events. Bacteria and phytoplankton from marine environments have been linked to cloud formation. However, for this same reason, bioaerosols cannot be transported long distances in the PBL since the clouds will eventually precipitate them out.
The rare earths again precipitate out at higher pH. The precipitates are neutralised by the original sodium hydroxide solution, although most of the phosphate must first be removed to avoid precipitating rare-earth phosphates. Solvent extraction may also be used to separate out the thorium and uranium, by dissolving the resultant filter cake in nitric acid. The presence of titanium hydroxide is deleterious as it binds thorium and prevents it from dissolving fully.
The pI value can affect the solubility of a molecule at a given pH. Such molecules have minimum solubility in water or salt solutions at the pH that corresponds to their pI and often precipitate out of solution. Biological amphoteric molecules such as proteins contain both acidic and basic functional groups. Amino acids that make up proteins may be positive, negative, neutral, or polar in nature, and together give a protein its overall charge.
As a result, the solubility behavior is "reversed" so that chlorinated hydrocarbons become soluble in the water, allowing single-phase reaction of aqueous waste with a dissolved oxidizer. The reversed solubility also causes salts to precipitate out of solution, meaning they can be treated using conventional methods for solid-waste residuals. Efficient oxidation reactions occur at low temperature (400-650 °C) with reduced NOx production. SCWO can be classified as green chemistry or as a Clean Technology.
A policeman can be used for cleaning the inside of glassware, or for getting the last bit of precipitate out of a vessel. Especially in chemical laboratories it is often used to transfer residues of precipitate or solid on glass surfaces when performing the gravimetric analysis. It also used in biological laboratories, to transfer tissue culture cells from a plate to a suspension. It feature is to prevent the glass rod from scratching or breaking glassware.
One of the processes involved in petrifaction is permineralization. The fossils created through this process tend to contain a large amount of the original material of the specimen. This process occurs when groundwater containing dissolved minerals (most commonly quartz, calcite, apatite (calcium phosphate), siderite (iron carbonate), and pyrite), fills pore spaces and cavities of specimens, particularly bone, shell or wood. The pores of the organisms' tissues are filled when these minerals precipitate out of the water.
These are used in the manufacture of PVC, plastics, paper pulp and many other inorganic and organic compounds. Salt is also used as a flux in the production of aluminium. For this purpose, a layer of melted salt floats on top of the molten metal and removes iron and other metal contaminants. It is also used in the manufacture of soaps and glycerine, where it is added to the vat to precipitate out the saponified products.
When the hotter sections of the discs reach extremely high temperatures ( ), the metal can undergo a phase transformation and the carbon which is dissolved in the steel can precipitate out to form carbon-heavy carbide regions known as cementite. This iron carbide is very different from the cast iron the rest of the disc is composed of. It is extremely hard, brittle, and does not absorb heat well. After cementite is formed, the integrity of the disc is compromised.
The acids dissolve minerals like calcite out of limestone. During conditions of high watertable these dissolved minerals can enter the egg through its pores or cracks and precipitate out of solution. If enough minerals make it inside the egg can become sturdy enough to withstand the weight of the overlying sediments. When the egg is buried deeply enough, the bacteria decomposing the egg are cut off from oxygen and begin to power their metabolisms using different energy sources.
Maghemite is a polymorph of hematite (γ-) with the same chemical formula, but with a spinel structure like magnetite. Large deposits of hematite are found in banded iron formations. Gray hematite is typically found in places that can have still, standing water or mineral hot springs, such as those in Yellowstone National Park in North America. The mineral can precipitate out of water and collect in layers at the bottom of a lake, spring, or other standing water.
Those with kidney disorders, gout, rheumatoid arthritis, or certain forms of chronic vulvar pain (vulvodynia) are typically advised to avoid foods high in oxalic acid . Methods to reduce the oxalate content in food are of current interest. Magnesium (Mg2+) oxalate is 567 times more soluble than calcium oxalate, so the latter is more likely to precipitate out when magnesium levels are low and calcium and oxalate levels are high. Magnesium oxalate is a million times more soluble than mercury oxalate.
The presence of water reduces the availability of oxygen which inhibits aerobic decomposition by bacteria and fungi. Mineral-laden water flowing through the sediments may lead to permineralization, which occurs when minerals precipitate out of solution filling the interiors of cells and other empty spaces. During replacement, the plant's cell walls act as a template for mineralization. There needs to be a balance between the decay of cellulose and lignin and mineral templating for cellular detail to be preserved with fidelity.
The hydrogen combines with chloride ions dissolved in sea water, forming hydrogen chloride gas (hydrochloric acid). The rapidly rising plume of gas also carries with it fine particles of volcanic glass. The hydrochloric acid and other contaminants can precipitate out rapidly and the plume may become relatively safe a few hundred meters away, however, laze plumes have killed people who come in contact with them. The USGS has reported that, in 2000, two people were killed by exposure to laze clouds.
Cold stabilization causes tartrates to crystallize and precipitate out of the wine. As a complex chemical mixture dependent on the activity of microorganisms, wine can be unstable and reactive to changes in its environment. Once bottled, a wine may be exposed to extremes of temperature and humidity, as well as violent movement during transportation and storage. These may cause cloudiness, sedimentation and/or the formation of tartrate crystals; more seriously, they may also cause spoilage or the production of carbonic gas.
The crystal growth is the subsequent size increase of the nuclei that succeed in achieving the critical cluster size. Crystal growth is a dynamic process occurring in equilibrium where solute molecules or atoms precipitate out of solution, and dissolve back into solution. Supersaturation is one of the driving forces of crystallization, as the solubility of a species is an equilibrium process quantified by Ksp. Depending upon the conditions, either nucleation or growth may be predominant over the other, dictating crystal size.
Smokebox ; Safety valve: an automatic valve used to release excess pressure within the boiler. ; : dissolved minerals from hard water that precipitate out in the steam space around the water-level. Where this scale falls to the bottom of the boiler and mixes with other contaminants, it is termed mud. ; Scum valve: A blow-down valve mounted at the water-level of a boiler, used to blow down lighter oily or foamy deposits within a boiler that float on the water-level.
Electric showers and tankless heaters usually use from 3 to 10.5 kilowatts. Minerals present in the water supply may precipitate out of solution and form a hard scale on the heating element surface, or may fall to the bottom of the tank and clog water flow. Maintenance of water heating equipment may require periodic removal of accumulated scale and sediment. Where water supplies are known to be highly mineralized, scale production can be reduced by using low-watt-density heating elements.
These variations likely coincided with the presence of small "sub- environments" commonly found between rivers like splays, ponds or creeks. After being deposited in their final resting places the carcasses were torn apart, had their bones trampled and chewed by scavengers. These processes left the abrasion and toothmarks seen on the bones preserved at H97-02. Chemical reactions between the decaying dinosaur flesh and floodwaters caused iron to precipitate out of the water and formed the ironstone concretions commonly found in the mudrock hosting the mega-bonebed.
One of the most famous steels produced in the medieval Near East was Damascus steel used for swordmaking, and mostly produced in Damascus, Syria, in the period from 900 to 1750. This was produced using the crucible steel method, based on the earlier Indian wootz steel. This process was adopted in the Middle East using locally produced steels. The exact process remains unknown, but it allowed carbides to precipitate out as micro particles arranged in sheets or bands within the body of a blade.
Deep-sea metallic mineral deposits in the Kermadec volcanic arc are attracting research into how they are formed and how they influence the surrounding undersea biodiversity. Mineral-rich fluids coming out of seafloor hot springs contact cold sea water and precipitate out high-grade ore deposits containing gold, copper, lead, zinc, iron, manganese and other metals. In one sense, these are renewable resources because they are constantly being formed. Discovering these deposits is one matter; mining them in an economic and environmentally appropriate way is another.
The boundary between the two formed a squall line stretching from Devon, along the England–Wales border and up across Northern England to the River Tees. Thick clouds, darkened by the Sahara dust, rose to , plunging areas along the squall line into total darkness. In some areas, the lightning continued for 24 hours, and ball lightning was seen at RAF Chivenor in Devon. The dust particles served as seeds for nucleation, causing water to rapidly precipitate out and form especially large raindrops and hailstones.
The solubility of an analyte can change drastically with its overall charge; as such it is common for reduced or oxidized analyte species to precipitate out onto the electrode. This layering of analyte can insulate the electrode surface, display its own redox activity in subsequent scans, or otherwise alter the electrode surface in a way that affects the CV measurements. For this reason it is often necessary to clean the electrodes between scans. Common materials for the working electrode include glassy carbon, platinum, and gold.
Such a heat treatment produces a steel that is rather soft. If the steel is cooled quickly, however, the carbon atoms will not have time to diffuse and precipitate out as carbide, but will be trapped within the iron crystals. When rapidly cooled, a diffusionless (martensite) transformation occurs, in which the carbon atoms become trapped in solution. This causes the iron crystals to deform as the crystal structure tries to change to its low temperature state, leaving those crystals very hard but much less ductile (more brittle).
Regardless of the precise mechanism of oxidation, the oxidation of ferrous to ferric iron likely caused the iron to precipitate out as a ferric hydroxide gel. Similarly, the silica component of the banded iron formations likely precipitated as a hydrous silica gel. The conversion of iron hydroxide and silica gels to banded iron formation is an example of diagenesis, the conversion of sediments into solid rock. Banded iron formations most likely formed from sediments with nearly the same chemical composition as is found in the BIFs today.
Accumulation occurs as crystals are formed by fractional crystallisation and, if they are dense enough, precipitate out from the magma. In large, hot magma chambers having vigorous convection and settling, pseudo-sedimentary structures such as flow banding, graded bedding, scour channels, and foreset beds, can be created. The Skaergaard intrusion in Greenland is a prime example of these quasi- sedimentary structures. Whilst the dominant process of layering is fractional crystallisation, layering can also result in a magma body through assimilation of the wall rocks.
Over 90% of methane is oxidized by microbes before it reaches the surface; this activity is "one of the most important controls on greenhouse gas emissions and climate on Earth." Reduced sulfur compounds such as elemental sulfur, hydrogen sulfide (H2S) and pyrite (FeS2) are found in hydrothermal vents in basaltic crust, where they precipitate out when metal- rich fluids contact seawater. Reduced iron compounds in sediments are mainly deposited or produced by anaerobic reduction of iron oxides. The electron acceptor with the highest redox potential is oxygen.
When this ammonia leaks out of the egg it raises the surrounding pH into the alkaline and can change what minerals will precipitate out of the water. The organic material in the eggshell itself can lead to the precipitation of calcite out of solution. This often causes fossil eggshell to be covered in a thin layer of calcite that complicates the identification process. However, since eggshells are usually chiefly composed of calcite anyway the eggshell itself is mostly composed of the original calcite it had in life.
After filtering and purification the iodine is packed. : 2 HI + Cl2 → I2↑ + 2 HCl : I2 \+ 2 H2O + SO2 → 2 HI + H2SO4 : 2 HI + Cl2 → I2↓ + 2 HCl These sources ensure that Chile and Japan are the largest producers of iodine today. Alternatively, the brine may be treated with silver nitrate to precipitate out iodine as silver iodide, which is then decomposed by reaction with iron to form metallic silver and a solution of iron(II) iodide. The iodine may then be liberated by displacement with chlorine.
Crème fraîche consists of heavy cream and a starter culture. In most places in Europe, strict regulation is placed on the production of crème fraîche, prohibiting addition of any stabilizers, bulking agents, or emulsifiers. Standard crème fraîche contains around 30–45% milkfat while low-fat crème fraîche contains closer to 15% milkfat. During processing, the acidification of the casein micelle begins at around a pH of 6.7, however the pH of the cream must drop to below 4.6, the isoelectric point of milk, for the casein micelles to fully precipitate out of solution.
Graph showing the CMC Specific temperature at a specific pressure at which large groups of micelles begin to precipitate out into a quasi-separate phase. As temperature is raised above the cloud point this causes the distinct surfactant phase to form densely packed micelle groups known as aggregates. The phase separation is a reversible separation controlled by enthalpy (promotes aggregation/separation) above the cloud point, and entropy (promotes miscibility of micelles in water) below the cloud point. The cloud point is the equilibrium between the two free energies.
Negative and positive iodoform test This reaction forms the basis of the iodoform test which was commonly used in history as a chemical test to determine the presence of a methyl ketone, or a secondary alcohol oxidizable to a methyl ketone. When iodine and sodium hydroxide are used as the reagents a positive reaction gives iodoform, which is a solid at room temperature and tends to precipitate out of solution causing a distinctive cloudiness. In organic chemistry, this reaction may be used to convert a terminal methyl ketone into the analogous carboxylic acid.
Conversely, this technique can be used to determine the rate of ocean sedimentation over time. The ionium/thorium method of dating assumes that the proportion of thorium-230 to thorium-232 is a constant during the time period that the sediment layer was formed. Likewise, both thorium-230 and thorium-232 are assumed to precipitate out in a constant ratio; no chemical process favors one form over the other. It must also be assumed that the sediment does not contain any pre-existing particles of eroded rock, known as detritus, that already contain thorium isotopes.
Salting out (also known as salt-induced precipitation, salt fractionation, anti-solvent crystallization, precipitation crystallization, or drowning out) is an effect based on the electrolyte–non-electrolyte interaction, in which the non-electrolyte could be less soluble at high salt concentrations. It is used as a method of purification for proteins, as well as preventing protein denaturation due to excessively diluted samples during experiments. The salt concentration needed for the protein to precipitate out of the solution differs from protein to protein. This process is also used to concentrate dilute solutions of proteins.
Cystinuria is characterized by the inadequate reabsorption of cystine in the proximal convoluted tubules after the filtering of the amino acids by the kidney's glomeruli, thus resulting in an excessive concentration of this amino acid in the urine. Cystine may precipitate out of the urine, if the urine is neutral or acidic, and form crystals or stones in the kidneys, ureters, or bladder. It is one of several inborn errors of metabolism included in the Garrod's tetrad. The disease is attributed to deficiency in transport and metabolism of amino acids.
A practical example used very widely in areas drawing drinking water from chalk or limestone aquifers is the addition of sodium carbonate to the raw water to reduce the hardness of the water. In the water treatment process, highly soluble sodium carbonate salt is added to precipitate out sparingly soluble calcium carbonate. The very pure and finely divided precipitate of calcium carbonate that is generated is a valuable by-product used in the manufacture of toothpaste. The salting-out process used in the manufacture of soaps benefits from the common-ion effect.
They are boiled to grain (i.e. until sugar crystals precipitate out) in a vacuum pan, forming a low-grade massecuite (boiled mass) which is centrifuged, yielding a brown sugar and a liquid by-product—treacle.Heriot p 392 Black treacle (molasses) naturally contains relatively high levels of sulphite (>100ppm, expressed in sulphur dioxide equivalent). These levels are deemed safe for the majority of the population, but some allergic and respiratory reactions have been reported particularly amongst asthmatics, such that the United States Food and Drug Administration requires that levels over 10ppm, i.e.
While fossils can be found in all grain types, more detailed specimens are found in the fine grained material. A second type of burial is the non-clastic rock, form where the rock is made up of the precipitation of compacted fossil material, types of rock include limestone and coal. The third fossil bearing material is the evaporates, which precipitate out of concentrated dissolved salts to form nodular deposits, examples include rock salt and phosphate concentrations. The evaporates are usually associated with gastropod, algae, vertebrate, and trace fossils.
Due to the extensive faulting at the Rainbow massif, cold ocean seawater is able to permeate deep into the seafloor. Water circulates down a fault line, actively reacting with various sediment and rock layers until it is warmed by an underlying heat source. When warmed, it can undergo a phase transition - often resulting in dramatic changes to fluid chemistry. Super- heated vent fluids then rise and are ejected from the seafloor, where a dramatic drop in temperature from cold-water mixing can cause some fluid chemicals to precipitate out and form chimneys.
At pressure above the critical pressure a saline brine forms as the second phase. In the subsurface, gravitational forces can lead the two phases to separate. Waters circulating deep within Rainbow rise to a high enough pressure or temperature so that they react with the rock and chemical constituents are dissolved into or precipitate out of the vent fluid. Chemical concentrations in the fluid are further modified when it undergoes phase separation because volatile constituents are concentrated in the vapor rich phase and metal ions in the brine.
As oxygen levels increased in the atmosphere and oceans, the sediments changed. In the late Archean, sediments went through a transitional stage with the banded-iron formations; after this transition they demonstrate an oxygen-rich environment - shown by iron oxide-stained siltstones or mudstones called red beds. Enough oxygen had accumulated in seawater so that dissolved iron - which had earlier eroded from the surrounding land - was oxidized. Oxygenated water has low levels of dissolved iron because iron reacts with oxygen to form compounds that precipitate out; the compounds include hematite (Fe2O3), limonite (Fe2O3·2H2O) and siderite (FeCO3).
Frost flowers are complex in microstructural chemistry due to many different conditions, like air, temperature, chemical concentrations in the water, surface skim, humidity, and precipitation influencing their formation and growth. An important part of their formation is the fractionation of sodium and sulfate in respects to chloride during precipitation of the salts. When the temperature decreases brine rejection increases and the channels become more and more concentrated, especially at the surface. When the salts begin the precipitate out of the ice, it changes the relative ion concentrations available in liquid water and in the frost flowers.
Cyanide extraction of gold may be used in areas where fine gold-bearing rocks are found. Sodium cyanide solution is mixed with finely ground rock that is proven to contain gold or silver, and is then separated from the ground rock as gold cyanide or silver cyanide solution. Zinc is added to precipitate out residual zinc as well as the silver and gold metals. The zinc is removed with sulfuric acid, leaving a silver or gold sludge that is generally smelted into an ingot then shipped to a metals refinery for final processing into 99.9999% pure metals.
BIFs have alternating layers of iron oxides and chert. BIFs only form if the water is allowed to supersaturate in dissolved iron (Fe2+) meaning there cannot be free oxygen or sulfur in the water column because it would form Fe3+ (rust) or pyrite and precipitate out of solution. Following this supersaturation, the water must become oxygenated in order for the ferric rich bands to precipitate it must still be sulfur poor otherwise pyrite would form instead of Fe3+. It has been hypothesized that BIFs formed during the initial evolution of photosynthetic organisms that had phases of population growth, causing over production of oxygen.
If the concentration were to rise more quickly, the molecule would simply precipitate out of solution, resulting in disorderly granules rather than an orderly and hence usable crystal. Once a crystal is obtained, data can be collected using a beam of radiation. Although many universities that engage in crystallographic research have their own X-ray producing equipment, synchrotrons are often used as X-ray sources, because of the purer and more complete patterns such sources can generate. Synchrotron sources also have a much higher intensity of X-ray beams, so data collection takes a fraction of the time normally necessary at weaker sources.
In water systems subject to heating hardness salts can be deposited as the decomposition of bicarbonate ions creates carbonate ions that precipitate out of solution. Water with high concentrations of hardness salts can be treated with soda ash (sodium carbonate) which precipitates out the excess salts, through the common-ion effect, producing calcium carbonate of very high purity. The precipitated calcium carbonate is traditionally sold to the manufacturers of toothpaste. Several other methods of industrial and residential water treatment are claimed (without general scientific acceptance) to include the use of magnetic and/or electrical fields reducing the effects of hard water.
The availability of cholesterol at the membrane surface is dependent upon its interaction with other membrane components such as phospholipids and proteins; and the more cholesterol interacts with these components the less available it is to interact with extramembranous molecules. Some factors that affect cholesterols availability are size of the polar head groups and the ability of the phospholipid to hydrogen bond with the 3-β-OH group of cholesterol. Cholesterol associates with phospholipids, forming a stoichiometric complex and contributes to membrane fluidity. If cholesterol concentration exceeds a certain point, free cholesterol will begin to precipitate out of the membrane.
Salt harvesting in Salar de Uyuni, Bolivia, the world's largest salt flat Sailing stone in Racetrack Playa A dry lake is formed when water from rain or other sources, like intersection with a water table, flows into a dry depression in the landscape, creating a pond or lake. If the total annual evaporation rate exceeds the total annual inflow, the depression will eventually become dry again, forming a dry lake. Salts originally dissolved in the water precipitate out and are left behind, gradually building up over time. A dry lake appears as a flat bed of clay, generally encrusted with precipitated salts.
Passengers may experience fatigue, nausea, headaches, sleeplessness, and (on extended flights) even pulmonary oedema. These are the same symptoms that mountain climbers experience, but the limited duration of powered flight makes the development of pulmonary oedema unlikely. Altitude sickness may be controlled by a full pressure suit with helmet and faceplate, which completely envelops the body in a pressurized environment; however, this is impractical for commercial passengers. ; Decompression sickness : The low partial pressure of gases, principally nitrogen (N2) but including all other gases, may cause dissolved gases in the bloodstream to precipitate out, resulting in gas embolism, or bubbles in the bloodstream.
Make-up waters from ground water supplies (such as wells) are usually higher in minerals, and tend to be scaling (deposit minerals). Increasing the amount of minerals present in the water by cycling can make water less aggressive to piping; however, excessive levels of minerals can cause scaling problems. Relationship between cycles of concentration and flow rates in a cooling tower As the cycles of concentration increase, the water may not be able to hold the minerals in solution. When the solubility of these minerals have been exceeded they can precipitate out as mineral solids and cause fouling and heat exchange problems in the cooling tower or the heat exchangers.
The use of the compound itself in the laboratory is rather limited, although its formation is used to indicate the endpoint in the titration of chloride with silver nitrate in the Mohr method of argentometry. The reactivity of chromate anion with silver is lower than halides (chloride and others), so that in a mixture of both ions, only silver chloride will be formed. Only when no chloride (or any halogen) is left will silver chromate (red-brown) form and precipitate out. Prior to the endpoint the solution has a milky lemon yellow appearance, due to the color of the chromate ion and the precipitate of silver chloride already formed.
Carpathite is deposited as pale yellow flakes in cracks between diorite (an igneous rock) and argillite (a sedimentary rock); it is prized for a beautiful blue fluorescence under ultraviolet light. Other PAC compounds appearing as minerals include fluorene as kratochvilite; and anthracene as ravatite. Others are mixtures: curtisite contains several PAH compounds, including dibenzofluorine, picene, and chrysene, while the most common components of idrialite are tribenzofluorenes. One theory for their formation involves burial of PAH compounds until they reach a temperature where pyrolisis can occur, followed by hydrothermal transport towards the surface, during which the composition of minerals that precipitate out depends on the temperature.
The fully protonated acid carries no charge (charge destruction) and is less soluble in water, and may precipitate out of the water onto the anode. The analogous situation occurs in cathodic deposition except that the material being deposited will have salts of a base as the charge bearing group. If the salt of the base has been formed by protonation of the base, the protonated base will react with the hydroxyl ions being formed by electrolysis of water to yield the neutral charged base (again charge destruction) and water. The uncharged polymer is less soluble in water than it was when was charged, and precipitation onto the cathode occurs.
Thus, in primary hyperparathyroidism the quantity of calcium excreted in the urine per day is increased despite the high levels of PTH in the blood. This is because hyperparathyroidism results in hypercalcemia, which increases the urinary calcium concentration (hypercalcuria) despite the modestly increased rate of calcium re-absorption from the renal tubules caused by PTH's effect on those tubules. Kidney stones are therefore often a first indication of hyperparathyroidism, especially since the hypercalcuria is accompanied by an increase in urinary phosphate excretion (a direct result of the high plasma PTH levels). Together the calcium and phosphate tend to precipitate out as water-insoluble salts, which readily form solid “stones”.
During fermentation, these tartrates bind with the lees, pulp debris and precipitated tannins and pigments. While some variance among grape varieties and wine regions exists, generally about half of the deposits are soluble in the alcoholic mixture of wine. The crystallization of these tartrates can happen at unpredictable times, and in a wine bottle may appear like broken glass, though they are in fact harmless. Winemakers will often put the wine through cold stabilization, where it is exposed to temperatures below freezing to encourage the tartrates to crystallize and precipitate out of the wine, or electrodialysis which removes the tartrates via a membrane process.
Each holon automates one of the three system-problem archetypes that have emerged from higher math with a distinct class of solution methods, applicable as interchangeable operators. These methods operate on the input formulas and their calculations, to guide the successive approximations to the holon solution. These problem archetypes easily precipitate out of the formula collections that represent modeling of natural phenomena, and can be used as building blocks to synthesize whole computation programs as holarchies of sequential or nested holons. Used together as an alphabet these archetypal problems become a topology of higher math modeling within an algebraic programming language containing special semantic "glue" methodologies which propagate calculus "influence" through the collections of holons.
In winemaking, fining is the process where a substance (fining agent) is added to the wine to create an adsorbent, enzymatic or ionic bond with the suspended particles, producing larger molecules and larger particles that will precipitate out of the wine more readily and rapidly. Unlike filtration, which can only remove particulates (such as dead yeast cells and grape fragments), fining can remove soluble substances such as polymerized tannins, coloring phenols and proteins; some of these proteins can cause haziness in wines exposed to high temperatures after bottling. The reduction of tannin can reduce astringency in red wines intended for early drinking.J. Robinson (ed) "The Oxford Companion to Wine" Third Edition pp.
Chill filtering prevents the whisky from becoming hazy when in the bottle, when served, when chilled, or when water or ice is added, as well as precluding sedimentation from occurring in the bottles. It works by reducing the temperature sufficiently so that some fatty acids, proteins and esters (created during the distillation process) precipitate out and are caught on the filter. Single malt whiskeys are usually chilled down to 0°C, while the temperature for blended whiskey tends to be lower because they have lower levels of fatty acid. Factors affecting the chill filtering process include the temperature, number of filters used, and speed at which the whiskey is passed through the filters.
When this diffusion happens, the carbon atoms are said to be in solution in the iron, forming a particular single, homogeneous, crystalline phase called austenite. If the steel is cooled slowly, the carbon can diffuse out of the iron and it will gradually revert to its low temperature allotrope. During slow cooling, the carbon atoms will no longer be as soluble with the iron, and will be forced to precipitate out of solution, nucleating into a more concentrated form of iron carbide (Fe3C) in the spaces between the pure iron crystals. The steel then becomes heterogeneous, as it is formed of two phases, the iron-carbon phase called cementite (or carbide), and pure iron ferrite.
Methyl cellulose has a lower critical solution temperature (LCST) between 40 °C and 50 °C. At temperatures below the LCST, it is readily soluble in water; above the LCST, it is not soluble, which has a paradoxical effect that heating a saturated solution of methyl cellulose will turn it solid, because methyl cellulose will precipitate out. The temperature at which this occurs depends on DS-value, with higher DS-values giving lower solubility and lower precipitation temperatures because the polar hydroxyl groups are masked. Preparing a solution of methyl cellulose with cold water is difficult however: as the powder comes into contact with water, a gel layer forms around it, dramatically slowing the diffusion of water into the powder, hence the inside remains dry.
It was not until four years after in 1808 the same patterns were discovered by Count Alois von Beckh Widmanstätten who was heating iron meteorites when he noticed geometric patterns caused by the differing oxidation rates of kamacite and taenite. Widmanstätten told many of his colleagues about these patterns in correspondence leading to them being referred to as Widmanstätten patterns in most literature. Thomson structures or Widmanstätten patterns are created as the meteorite cools; at high temperatures both iron and nickel have face- centered lattices. When the meteorite is formed it starts out as entirely molten taenite (greater than 1500 °C) and as it cools past 723 °C the primary metastable phase of the alloy changes into taenite and kamacite begins to precipitate out.
The whiteness of tofu is ultimately determined by the soybean variety, soybean protein composition and degree of aggregation of the tofu gel network. The yellowish beige color of soybeans is due to the color compounds including anthocyanin, isoflavones and polyphenol compounds; therefore the soybean variety used will predicate the color of the final tofu product. Ways to reduce the yellow color include reducing isoflavone content by changing the pH of the soy milk solution used in the production of the tofu so that the relevant compounds precipitate out and are removed during the extraction of okara. The opacity of tofu gel and the off- white color typical of standard uncooked firm tofu is due to the scattering of light by the colloidal particles of the tofu.
Most metal species are toxic to humans at certain concentrations, therefore it is imperative to minimize metal bioavailability and mobility. Granular MgO is often blended into metals-contaminated soil or waste material, which is also commonly of a low (acidic) pH, in order to drive the pH into the 8–10 range where most metals are at their lowest solubilities. Metal-hydroxide complexes have a tendency to precipitate out of aqueous solution in the pH range of 8–10. MgO is widely regarded as the most effective metals stabilization compound when compared to Portland cement, lime, kiln dust products, power generation waste products, and various proprietary products due to MgO's superior buffering capacity, cost effectiveness, and ease/safety of handling.
The significance of this substance in the purification of compounds stems from its ability to become more so hydrated compared to relatively more nonpolar molecules and so the desirable non-polar molecules coalesce and precipitate out of the solution in a concentrated form. This method is called salting out and necessitates the use of high salt concentrations that can reliably dissolve in the aqueous mixture. The percentage of the salt used is in comparison to the maximal concentration of the salt in the mixture can dissolve. As such, although high concentrations are needed for the method to work adding an abundance of the salt, over 100%, can also oversaturate the solution, therefore, contaminating the non-polar precipitate with salt precipitate.
When solar energetic particles reach the Earth's atmosphere they cause ionisation that creates nitric oxide (NO) and other reactive nitrogen species, which then precipitate out in the form of nitrates. Since all energetic charged particles are deflected to a greater or lesser extent by the geomagnetic field, they enter preferentially at the polar latitudes; since high latitudes also contain permanent ice, it is natural to look for the nitrate signature of particle events in ice cores. A study of a Greenland ice core extending back to 1561 AD achieved resolutions of 10 or 20 samples a year, allowing in principle the detection of single events. Precise dates (within one or two years) can be achieved by counting annual layers in the cores, checked by identification of deposits associated with known volcanic eruptions.
Some small Archean evaporite deposits require that at least locally elevated concentrations (possibly due to local volcanic activity) of sulfate existed in order for them to be supersaturated and precipitate out of solution. 3.8–3.6 Ga marks the beginning of the exposed geologic record because this is the age of the oldest rocks on Earth. Metasedimentary rocks from this time still have an isotopic value of 0 because the biosphere was not developed enough (possibly at all) to fractionate sulfur. 3.5 Ga anoxyogenic photosynthesis is established and provides a weak source of sulfate to the global ocean with sulfate concentrations incredibly low the δ34S is still basically 0. Shortly after, at 3.4 Ga the first evidence for minimal fractionation in evaporitic sulfate in association with magmatically derived sulfides can be seen in the rock record.
Iron snow is crystalized particles of iron which are believed to precipitate through the outer core of some terrestrial planets and moons as that core slowly cools, much like snowflakes do on Earth. These iron crystals are more dense than the surrounding liquid, and fall back towards the planet's inner core where they remelt under pressure and combine with other elements. Here, the melting point of the iron is reduced by the presence of sulfur, and the newly-mixed sulfur and iron compounds begin to float back up towards the outer core, . Iron and sulfur which do not precipitate out will tend to be lighter than the surrounding material and are believed to collect into a solid layer at the core/ mantle boundary sometimes referred to as an anticrust.
Some of this sulfate is reduced through microbial metabolism (microbial sulfate reduction or MSR) or by hydrothermal processes, yielding sulfides, thiosulfate, and elemental sulfur. Some reduced sulfur species are buried as metal-sulfide compounds, some are cyclically reduced and oxidized in the oceans and sediments indefinitely, and some are oxidized back into sulfate minerals, which precipitate out in tidal flats, lakes, and lagoons as evaporite deposits or are incorporated into the structure of carbonate and phosphate minerals in the ocean (i.e. as CAS). Because oxidation-reduction reactions with sulfur species are often accompanied by mass-dependent fractionation, the sulfur isotope composition of the various pools of reduced and oxidized sulfur species in the water column, sediment, and rock record is a clue to how sulfur moves between those pools or has moved in the past.
But he continues to awkwardly search for vain excuses while the guests hurry to get out of the party. From this point on events precipitate out of control as everything becomes a prey to chance: Pepé, the maldextrous cavalier, gets himself caught up in a duel in order to defend Stellina, a situation which he could have easily avoided had he not asked for help from his overweening and domineering brother-in-law, the lawyer Ciro Coppa, who insists that he must challenge his adversary or be looked on as a coward. Pepé loses and ends up seriously wounded, as he will lose Stellina herself after continually begging Cirro to intervene in his favour. After the death of his wife, Ciro, in fact, marries Stellina, who has lost her patience and can no longer wait for the death of her elderly husband, himself.
However, a calc- alkaline magma is oxidized enough to precipitate significant amounts of the iron oxide magnetite, causing the iron content of the magma to remain more steady as it cools than with a tholeiitic magma. The difference between these two magma series can be seen on an AFM diagram, a ternary diagram showing the relative proportions of the oxides Na2O + K2O (A), FeO + Fe2O3 (F), and MgO (M). As magmas cool, they precipitate out significantly more iron and magnesium than alkali, causing the magmas to move towards the alkali corner as they cool. In the tholeiitic magma, magnesium-rich crystals are produced preferentially, the magnesium content of the magma plummets, causing the magma to move away from the magnesium corner until it runs low on magnesium and simply moves towards the alkali corner as it loses iron and any remaining magnesium.
Green Lake in particular has been the subject of a great deal of limnological research. The lakes are meromictic both because of their depth (relative to their diameters) and because there is an influx of mineral-laden groundwater into them; to some extent the lakes are giant mineral springs. The mineral content also accounts for the lakes' greenish appearance at certain times of year, when small particles of calcium carbonate and other minerals precipitate out of the water; these "whitings" cause the white coating of the lake bottoms that is readily observable at the shoreline. left In addition to the strictly limnological research on the lakes, the sediments at their bottoms are being used to explore the history of the plant and animal life and of the climate around the lake over the last several thousand years (i.e.
Moreover, below this temperature almost no Si is deposited on the growth surface. However, Au particles can form Au-Si eutectic droplets at temperatures above 363 °C and adsorb Si from the vapor state (because Au can form a solid-solution with all Si concentrations up to 100%) until reaching a supersaturated state of Si in Au. Furthermore, nanosized Au-Si droplets have much lower melting points (ref) because the surface area-to-volume ratio is increasing, becoming energetically unfavorable, and nanometer-sized particles act to minimize their surface energy by forming droplets (spheres or half-spheres). #Si has a much higher melting point (~1414 °C) than that of the eutectic alloy, therefore Si atoms precipitate out of the supersaturated liquid-alloy droplet at the liquid- alloy/solid-Si interface, and the droplet rises from the surface. This process is illustrated in figure 1.
Apart from the intrinsic "prompt effects" of nuclear detonations, that of thermal flash, blast and initial radiation releases, if any part of the fireball of the nuclear detonation contacts the ground, in what is known as a surface burst, another, comparatively slowly increasing, radiation hazard will also begin to form in the immediate area. Putting aside the possibility of the detonation occurring during an already established heavy rain-storm, the formation of this life-threatening "delayed nuclear radiation" manifests only when the altitude, or "height of burst" of the explosion, is such that both the fireball and the buoyant updrafts it creates, sufficiently heats and lifts the soil that was below it into the core of the mushroom cloud. Once there, the very hot radioactive isotope products of the nuclear reactions that produced the explosion, begin to coalesce with the cooler and denser soil. Upon cooling, this mixture begins to locally fall-out or precipitate-out of the mushroom cloud, falling back to the surface of the earth, near to the point of detonation, over the next few minutes and hours.

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