Sentences Generator
And
Your saved sentences

No sentences have been saved yet

"methyl methacrylate" Definitions
  1. a volatile flammable liquid C5H8O2 that polymerizes readily and is used especially as a monomer for resins

137 Sentences With "methyl methacrylate"

How to use methyl methacrylate in a sentence? Find typical usage patterns (collocations)/phrases/context for "methyl methacrylate" and check conjugation/comparative form for "methyl methacrylate". Mastering all the usages of "methyl methacrylate" from sentence examples published by news publications.

And poly(methyl methacrylate), known as Plexiglas, substituted for glass in aircraft windows.
The fine, silvery powder is made from a polymer called PMMA (poly-methyl methacrylate), which you might know better in its acrylic glass form, Plexiglas.
The FDA first warned consumers about methyl methacrylate in the 70's, and most professional societies and cosmetology schools now advise techs to only use the much safer ethyl methacrylate.
In the bad old days, fake nails were often made out of methyl methacrylate, or MMA, more commonly used for making tooth crowns and cementing hip and knee replacements to bone.
Inspired by his sister, who is a pediatric dentist, Turner adopted the same kind of UV-cured resin used for teeth fillings, and combined it with methyl methacrylate, an ultra tough resin developed in Europe as an alternative to paint to use for road markings.
Emissions from the plant included methyl methacrylate and vinyl fluoride.
Methyl methacrylate is the monomer from which many polymethacrylates are made.
Methyl methacrylate (MMA) is an organic compound with the formula CH2=C(CH3)COOCH3. This colorless liquid, the methyl ester of methacrylic acid (MAA), is a monomer produced on a large scale for the production of poly(methyl methacrylate) (PMMA).
Stonhard manufactures and installs seamless epoxy, polyurethane and methyl methacrylate flooring products for industrial and commercial environments.
Initial lab work was conducted on spalting in the 1980s at Brigham Young University. A method for improving machinability in spalted wood using methyl methacrylate was developed in 1982,Christensen, K.W. (1982). Improving the Working Properties of Spalted Woods Through Impregnation with Methyl Methacrylate. Thesis: Brigham Young University.
One of the most commonly used stabilizing methods utilizes a heat cured polymer known as methyl methacrylate (MMA).
MNP is also an efficient regulator of the radical polymerization of methyl methacrylate through the 'pseudoliving' chain mechanism.
Acrylic can be a chemical irritant or allergen, resulting in Acrylic monomer dermatitis from the decomposition of methyl methacrylate.
Methacrylamide is an industrial chemical used in the production of polymers and copolymers. Methacrylamide is a precursor of methyl methacrylate.
EGDMA can be used in free radical copolymer crosslinking reactions. When used with methyl methacrylate, it leads to gel point at relatively low concentrations because of the nearly equivalent reactivities of all the double bonds involved. It is used as a monomer to prepare Hydroxyapatite/Poly methyl methacrylate composites. EGDMA can be used in free radical copolymer crosslinking reactions.
In 2008, spherical amphiphilic Janus nanoparticles, having one polystyrene and one poly(methyl methacrylate) side, were shown to be effective as compatibilizing agents of multigram scale compatibilization of two immiscible polymer blends, polystyrene and poly(methyl methacrylate). The Janus nanoparticles oriented themselves at the interface of the two polymer phases, even under high temperature and shear conditions, allowing the formation of much smaller domains of poly(methyl methacrylate) in a polystyrene phase. The performance of the Janus nanoparticles as compatibilizing agents was significantly superior to other state-of-the-art compatibilizers, such as linear block copolymers.
Other polymers, including poly(methyl methacrylate) and polyacetal(polyoxymethylene), are not as brittle as "brittle polymers" and are also not as ductile as "ductile polymers".
About a third of the world's acetone is used as a solvent, and a quarter is consumed as acetone cyanohydrin, a precursor to methyl methacrylate.
Maleic acid is also used as an adhesion promoter for different substrates, such as nylon and zinc coated metals e.g galvanized steel, in methyl methacrylate based adhesives.
Condensation of Methyl propionate with formaldehyde followed by dehydration yields methyl methacrylate: :MeO2CCH2CH3 \+ CH2O → MeO2CCH(CH2OH)CH3 :MeO2CCH(CH2OH)CH3 → MeO2CC(=CH2)CH3 Methyl propionate is used as a solvent for cellulose nitrate and lacquers, and as a raw material for the production of paints, varnishes and other chemicals such as methyl methacrylate. Due to its fruity smell and taste, it is also used in fragrances and flavoring.
Due to the war, contact lenses were unavailable to be shipped from Germany. During this time plastics such as methyl methacrylate were coming into the marketplace. Methyl methacrylate was used mostly in the windshields of fighter planes. Doctors were finding that when the windshields broke, and the plastic flew into the pilot's eyes, their eyes did not react the same way an eye usually did to a foreign body.
Today there are primarily seven commodity polymers in use: polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate (PET, PETE), polystyrene, polycarbonate, and poly(methyl methacrylate) (Plexiglas). These make up nearly 98% of all polymers and plastics encountered in daily life. Each of these polymers has its own characteristic modes of degradation and resistances to heat, light and chemicals. Polyethylene, polypropylene, and poly(methyl methacrylate) are sensitive to oxidation and UV radiation, (Russian translation is available).
116, 12823-12864 (2016). Laser dyes are also used to dope solid-state matrices, such as poly(methyl methacrylate) (PMMA), and ORMOSILs, to provide gain media for solid state dye lasers.
For example, methyl methacrylate (MMA) can be polymerized to produce Poly(methyl methacrylate) (PMMA - Plexiglas or Perspex) via a repeating series of radical addition steps: :Radical intermediates in the formation of polymethacrylate (plexiglas or perspex). Newer radical polymerization methods are known as living radical polymerization. Variants include reversible addition-fragmentation chain transfer (RAFT) and atom transfer radical polymerization (ATRP). Being a prevalent radical, O2 reacts with many organic compounds to generate radicals together with the hydroperoxide radical.
This is because methyl methacrylate is proved to be an inert substance like glass, and did not create a rejection response from the eyes. Using methyl methacrylate, the partners pioneered a new type of contact lens. Wesley and Jessen worked to develop the plastic lenses known as the rigid corneal contact lens. The corneal lens fit floated on the cornea, unlike its scleral predecessor, which rested on the sclera or white of the eye and bridged the cornea.
The waka taua Te Tuhono in the National Museum of Scotland was restored and partially reconstructed by the Māori craftsman George Nuku, using carved poly(methyl methacrylate) (PMMA) to recreate missing sections.
Methacrylates are derivatives of methacrylic acid. These derivatives include the parent acid (CH2C(CH3)CO2H), salts (e.g., Na+), esters (e.g. CH2C(CH3)CO2CH3, or methyl methacrylate) and the polymers of these species.
Initially different blends and copolymers of PVDF were discovered, such as a polyvinylidene fluoride with poly(methyl methacrylate). Other structures were discovered to possess ferroelectric properties, such as polytrifluoroethylene and odd- numbered nylon.
Due to its aforementioned biocompatibility, Poly(methyl methacrylate) is a commonly used material in modern dentistry, particularly in the fabrication of dental prosthetics, artificial teeth, and orthodontic appliances. ; Acrylic prosthetic construction: Pre-polymerized, powdered PMMA spheres are mixed with a Methyl Methacrylate liquid monomer, Benzoyl Peroxide (initiator), and NN-Dimethyl-P-Toluidine (accelerator), and placed under heat and pressure to produce a hardened polymerized PMMA structure. Through the use of injection molding techniques, wax based designs with artificial teeth set in predetermined positions built on gypsum stone models of patients' mouths can be converted into functional prosthetics used to replace missing dentition. PMMA polymer and methyl methacrylate monomer mix is then injected into a flask containing a gypsum mold of the previously designed prosthesis, and placed under heat to initiate polymerization process.
Thermoplastic polymers include polyethylene, teflon, polystyrene, polypropylene, polyester, polyurethane, Poly(methyl methacrylate), polyvinyl chloride, nylons, and rayon. Thermoset plastics include vulcanized rubber, bakelite, Kevlar, and polyepoxide. Almost all synthetic polymers are derived from petrochemicals.
The principal application, consuming approximately 75% of the MMA, is the manufacture of polymethyl methacrylate acrylic plastics (PMMA). Methyl methacrylate is also used for the production of the co-polymer methyl methacrylate-butadiene-styrene (MBS), used as a modifier for PVC. Another application is as cement used in total hip replacements as well as total knee replacements. Used as the "grout" by orthopedic surgeons to make the bone inserts fix into bone, it greatly reduces post-operative pain from the insertions but has a finite lifespan.
A possible sequence of repeat units A and B in a triblock copolymer might be ~A-A-A-A-A-A-A-B-B-B-B-B-B-B-A-A-A-A-A~.Cowie, p.4 Block copolymers are made up of blocks of different polymerized monomers. For example, polystyrene-b- poly(methyl methacrylate) or PS-b-PMMA (where b = block) is usually made by first polymerizing styrene, and then subsequently polymerizing methyl methacrylate (MMA) from the reactive end of the polystyrene chains.
Stonhard, Inc. is an American-based multi-national company specializing in manufacturing and installing high-performance epoxy, polyurethane and methyl methacrylate floor, wall and lining systems. It is an industrial brand of RPM International. Stonhard, Inc.
Methyl propionate ester is a precursor to methyl methacrylate, which is used in plastics and adhesives.Scott D. Barnicki "Synthetic Organic Chemicals" in Handbook of Industrial Chemistry and Biotechnology edited by James A. Kent, New York : Springer, 2012. 12th ed. .
The polymer of methyl acrylate, PMA or poly(methyl acrylate), is similar to poly(methyl methacrylate), except for the lack of methyl groups on the backbone carbon chain.Polymethyl acrylate and polyethyl acrylate, Encyclopædia Britannica . Encyclopædia Britannica. Retrieved 2012-05-09.
Photopolymerization of methyl methacrylate monomers under UV that resulting into polymer Photodecomposing photoresist is a type of photoresist that generates hydrophilic products under light. Photodecomposing photoresists are usually used for positive photoresist. A typical example is azide quinone, e.g. diazonaphthaquinone (DQ).
Curettage is performed on some patients, and is sufficient for inactive lesions. The recurrence rate with curettage is significant in active lesions, and marginal resection has been advised. Liquid nitrogen, phenol, methyl methacrylate are considered for use to kill cells at margins of resected cyst.
Sneeze guards are advertised under many different materials. Most companies will sell sneeze guards made of clear acrylic plastic. Acrylic is more well known under its commercial name Plexiglas is made of Poly(methyl methacrylate). This material is sold under a variety of names.
Testing small portions of the frame may be necessary to determine which method is best used to clean the frame. Possible materials used for cleaning include tri-ammonium citrate, Plextol B500, ethyl acrylate, EA, methyl methacrylate, and MMA. A carver reproduces the missing ornamentation on a frame.
A possible synthesis of umbellulone is given by the following process. Diazomethyl isopropyl ketone reacts with methyl methacrylate to give 1-carbo-methoxy-2-isobutyryl-1-methylcyclopropane. This reaction gives a yield of 35%. This is then hydrolyzed to a mixture of cis and trans 2-isobutyryl-1-methyl-1-cyclopropane.
Inorganic particulate film/poly(methyl methacrylate) (PMMA)/inorganic particulate film trilayer separators are prepared by dip-coating inorganic particle layers on both sides of PMMA thin films. This inorganic trilayer membrane is believed to be an inexpensive, novel separator for application in lithium-ion batteries from increased dimensional and thermal stability.
In 1909, Leo Hendrik Baekeland invented bakelite made from phenol and formaldehyde. In 1928 synthetic fuels invented using Fischer-Tropsch process. In 1929, Walter Bock invented synthetic rubber Buna-S which is made up of styrene and butadiene and used to make car tires. In 1933, Otto Röhm polymerized the first acrylic glass methyl methacrylate.
Her use and juxtaposition of apparently incongruous materials: bone china, porcelain, Poly(methyl)methacrylate , fine wire, stainless steel, and paper create tension within the harmony of the pattern. In addition to international awards and plaudits, Babuniak has a following of private and public collectors and publications about her work have appeared in many countries.
The addition of WS2 nanotubes to epoxy resin improved adhesion, fracture toughness and strain energy release rate. The wear of the nanotubes-reinforced epoxy is lower than that of pure epoxy. WS2 nanotubes were embedded into a poly(methyl methacrylate) (PMMA) nanofiber matrix via electrospinning. The nanotubes were well dispersed and aligned along fiber axis.
The first acrylic acid was created in 1843. Methacrylic acid, derived from acrylic acid, was formulated in 1865. The reaction between methacrylic acid and methanol results in the ester methyl methacrylate. Polymethyl methacrylate was discovered in the early 1930s by British chemists Rowland Hill and John Crawford at Imperial Chemical Industries (ICI) in the United Kingdom.
Skeletal structure of methyl methacrylate, the constituent monomer of PMMA Pieces of perspex, the windscreen of a German plane shot down during World War II PMMA is a strong, tough, and lightweight material. It has a density of 1.17–1.20 g/cm3, which is less than half that of glass.Polymethylmethacrylate (PMMA, Acrylic) . Makeitfrom.com. Retrieved 2015-03-23.
Zhong S, Huang GJ, Susarla SM, Swanson EW, Huang J, Gordon CR. Quantitative analysis of dual-purpose, patient-specific craniofacial implants for correction of temporal deformity. Neurosurgery. 2015 Jun;11 Suppl 2:220-9; discussion 229. doi: 10.1227/NEU.0000000000000679. Gordon CR, Yaremchuk MJ. Temporal augmentation with methyl methacrylate. Aesthet Surg J. 2011 Sep;31(7):827-33.
Based on the chemical structure of photoresists, they can be classified into three types: photopolymeric, photodecomposing, photocrosslinking photoresist. Photopolymeric photoresist is a type of photoresist, usually allyl monomer, which could generate free radical when exposed to light, then initiates the photopolymerization of monomer to produce a polymer. Photopolymeric photoresists are usually used for negative photoresist, e.g. methyl methacrylate.
For thermosetting plastics that require only one monomer, the monomer compound is the "resin". For example, liquid methyl methacrylate is often called the "resin" or "casting resin" while in the liquid state, before it polymerizes and "sets". After setting, the resulting PMMA is often renamed acrylic glass, or "acrylic". (This is the same material called Plexiglas and Lucite).
Lichtenberg figure: high voltage dielectric breakdown in an acrylic polymer block Poly(methyl methacrylate) (PMMA), also known as acrylic, or acrylic glass, as well as by the trade names Crylux, Plexiglas acrylic, Acrylite, Astariglas, Lucite, Perclax, and Perspex, among several others (see below), is a transparent thermoplastic often used in sheet form as a lightweight or shatter-resistant alternative to glass. The same material can be used as a casting resin or in inks and coatings, among many other uses. Although not a type of familiar silica-based glass, the substance, like many thermoplastics, is often technically classified as a type of glass (in that it is a non- crystalline vitreous substance) hence its occasional historic designation as acrylic glass. Chemically, it is the synthetic polymer of methyl methacrylate.
There are a few commodity plastics that have emerged as suitable for medical microfluidic applications. These include poly(methyl methacrylate)(PMMA), polystyrene, polycarbonate, and a variety of cyclic polyolefin materials. PMMA has good optical properties for fluorescence, and UV detection modes are relatively easy to seal to themselves. These are available in grades suitable for both injection and compression molding.
These turbines (or rotors) come in a variety of diameters (outside diameter), from 0.70–15.0 mm, and are usually spun on air or nitrogen gas. The rotors are made from a number of different materials such as ceramics e.g. zirconia, silicon nitride or polymers such as poly(methyl methacrylate) (PMMA), polyoxymethylene (POM). The cylindrical rotors are axially symmetric about the axis of rotation.
Diphenyl diselenide and several benzylic selenides have been explored by Kwon et al. as photoiniferters in polymerization of styrene and methyl methacrylate. Their mechanism of control over polymerization is proposed to be similar to the dithiuram disulfide iniferters. However, their low transfer constants allow them to be used for block copolymer synthesis but give limited control over the molecular weight distribution.
Diphenyl diselenide and several benzylic selenides have been explored by Kwon et al. as photoiniferters in polymerization of styrene and methyl methacrylate. Their mechanism of control over polymerization is proposed to be similar to the dithiuram disulfide iniferters. However, their low transfer constants allow them to be used for block copolymer synthesis but give limited control over the molecular weight distribution.
The glass- transition temperature Tg of a material characterizes the range of temperatures over which this glass transition occurs. It is always lower than the melting temperature, Tm, of the crystalline state of the material, if one exists. Hard plastics like polystyrene and poly(methyl methacrylate) are used well below their glass transition temperatures, i.e., when they are in their glassy state.
Scheme 1. Homolytic cleavage of poly(methyl methacrylate) (PMMA). Polymers have been observed to undergo homolytic bond cleavage through the use of radical reporters such as DPPH (2,2-diphenyl-1-picrylhydrazyl) and PMNB (pentamethylnitrosobenzene.) When a bond is cleaved homolytically, two radical species are formed that can recombine to repair damage or can initiate other homolytic cleavages which can in turn lead to more damage.
Solid-state dye lasers (SSDL) were introduced in 1967 by Soffer and McFarland. In these solid-state lasers, the gain medium is a laser dye-doped organic matrix such as poly(methyl methacrylate) (PMMA), rather than a liquid solution of the dye. An example is rhodamine 6G-doped PMMA. These lasers are also referred to as solid-state organic lasers and solid-state dye-doped polymer lasers.
Poly(methyl methacrylate) (PMMA), also known as acrylic or acrylic glass as well as by the trade names Plexiglas, Acrylite, Lucite, and Perspex among several others (see below), is a transparent thermoplastic often used in sheet form as a lightweight or shatter-resistant alternative to glass. The same material can be utilised as a casting resin, in inks and coatings, and has many other uses.
Lower-power fluorescent lamps and LEDs can be used for static applications. Small high-pressure lamps can have light focused and transmitted to the work area via liquid-filled or fiber-optic light guides. The impact of UV on polymers is used for modification of the (roughness and hydrophobicity) of polymer surfaces. For example, a poly(methyl methacrylate) surface can be smoothed by vacuum ultraviolet.
ICI registered the product under the trademark Perspex. About the same time, chemist and industrialist Otto Röhm of Rohm and Haas AG in Germany attempted to produce safety glass by polymerizing methyl methacrylate between two layers of glass. The polymer separated from the glass as a clear plastic sheet, which Röhm gave the trademarked name Plexiglas acrylic in 1933. Both Perspex and Plexiglas acrylic were commercialized in the late 1930s.
The glass transition temperature (Tg) of atactic PMMA is . The Tg values of commercial grades of PMMA range from ; the range is so wide because of the vast number of commercial compositions which are copolymers with co-monomers other than methyl methacrylate. PMMA is thus an organic glass at room temperature; i.e., it is below its Tg. The forming temperature starts at the glass transition temperature and goes up from there.
In the past, heterogeneous gold catalysts have found commercial applications for the industrial production of polyvinyl chloride (PVC), methyl methacrylate, and catalytic converters. Traditionally, PVC production uses mercury catalysts and leads to serious environmental concerns. China accounts for 50% of world's mercury emissions and 60% of China's mercury emission is caused by PVC production. Although gold catalysts are slightly expensive, overall production cost is affected by only ~1%.
Elimination of moving parts increased performance reliability and minimized maintenance. The mask is composed of a poly(methyl methacrylate) (commercially known as Lucite) block, about the size of a pack of cards, with machined channels and a cemented or screwed-in cover plate. The reduction of moving parts cut manufacturing costs and increased durability. The bistable fluid amplifier design allowed the respirator to function as both a respiratory assistor and controller.
Provisional bridges can either be made of acrylic resins or metal. The resins are the most commonly used, they are either made of cellulose acetate, polycarbonate or poly-methyl methacrylate. Other chemically activated resins include poly-R methacrylates: these are methacrylates with ethyl or isobutyl substances added to increase the strength of material. Also, commonly used resins include the BisGMA based dimethacrylate, and the visible light urethane di-methylacrylate.
The resins for the water-based paints are polyvinyl acetate latex, methyl methacrylate or acrylic resin. The resins for solvent- based paints are linseed or soya oils and alkyd resins. The pigments and resins are mixed with water for water-based paints and solvents for solvent- based paints so that they can be applied onto the road surface. Solvents that are use can be naphtha, toluene, methanol, methylene chloride, and acetone.
In fact the sulfate ester of the amide is initially produced as an adduct with sulfuric acid ((CH3)2C(OSO3H)C(O)NH2. H2SO4), which is removed in a cracking step. The sulfate ester is then methanolyzed (reacted with methanol): :(CH3)2C(OSO3H)C(O)NH2 \+ CH3OH → CH2 =C(CH3)C(O)OCH3 \+ NH4HSO4 As indicated in the last reaction, each kilogram of methyl methacrylate produced yields roughly 1.1 kg of ammonium hydrogen sulfate.
The drawback of this polymer is that if it has high flexibility and toughness, then it will not be strong and rigid. This makes it non-ideal for any situation in which a strong, rigid container is desired. An example of this would be transparent barriers, such as those made of plexiglass (Poly(methyl methacrylate)), a transparent glass substitute. PBAT is fully biodegradable when composted due to the presence of butylene adipate groups.
Unsaturated monomers are those having carbon–carbon double bonds. In general, the term "unsaturated" refers to the presence of one or more double (or triple) bonds and the ability to "saturate" the molecule by addition of H2. Some examples of unsaturated monomers include: acrylic acid, acrylamide, acryloyl chloride, and methyl methacrylate. Research suggests that unsaturated monomers that are coordinatively complexed together may be important in the process of enantioselective cyclopropanation of synthetic fibers.
Demand for plastic resins in Europe during 2017 as a percentage of total plastic demand. Commodity plastics are plastics produced in high volumes for applications where exceptional material properties are not needed (such as packaging, food containers, and household products). In contrast to engineering plastics, commodity plastics tend to be inexpensive to produce and exhibit relatively weak mechanical properties. Some examples of commodity plastics are polyethylene, polypropylene, polystyrene, polyvinyl chloride, and poly(methyl methacrylate).
Copolymers, due to their unique tunability of properties, can have a wide range of applications. One example (of many) is nano-scale lithography using block copolymers. One used frequently is a block copolymer made of polystyrene and poly(methyl methacrylate) (abbreviated PS-b- PMMA). This copolymer, upon proper thermal and processing conditions, can form cylinders on the order of a few tens of nanometers in diameter of PMMA, surrounded by a PS matrix.
While bacterial infections are common concerns in the medical, dental, and food industries, they are the primary cause of device failures in biological implants. To combat this issue, BSM has been used as a coating for a poly(acrylic acid-b-methyl methacrylate) (PAA-b- PMMA) diblock copolymer. The copolymer provides two mechanisms that contribute to the bacterial resistance of the biomaterial. First, the PAA block assists the adsorption of BSM to the surface.
For implanting a poly(methyl methacrylate) (PMMA) IOL, the incision has to be enlarged. For implanting a foldable IOL, the incision does not have to be enlarged. The foldable IOL, made of silicone or acrylic of appropriate power is folded either using a holder/folder, or a proprietary insertion device provided along with the IOL. It is then inserted and placed in the posterior chamber in the capsular bag (in-the-bag implantation).
A choice for new roofs and roof refurbishment. This type of a roof membrane is generally referred to as Liquid Roofing and involves the application of a cold liquid roof coating. No open flames or other heat sources are needed and the glass fiber reinforced systems provide seamless waterproofing around roof protrusions and details. Systems are based on flexible thermoset resin systems such as polyester and polyurethane, and poly-methyl-methacrylate (PMMA).
Benzoyl peroxide is also used as a radical initiator to induce chain-growth polymerization reactions, such as for polyester and poly(methyl methacrylate) (PMMA) resins and dental cements and restoratives. It is the most important among the various organic peroxides used for this purpose, a relatively safe alternative to the much more hazardous methyl ethyl ketone peroxide. It is also used in rubber curing and as a finishing agent for some acetate yarns.
Its dominant use is as an antioxidant. 2,6-di-tert-butylphenol is a precursor to more complex compounds used as antioxidants and light-protection agents for the stabilization for polymers. Of particular note is methyl-3-(3,5-di-tert- butyl-4-hydroxyphenyl)-propionate (CAS# 6386-38-5), which is formed by the Michael addition of methyl methacrylate. This compound is used as a feedstock in the synthesis of more complex antioxidants such as Irganox 1098.
The fifth generation Espace was preceded by the Initiale Paris concept car, which is similar to the production version. The concept was unveiled in September 2013 at the Frankfurt Motor Show and it has a mid-size luxury crossover SUV like design and various luxury elements, previewing also the new Renault's Initiale Paris luxury sub marque. The car incorporates an aluminium-poly(methyl methacrylate) roof, which has a map of Paris. The engine is a 1.6 litre diesel unit.
The risk of bacterial infections in performing cranioplasty ranges from 5 to 12.8%. Multiple factors are affecting the risk of infection, one being the materials used for the operation. Using titanium, whether being custom-made or using a mesh, is associated with a lower infection rate; on the other hand, materials such as methyl methacrylate and autologous bone is associated with a higher infection rate. Another risk factor for bacterial infection is the location of the operation.
Sulfonyl iodides, having the general formula RSO2I, are quite light-sensitive. Perfluoroalkanesulfonyl iodides, prepared by reaction between silver perfluoroalkanesulfinates and iodine in dichloromethane at −30 °C, react with alkenes to form the normal adducts, RFSO2CH2CHIR and the adducts resulting from loss of SO2, RFCH2CHIR. Arenesulfonyl iodides, prepared from reaction of arenesulfinates or arenehydrazides with iodine, can be used as initiators to facilitate the synthesis of poly(methyl methacrylate) containing C–I, C–Br and C–Cl chain ends.
Many structures can be formed using the most common, rapid prototyping technology, soft lithography with polydimethylsiloxane(PDMS). PDMS is an inexpensive, clear elastomeric polymer with rubbery mechanical properties at room temperature. In the laboratory, PDMS is mixed in small batches, poured onto moulds, for example, poly(methyl methacrylate)(PMMA), with microscale features, and cured at moderate temperatures for minutes to hours. Open PDMS channels are closed by adhering the channel bearing component to a glass slide or a second, flat piece of PDMS.
Caesium chloride powder Relatively few chemical applications use caesium. Doping with caesium compounds enhances the effectiveness of several metal-ion catalysts for chemical synthesis, such as acrylic acid, anthraquinone, ethylene oxide, methanol, phthalic anhydride, styrene, methyl methacrylate monomers, and various olefins. It is also used in the catalytic conversion of sulfur dioxide into sulfur trioxide in the production of sulfuric acid. Caesium fluoride enjoys a niche use in organic chemistry as a base and as an anhydrous source of fluoride ion.
A Futuro at Espoo Museum of Modern Art, Finland A Futuro house, or Futuro Pod, is a round, prefabricated house designed by Finnish architect Matti Suuronen, of which fewer than 100 were built during the late 1960s and early 1970s. The shape, reminiscent of a flying saucer, and the structure's airplane hatch entrance has made the houses sought after by collectors. The Futuro is composed of fiberglass-reinforced polyester plastic, polyester-polyurethane, and poly(methyl methacrylate), measuring high and in diameter.
About 6.7 million tonnes were produced worldwide in 2010, mainly for use as a solvent and production of methyl methacrylate and bisphenol A.Acetone, World Petrochemicals report, January 2010fStylianos Sifniades, Alan B. Levy, "Acetone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. It is a common building block in organic chemistry. Familiar household uses of acetone are as the active ingredient in nail polish remover and as paint thinner. It has volatile organic compound (VOC) exempt status in the United States.
Synthetic casting "resin" for embedding display objects in Plexiglas/Lucite (PMMA) is simply methyl methacrylate liquid, into which a polymerization catalyst is added and mixed, causing it to "set" (polymerize). The polymerization creates a block of PMMA plastic ("acrylic glass") which holds the display object in a transparent block. Another synthetic polymer, sometimes called by the same general category, is acetal resin. By contrast with the other synthetics, however, it has a simple chain structure with the repeat unit of form −[CH2O]−.
Course of a redox-initiated methyl methacrylate substance polymerization with clearly visible Trommsdorff-Norrish-effect / autoacceleration Autoacceleration (gel effect, Trommsdorff–Norrish effect) is a dangerous reaction behavior that can occur in free-radical polymerization systems. It is due to the localized increases in viscosity of the polymerizing system that slow termination reactions. The removal of reaction obstacles therefore causes a rapid increase in the overall rate of reaction, leading to possible reaction runaway and altering the characteristics of the polymers produced.Alger, Mark.
HCN is the precursor to sodium cyanide and potassium cyanide, which are used mainly in gold and silver mining and for the electroplating of those metals. Via the intermediacy of cyanohydrins, a variety of useful organic compounds are prepared from HCN including the monomer methyl methacrylate, from acetone, the amino acid methionine, via the Strecker synthesis, and the chelating agents EDTA and NTA. Via the hydrocyanation process, HCN is added to butadiene to give adiponitrile, a precursor to Nylon-6,6.
Representative types of artificial cell membranes. Membranes for artificial cells be made of simple polymers, crosslinked proteins, lipid membranes or polymer-lipid complexes. Further, membranes can be engineered to present surface proteins such as albumin, antigens, Na/K-ATPase carriers, or pores such as ion channels. Commonly used materials for the production of membranes include hydrogel polymers such as alginate, cellulose and thermoplastic polymers such as hydroxyethyl methacrylate-methyl methacrylate (HEMA- MMA), polyacrylonitrile-polyvinyl chloride (PAN-PVC), as well as variations of the above-mentioned.
Ethyl methacrylate can be used for artificial nails and can cause contact dermatitis, asthma, and allergies in the eyes and nose. Nail salon workers also face exposure to other chemicals used, such as toluene, dibutyl phthalate, and formaldehyde. The products used to make acrylic nails may also be flammable. Exposure to methyl methacrylate (the precursor to acrylic glass) can cause drowsiness, light-headedness, and trembling of the hands, and so it has been banned for use in cosmetology in the majority of US states.
Cell casting is a method used for creating poly(methyl methacrylate) (PMMA) sheets. Liquid monomer is poured between two flat sheets of toughened glass sealed with a rubber gasket and heated for polymerization. Because the glass sheets may contain surface scratches or sag during the process, this traditional method has some disadvantages: among other problems, the PMMA sheets may contain variations in thickness and surface defects. It has since been replaced by the more modern method for making PMMA, extrusion, which gives uniform quality.
BVS was first developed by C. P. Chen and R. S. Lakes in 1989 in order to address the shortcomings of existing laboratory techniques for studying viscoelastic materials. It was later refined by M. Brodt et al. to improve the rigidity and resolution of the apparatus, which were sources of error in the original design. First used to study poly(methyl methacrylate) (PMMA), it has since seen applications in determining the properties of bone, capacitor dielectrics, high damping metals, and other such viscoelastic materials.
Using ultra-fine full-vulcanized powdered rubber (UFPR) researchers have been able to improve all three, toughness, stiffness, and heat resistance simultaneously, resetting the stage for rubber toughening with particles smaller than previously thought to be effective. In applications where high optical transparency is necessary, examples being poly(methyl methacrylate) and polycarbonate it is important to find a secondary phase that does not scatter light. To do so it is important to match refractive indices of both phases. Traditional rubber particles do not offer this quality.
Hydroquinone has a variety of uses principally associated with its action as a reducing agent that is soluble in water. It is a major component in most black and white photographic developers for film and paper where, with the compound metol, it reduces silver halides to elemental silver. There are various other uses associated with its reducing power. As a polymerisation inhibitor, exploiting its antioxidant properties, hydroquinone prevents polymerization of acrylic acid, methyl methacrylate, cyanoacrylate, and other monomers that are susceptible to radical-initiated polymerization.
However, at Jiangsu Co- Innovation Center for Efficient Processing and Utilization of Forest Resources, Wang and his colleagues recently developed a new production method of infiltrating a prepolymerized methyl methacrylate (MMA) solution into delignified wood fibers. By utilizing this groundbreaking strategy, large-size transparent wood with any thickness or any measure can be easily made. Yet in spite of this success in the manufacture, challenges still exist with regard to mechanical stability and adjustable optical performance. These questions should be addressed in future findings.
Autoacceleration of the overall rate of a free-radical polymerization system has been noted in many bulk polymerization systems. The polymerization of methyl methacrylate, for example, deviates strongly from classical mechanism behavior around 20% conversion; in this region the conversion and molecular mass of the polymer produced increases rapidly. This increase of polymerization is usually accompanied by a large rise in temperature if heat dissipation is not adequate. Without proper precautions, autoacceleration of polymerization systems could cause metallurgic failure of the reaction vessel or, worse, explosion.
The mechanical strength of cellulose fibers can be increased by an order of magnitude by adding only 0.1 wt% of TMCH nanotubes, and measurements of electrical conductivity of polycaprolactone doped with TMCH nanotubes revealed a percolative behavior with an extremely low percolation threshold. The addition of WS2 nanotubes to epoxy resin improved adhesion, fracture toughness and strain energy release rate. The wear of the nanotubes-reinforced epoxy was eight times lower than that of pure epoxy. WS2 nanotubes were also embedded into a poly(methyl methacrylate) (PMMA) nanofiber matrix via electrospinning.
Illustrative and secure bromine chemical sample used for teaching. The glass sample vial of the corrosive and poisonous liquid has been cast into an acrylic plastic cube Methyl methacrylate "synthetic resin" for casting (simply the bulk liquid chemical) may be used in conjunction with a polymerization catalyst such as methyl ethyl ketone peroxide (MEKP), to produce hardened transparent PMMA in any shape, from a mold. Objects like insects or coins, or even dangerous chemicals in breakable quartz ampules, may be embedded in such "cast" blocks, for display and safe handling.
In 2007, a research group claimed the first reproducible synthesis of unsubstituted hexacene—purportedly invalidating previous claims—based on photochemical decarbonylation of a diketone precursor: :Neckers hexacene synthesis (2007). The compound synthesized could not be isolated: it dimerized at concentrations as low as 10−4 M, and reacted with oxygen in solution to form an organic peroxide. In a poly(methyl methacrylate) polymer matrix such side-reactions were limited, and the compound survived up to 12 hours. The next homologue heptacene also studied by this group, and was even more unstable, decomposing within 4 hours.
Compared to other sources of illumination, such as fluorescent and incandescent bulbs, LEDs are energy efficient and increasingly inexpensive. As hard-point light sources, however, LEDs have several significant limitations in edge-lit digital displays. First, the light generated by LEDs must be spread evenly to all parts of the display by a light guide (typically a plate of poly(methyl methacrylate)), which transports light by total internal reflection (TIR). Extraction patterns on the surface of the light-guide meter out the light and generate a uniform brightness distribution.
The glass cone is made by heating and pulling a glass rod to a point and then cutting the tip at the desired length. The other end is not a straight cut, but rather is carved at an angle to provide a shelf onto which the gold wires can be attached. The wires are then placed on the shelf and a methyl methacrylate gel glue is applied in several coats, with care taken to avoid covering the conductive tips. Lastly, the device is sterilized using glutaraldehyde gas at a low temperature, and aerated.
Janus particles' two or more distinct faces give them special properties in solution. In particular, they have been observed to self- assemble in a specific way in aqueous or organic solutions. In the case of spherical Janus micelles having hemispheres of polystyrene (PS) and poly(methyl methacrylate) (PMMA), aggregation into clusters has been observed in various organic solvents, such as tetrahydrofuran. Similarly, Janus discs composed of sides of PS and poly(tert-butyl methacrylate) (PtBMA) can undergo back-to-back stacking into superstructures when in an organic solution.
The common plastic poly (methyl methacrylate) (PMMA) absorbs IR light in the 2.8–25 μm wavelength band, so CO2 lasers have been used in recent years for fabricating microfluidic devices from it, with channel widths of a few hundred micrometers. Because the atmosphere is quite transparent to infrared light, CO2 lasers are also used for military rangefinding using LIDAR techniques. CO2 lasers are used in spectroscopyC. P. Bewick, A. B. Duval, and B. J. Orr, Rotationally selective mode-to-mode vibrational energy transfer in D2CO/D2CO and D2CO/Ar collisions, J. Chem Phys.
She has used metamaterials to create a hyperlens; that is, a lens that escapes the diffraction limit by converting evanescent waves into propagating waves. To create the lens Litchinitser made use of gold and poly(methyl methacrylate) arranged in Slinky-like formation, which can overcome the diffraction limit to visible light. It is hoped that such lens could be used to improve the resolution of endscopes, allowing early detection of certain cancers. Litchinitser makes use of metamaterials to manipulate electric and magnetic fields, engineering shaped beams of light.
The chemical structure of polypropylene The chemical structure of polyethylene Specific types of polymers are ideal for the different types of synthesis. Most polymers currently used in battery separators are polyolefin based materials with semi-crystalline structure. Among them, polyethylene, polypropylene, and their blends such as polyethylene-polypropylene are widely used. Recently, graft polymers have been studied in an attempt to improve battery performance, including micro-porous poly(methyl methacrylate)-grafted and siloxane grafted polyethylene separators, which show favorable surface morphology and electrochemical properties compared to conventional polyethylene separators.
Electropolymerization supplies a thin polymer film, 10 to 100 nm. The electropolymerization of an insulating polymer results in self-limiting deposition as the active moiety is protected; the deposition can also be self-limiting if the polymer can block the solubilized monomer and prohibit continued growth. Through the control of electrochemical variables, polyaniline and polythiophene can be deposited in a controlled manner. Styrene, methyl methacrylate, phenols and other electrically insulating polymers have been deposited on the electrodes to act as a separator that allows ionic transport, but inhibits electrical transport to prevent shorts.
Pyrolysis is one of various types of chemical degradation processes that occur at higher temperatures (above the boiling point of water or other solvents). It differs from other processes like combustion and hydrolysis in that it usually does not involve the addition of other reagents such as oxygen (O2, in combustion) or water (in hydrolysis).Cory A. Kramer, Reza Loloee, Indrek S. Wichman and Ruby N. Ghosh, 2009, Time Resolved Measurements of Pyrolysis Products From Thermoplastic Poly-Methyl-Methacrylate (PMMA) ASME 2009 International Mechanical Engineering Congress and Exposition Pyrolysis produces solids (char), condensable liquids (tar), and uncondensing/permanent gasses.
The BMA process or Degussa process is a chemical process developed by the German chemical company Degussapatent literature for the production of hydrogen cyanide from methane and ammonia in presence of a platinum catalyst. Hydrogen cyanide is used in the chemical industry for the production of intermediate chemicals like acrylonitrile, methyl methacrylate, and adiponitrile. The name is abbreviated from Blausäure (hydrogen cyanide) from Methan (methane) and Ammoniak (ammonia) in German. The reaction equation is analog to the steam methane reforming (SMR) reaction of methane and water: :CH4 \+ NH3 -> HCN + 3 H2, ΔHR = 251 kJ / mol The reaction is extremely endothermic.
2-Vinylpyridine is readily polymerized or copolymerized with styrene, butadiene, isobutylene, methyl methacrylate, and other compounds in the presence of radical, cationic, or anionic initiators. The homopolymer is soluble in organic solvents such as methanol and acetone, whereas cross-linked copolymers are insoluble in organic solvents. An important application of 2-vinylpyridine involves the production of a latex terpolymer of 2-vinylpyridine, styrene, and butadiene, for use as a tire-cord binder. The tire cord is treated first with a resorcinol-formaldehyde polymer and then with a terpolymer made from 15% 2-vinylpyridine, styrene, and butadiene.
Leuna-Werke in 1991 Chemical and Industrial Plant Leuna in 2007 After German reunification in 1990, the Leuna works were divided into several smaller units that were sold to several companies, among them Total S.A., BASF, Linde AG, and Belgian DOMO Group. Common utilities for the companies are provided by InfraLeuna. With the closure of unprofitable plants and general modernization, the number of employees was reduced significantly from 28000 (1978) to 9000 in 2014. QUINN Chemicals invested in a plant to manufacture methyl methacrylate (MMA) but construction has halted as of January 2009 due to heavy cost overruns.
Poly(methyl methacrylate) (PMMA) is the material of choice for denture teeth, however ceramic denture teeth have been, and still are used for this purpose. The main benefit associated with the use of ceramic teeth is their superior wear resistance. There are however a number of disadvantages to using ceramic for denture teeth including their inability to form chemical bonds with the PMMA denture base; rather, ceramic teeth are attached to the base via mechanical retention which increases the chance of debonding during use over time. Additionally, they are more likely to fracture due to their brittle nature.
As part of this work, Priestley studied plexiglas, a composite system of poly(methyl methacrylate) (PMMA) and poly(butyl methacrylate) (PBMA) that is found in coronary stents and paints. He combines experimental studies with computational investigations to better understand the distribution of the PMMA and PBMA throughout the plexiglass. Through his understanding of phase transitions, Priestley has shown that it is possible to precisely control nanostructures, and realised self-assembled biopolymers for use in artificial skin. Alongside his work on polymeric systems, Priestley has investigated nanoparticles, specifically engineered nanoscale zerovalent iron (enZVI) particles, as a means to clean groundwater.
Tribromoethanol can be used as a functional polymerization initator for the introduction of α-hydroxyl groups in poly(methyl methacrylate) (PMMA) and poly(n-butyl acrylate) (PBAK).G. Moineau, M. Minet, Ph. Dubois, Ph. Teyssié, T. Senninger, and R. Jérôme (1999): "Controlled radical polymerization of (meth)acrylates by ATRP with NiBr2(PPh3)2 as catalyst". Macromolecules, volume 32, issue 1, pages 27–35. Mohammed Dirany, Marylène Vayer, Christophe Sinturel, René Erre, Patrick Lacroix-Desmazes, and Bernard Boutevin (2009): "Synthesis and characterization of polystyrene-block-polylactide by combination of ATRP and ROP using tribromoethanol as initiator: Precursors to ordered nanoporous materials".
To extend the coverage of antibiotics against more bacteria in Type III Gustilo fractures, combination of first generation cephalosporin and aminoglycoside (gentamicin or tobramycin) or a third generation cephalosporin is recommended to cover against nosocomial gram negative bacilli such as Pseudomonas aeruginosa. Adding penicillin to cover for gas gangrene caused by anaerobic bacteria Clostridium perfringens is a controversial practice. Studies has shown that such practice may not be necessary as the standard antibiotic regimen is enough to cover for Clostridial infections. Antibiotic impregnated devices such as tobramycin impregnated Poly(methyl methacrylate) (PMMA) beads and antibiotic bone cement are helpful in reducing rates of infection.
David Turnock, The Economy of East Central Europe, 1815-1989, p. 255. London: Routledge, 2004, From 1950 to 1970, new units for producing carbon black were set up, as well as for formic and oxalic acid and methyl methacrylate. The company's products were the chief raw materials for various objects made of rubber (tires, transmission belts, conveyor belts, protective clothes and shoes), but were also used in the chemical, pharmaceutical, agricultural and other industries. The output of various types of carbon black amounted to 24,400 tons in 1989 (63,000 tons had been projected), a number that steadily decreased until 1993, when the factory was shut down following lengthy negotiations.
The typical choice, poly(methyl methacrylate) (PMMA) is applied to the substrate by a glue-down process in which a precast, high- molecular-weight sheet of PMMA is attached to the plating base on the substrate. The applied photoresist is then milled down to the precise height by a fly cutter prior to pattern transfer by X-ray exposure. Because the layer must be relatively free from stress, this glue-down process is preferred over alternative methods such as casting. Further, the cutting of the PMMA sheet by the fly cutter requires specific operating conditions and tools to avoid introducing any stress and crazing of the photoresist.
Acrylic resin, in particular the methyl methacrylate type of synthetic resin, produces acrylic glass (also called PMMA, Lucite, Plexiglass), which is not a glass but a plastic polymer that is transparent, and very hard. It is suitable for embedding objects (such as, for example, acrylic trophies), for display purposes. Styrene is a similar liquid monomer at room temperature, which will also polymerize into clear glass-like polystyrene plastic, with addition of a suitable catalyst. A flexible mold can be made of latex rubber, room temperature vulcanized silicone rubber or other similar materials at relatively low cost, but can only be used for a limited number of castings.
Windscreens of all kinds of vehicles as well as crash-proof glazing or pavement light used in the construction sector are part of the main fields of application. The composite film used mostly in the construction and automotive sectors is composed of polyvinyl butyral (PVB). Other customary intermediate layer materials include ethylene-vinyl acetate (EVA), polyarcylate (PA), poly(methyl methacrylate) (PMMA), polyurethane (PUR), etc. Depending on the number, type and thickness of the glass panes used and intermediate layers, composite glasses are used as safety glass, sound-proof glas, fireproof glass, as well as throw-through-resistant, breakthrough- resistant or ballistic-resistant glass etc.
These devices have been developed to realize low-cost, large-area electronic products and biodegradable electronics. OFETs have been fabricated with various device geometries. The most commonly used device geometry is bottom gate with top drain and source electrodes, because this geometry is similar to the thin-film silicon transistor (TFT) using thermally grown SiO2 as gate dielectric. Organic polymers, such as poly(methyl-methacrylate) (PMMA), can also be used as dielectric.. One of the benefits of OFETs, especially compared with inorganic TFTs, is their unprecedented physical flexibility, which leads to biocompatible applications, for instance in the future health care industry of personalized biomedicines and bioelectronics.
In the 1980s, the use of cadaver allograft disc for filling in small holes received a satisfactory result, and there was a resurgence of the use of cadaver bone. However, cadaver bones and allografts, in general, are not the preferred materials in modern operations. The use of methyl methacrylate (PMMA) for cranioplasty was being developed since World War II, and the material is used extensively since 1954, when there is a high demand for cranioplasty due to a large number of injuries. It becomes malleable when an exothermic reaction occurs between its powder form and benzoyl peroxide, allowing it to be moulded to the cranial defect.
Liquid Light is a New Jersey-based company that develops and licenses electrochemical process technology to make chemicals from carbon dioxide (CO2). The company has more than 100 patents and patent applications for the technology that can produce multiple chemicals such as ethylene glycol, propylene, isopropanol, methyl-methacrylate and acetic acid. Funding has been provided by VantagePoint Capital Partners, BP Ventures, Chrysalix Energy Venture Capital, Osage University Partners and Sustainable Conversion Ventures. Liquid Light’s technology can be used to produce more than 60 chemicals, but its first targeted process is for the production of monoethylene glycol (MEG) which has a $27 billion annual market.
Sciatic nerve injury occurs between 0.5% and 2.0% of the time during a hip replacement. Sciatic nerve palsy is a complication of total hip arthroplasty with an incidence of 0.2% to 2.8% of the time, or with an incidence of 1.7% to 7.6% following revision. Following the procedure, in rare cases, a screw, broken piece of trochanteric wire, fragment of methyl methacrylate bone cement, or of a Burch-Schneider antiprofusio cage can impinge on the nerve; this can cause sciatic nerve palsy which may resolve after the fragment is removed and the nerve freed. The nerve can be surrounded in oxidized regenerated cellulose to prevent further scarring.
Then, the lignin is separated from the cellulose and hemicellulose structure turning the wood white and allowing the resin penetration to start. Finally, the sample is immersed in a matching resin, usually Poly Methyl Methacrylate (PMMA), under high temperatures (85 °C) and a vacuum for 12 hours. This process fills the space previously occupied by the lignin and the open wood cellular structure resulting in the final transparent wood composite. While the delignification process is a successful method of production, it is limited to its laboratory and experimental production of a small, and low thickness material that is unable to meet its practical application requirements.
"Construction #48" is a representative example of Lamis's plexiglas cubes.Lamis was strongly influenced by constructivism, which he read about as an art student, particularly the theories of Naum Gabo, Antoine Pevsner and Richard Lippold. Throughout the 1960s and early 1970s, Lamis worked with sheet acrylic (Poly(methyl methacrylate), more commonly called Plexiglas), drawn to its reflective and refractive qualities. Many of his works were precisely- measured, abstractly geometric cubes named Construction sequentially, such as Construction #31 (1963) at the Loretta Howard Gallery, Construction #48 (1964), in the collection of the Brooklyn Museum, and Construction #208 (1972), at the Swope Art Museum in Terre Haute, Indiana.
Setco from Mumbai is producing sealants developed for submarines of Indian Navy at DRDO labs for personal protection equipments. Research Centre Imarat (RCI) and Terminal Ballistics Research Laboratory (TBRL) developed product called Aerosol Containment Box for enclosure of intubation procedure made with Poly(methyl methacrylate). It is cubical in shape designed for both adults and minors that covers the COVID-19 infected patients during medical examination and treatment from head to chest to stop the transmission of droplets containing the virus to others. Employees' State Insurance Corporation Medical College, Hyderabad helped RCI in prototype development while Postgraduate Institute of Medical Education and Research helped in testing, validation and acceptance of product for medical use.
Light microscopic picture of a PMMA-copolymer, made by suspension polymerization SEM-Picture of PMMA-particles, that started to coalesce during suspension polymerization, close to a single bead SEM-picture of a Pac-Man shaped PMMA-copolymer particle, made by suspension polymerization Suspension polymerization is a heterogeneous radical polymerization process that uses mechanical agitation to mix a monomer or mixture of monomers in a liquid phase, such as water, while the monomers polymerize, forming spheres of polymer. This process is used in the production of many commercial resins, including polyvinyl chloride (PVC), a widely used plastic, styrene resins including polystyrene, expanded polystyrene, and high-impact polystyrene, as well as poly(styrene-acrylonitrile) and poly(methyl methacrylate).
Lithium polymer cells have evolved from lithium-ion and lithium-metal batteries. The primary difference is that instead of using a liquid lithium-salt electrolyte (such as LiPF6) held in an organic solvent (such as EC/DMC/DEC), the battery uses a solid polymer electrolyte (SPE) such as poly(ethylene oxide) (PEO), poly(acrylonitrile) (PAN), poly(methyl methacrylate) (PMMA) or poly(vinylidene fluoride) (PVdF). The solid electrolyte can typically be classified as one of three types: dry SPE, gelled SPE and porous SPE. The dry SPE was the first used in prototype batteries, around 1978 by Michel Armand, and 1985 by ANVAR and Elf Aquitaine of France, and Hydro Quebec of Canada.
Basu's researches were published in a number of articles and the article, Degree of Polymerization and Chain Transfer in Methyl Methacrylate, he and his co-authors, J. N. Sen and S. R. Palit, published in 1950 was the first Indian article on polymer chemistry. He was associated with International Journal of Quantum Chemistry, the Indian Journal of Chemistry and the Proceedings of the Proceedings of Indian National Science Academy as their associate editor and mentored a number of students in their doctoral researches. During 1961-62, Basu was a visiting professor at Indiana University Bloomington and was subsequently (1962–63) a visiting professor in the quantum chemistry group at the University of Uppsala.
Ion implantation has been used to create silver nanoparticles embedded in glass, polyurethane, silicone, polyethylene, and poly(methyl methacrylate). Particles are embedded in the substrate by means of bombardment at high accelerating voltages. At a fixed current density of the ion beam up to a certain value, the size of the embedded silver nanoparticles has been found to be monodisperse within the population, after which only an increase in the ion concentration is observed. A further increase in the ion beam dose has been found to reduce both the nanoparticle size and density in the target substrate, whereas an ion beam operating at a high accelerating voltage with a gradually increasing current density has been found to result in a gradual increase in the nanoparticle size.
It also has good impact strength, higher than both glass and polystyrene; however, PMMA's impact strength is still significantly lower than polycarbonate and some engineered polymers. PMMA ignites at and burns, forming carbon dioxide, water, carbon monoxide and low-molecular-weight compounds, including formaldehyde. PMMA transmits up to 92% of visible light (3 mm thickness), and gives a reflection of about 4% from each of its surfaces due to its refractive index (1.4905 at 589.3 nm).Refractive index and related constants – Poly(methyl methacrylate) (PMMA, Acrylic glass) . Refractiveindex.info. Retrieved 2014-10-27. It filters ultraviolet (UV) light at wavelengths below about 300 nm (similar to ordinary window glass). Some manufacturersAltuglas International Plexiglas UF-3 UF-4 and UF-5 sheets . Plexiglas.com. Retrieved 2012-05-09.
Examples of fillers used for this purpose include hyaluronic acid; poly(methyl methacrylate) microspheres with collagen; human and bovine collagen derivatives, and fat harvested from the person's own body (autologous fat transfer). Microneedling is a procedure in which an instrument with multiple rows of tiny needles is rolled over the skin to elicit a wound healing response and stimulate collagen production to reduce the appearance of atrophic acne scars in people with darker skin color. Notable adverse effects of microneedling include post-inflammatory hyperpigmentation and tram track scarring (described as discrete slightly raised scars in a linear distribution similar to a tram track). The latter is thought to be primarily attributable to improper technique by the practitioner, including the use of excessive pressure or inappropriately large needles.
It may be, for example, a compound of lithium bis(fluorosulfonyl)imide (LiFSI) and high molecular weight poly(ethylene oxide) (PEO), or a high molecular weight poly(trimethylene carbonate) (PTMC). The performance of these proposed electrolytes is usually measured in a half-cell configuration against an electrode of metallic lithium, making the system a "lithium-metal" cell, but it has also been tested with a common lithium-ion cathode material such as lithium-iron-phosphate (LiFePO4). Other attempts to design a polymer electrolyte cell include the use of inorganic ionic liquids such as 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM]BF4) as a plasticizer in a microporous polymer matrix like poly(vinylidene fluoride-co- hexafluoropropylene)/poly(methyl methacrylate) (PVDF-HFP/PMMA).
Acetone is used to synthesize methyl methacrylate. It begins with the initial conversion of acetone to acetone cyanohydrin: :(CH3)2CO + HCN → (CH3)2C(OH)CN In a subsequent step, the nitrile is hydrolyzed to the unsaturated amide, which is esterified: :(CH3)2C(OH)CN + CH3OH → CH2=(CH3)CCO2CH3 \+ NH3 The third major use of acetone (about 20%) is synthesizing bisphenol A. Bisphenol A is a component of many polymers such as polycarbonates, polyurethanes, and epoxy resins. The synthesis involves the condensation of acetone with phenol: :(CH3)2CO + 2 C6H5OH → (CH3)2C(C6H4OH)2 \+ H2O Many millions of kilograms of acetone are consumed in the production of the solvents methyl isobutyl alcohol and methyl isobutyl ketone. These products arise via an initial aldol condensation to give diacetone alcohol.
The line coefficient (Fig 5) suggests that this is a fairly accurate result, however this is only the case for the pairing of that particular solid with those particular liquids. In other cases, the fit may not be so great (such is the case if we replace polyethylene with poly(methyl methacrylate), wherein the line coefficient of the plot results using the same list of liquids would be significantly lower). This shortcoming is a result of the fact that the Zisman theory treats the surface energy as one single parameter, rather than accounting for the fact that, for example, polar interactions are much stronger than dispersive ones, and thus the degree to which one is happening versus the other greatly affects the necessary calculations. As such, it is a simple but not particularly robust theory.
The Prilezhaev reaction involves the conversion of an alkene to an epoxide using a peracid as the oxidant and was first reported in 1909. The reaction has been used as the final step of the synthesis of scopine, a tropane alkaloid. In this approach, a [4+3] cycloaddition mediated by diiron nonacarbonyl is used to construct the bicyclic skeleton, the hydroxyl functional group is then introduced by diastereoselective reduction of the ketone with diisobutylaluminum hydride, and the preparation completed with a Prilezhaev trifluoroperacetic acid epoxidation. 600px The high reactivity of trifluoroperacetic acid relative to other peroxy acids allows it to successfully oxidize relatively electron-poor alkenes such as 1-hexene and α,β-unsaturated esters such as methyl methacrylate, substrates that are generally resistant to peroxy-acid epoxidation.
It was incorporated on 21 December 1933; the first Chairman was Charles Waghorne of Insulators Limited.Companies House It is the longest-established plastics federation in the world. It was the 1930s that was the decade in which many common plastics were discovered, some in the UK. On 27 March 1933 Reginald Gibson and Eric Fawcett (with Francis Arthur Freeth FRS and Sir Michael Perrin) discovered polyethylene (polythene) at ICI's Winnington Research Laboratory at Winnington, Cheshire; John Crawford, at the Explosives group of ICI at Ardeer, North Ayrshire near Stevenston, produced a commercial synthesis of poly(methyl methacrylate), also known as Perspex with production beginning in 1934. Polythene is the world's most widespread polymer, and was first produced by ICI from 1939; many plastic bottles are made from LDPE.
A research group led by Professor Lars Berglund from Swedish KTH University along with a University of Maryland research group led by Professor Liangbing Hu have developed a method to remove the color and some chemicals from small blocks of wood, followed by adding polymers, such as Poly(methyl methacrylate) and epoxy, at the cellular level, thereby rendering them transparent. As soon as released in between 2015 and 2016, see-through wood had a large press reaction, with articles in ScienceDaily, Wired, the Wall Street Journal, the New York Times, to name a few. Actually those research groups rediscovered a work from Siegfried Fink, a German Researcher, from as early as 1992: with a process very similar to Berglund's and Hu's, the German Researcher turned wood transparent to reveal specific cavities of the wood structure for analytical purpose.
Graham & Brown at Blackburn make fancy wallpaper, next to the Leeds & Liverpool Canal, and off the A6077 is CWV (Coloroll and Crown Wallpaper); Capita Group runs TV Licensing in the middle of the town; Lucite International has its main plant on the A666 in the north of the town centre, where it makes Lucite; this site, under ICI Acrylics, manufactured the perspex for wartime aircraft canopies from 1940, becoming Ineos Acrylics from 1999 until 2002 and the company is the world's largest manufacturer of methyl methacrylate (MMA); ICI Acrylics invented the process to make perspex in 1936; the granular form of Perspex was known by ICI as Leukon. Tensar International, invented and manufacture geogrids for construction, off the A6077 near junction 5 of the M65 in Blackburn near the B6231 roundabout; nearby is Castle Metals UK; also on the Shadsworth Business Park is Evertaut, who make auditorium seating.
Sadhan Basu FNA, FASc, FRSC (2 January 1922 – 5 October 1992) was an Indian physical chemist, academic and the Palit Professor of Chemistry at the University of Calcutta from 1964 to 1985. He was known for his elucidation of the Quantum Mechanical Model of Robert S. Mulliken and his article, Degree of Polymerization and Chain Transfer in Methyl Methacrylate, co-authored by Jyotirindra Nath Sen and Santi R. Palit was the first published Indian article on polymer chemistry. He was an elected fellow of the Royal Society of Chemistry, Chemical Society of France, Indian Chemical Society, Indian National Science Academy and the Indian Academy of Sciences. The Council of Scientific and Industrial Research, the apex agency of the Government of India for scientific research, awarded him the Shanti Swarup Bhatnagar Prize for Science and Technology, one of the highest Indian science awards, in 1962, for his contributions to chemical sciences.
R. R. PG Autonomous College, Alwar (Raj.) on Sept. 23-24, 2011. # Shalu Vashistha and priyanka Yadav, Biochemical Modification of Sisal Fibers (Agave sisalina) using Bacteria (Brevibacillus parabrevis) and poly(MMA) National conference “Green Chemistry- Safer chemistry “ to be organized by the Department of Chemistry, Govt. R. R. PG Autonomous College, Alwar (Raj.) on Sept. 23-24, 2011. # Shalu Vashistha and Ijeoma ekeledo Rachel Cellulase enzyme assisted biopolishing and microwave assisted grafting of Sisal fibers (Agave sisalana) for use in biocomposite materials. ) National conference “Green Chemistry- Safer chemistry “ to be organized by the Department of Chemistry, Govt. R. R. PG Autonomous College, Alwar (Raj.) on Sept. 23-24, 2011. # Shalu Vashistha and Piyush Sharma, Role of Resveratrol in treatment of cancer National Level Conference on Natural products in healthcare to be organized by gurunanak college of pharmacy, Nagpur(Maharastha) on 24-26 nov 2011 # Shalu Vashistha and Ijeoma ekeledo Rachel Role of Artemisinin in treatment of Malaria National Level Conference on Natural products in healthcare to be organized by gurunanak college of pharmacy, Nagpur(Maharastha) on 24-26 nov 2011 # Susheel Kalia, and Shalu Vashistha, Bacterial and Chemical Modification of Sisal fibers using Brevibacillus parabrevis and Methyl methacrylate: A Comparative Study, Arbian Journal of Chemistry, Under Review.

No results under this filter, show 137 sentences.

Copyright © 2024 RandomSentenceGen.com All rights reserved.