Prior to her coupling with Pratt, Faris was married to actor Ben Indra.
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"I hope it's a romance for the ages," he said of his character's coupling with Metz's Kate.
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We're coupling with others to do investigative pieces from time to time, whether it be ProPublica or whomever.
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Mr. Hefner told a film interviewer that in the early days, yes, "everybody was coupling with everybody," including him.
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Each season begins with an initial coupling, with contestants pairing up based on first impressions and, sometimes, whoever is left.
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"I wanna be somewhat reasonable about it, but I think good things happen fast," Stewart said of her relatively recent coupling with Meyer.
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Her coupling with Mr. Big at the end of the series "ultimately betrayed what [the series] was about," creator Darren Star recently wrote.
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However, often lost in the weeds of repealing the death tax is the tax's complex yet direct coupling with other taxes, including the gift tax.
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Allen's coupling with the #MeToo movement seems to be at least part of the motivation for Previn coming forward now after refraining from public comment for so long.
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After Brussels blocked its preferred coupling with the rail unit of Germany's Siemens, the French locomotive maker is paying 7.5 billion euros for the rival business of Canada's Bombardier.
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Asked about the won's exchange rate with the yuan, Kim said the ministry was "closely monitoring won coupling with yuan," but added that it is not targeting a specific currency level.
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When asked about won's exchange rate with the yuan, Deputy Minister Kim said the ministry was "closely monitoring won coupling with yuan," but added that it is not targeting a specific currency level.
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He will recapitulate the old man's fondness for young flesh in his coupling with the Blackmail Girl, enjoy the disapproval of cast and crew when he takes her with him on a set.
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Watching them together does feel like witnessing a rarefied coupling: With her windup impish curiosity and his reserved charm, they recall one of those adorable wildlife videos where, like, a coyote befriends a badger.
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Even if you end up marrying that person or coupling with them, money becomes your partner," O'Leary says adding that, "More than half the time the reason people break up is they're not compatible financially.
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In coupling with the new Apple Watch's upgrade from IPX7 to WR 50M (water resistant to 50M), this makes the whole lineup of very expensive gadgets much less likely to be killed off by an errant spill.
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Warwick himself created such a coupling with medical assistance in 2002, embedding a device in his arm which connected to a part of his nervous system so that it could send signals bidirectionally, communicating with his brain and also the internet.
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Haters and fans alike flooded Twitter with images of "Elon Musk and Grimes" at the Met Gala, joked about what their conversations are like, and expressed betrayal at the thought of the indie darling coupling with a Silicon Valley billionaire.
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In terms of precedent for what could follow, the NX debuting with a terrific new Zelda game bundled beside it beats the shit out of the Wii U's coincided coupling with a tired-looking 2D-plane Mario outing, Your Shape: Fitness Evolved and Epic Mickey 2.
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For months – years, really – before news of her coupling with the only Kardashian son, Chyna had been entangled in a complicated, sometimes contentious, relationship with the Keeping Up with the Kardashians stars, including going from Kim Kardashian West's BFF to an outsider of her circle, not to mention sharing a son with Kylie Jenner's on-again, off-again boyfriend, Tyga.
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Abnormal right ventricular-pulmonary artery coupling with exercise in heart failure with preserved ejection fraction. European heart journal, ehw241.
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In these applications, the model is able to take advantage of tight coupling with wave models to increase calculation accuracy.
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Bhardwaj's research interests include theoretical and observational studies of planetary surfaces, atmospheres, ionospheres and their coupling with magnetospheric plasma and solar wind.
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Booth is credited with the invention of the screw coupling, with a statue of him holding one displayed in St George's Hall, Liverpool.
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The Hay coupling (1962) is another version of the Glaser coupling with the TMEDA complex of copper(I) chloride. An example is the coupling of trimethylsilylacetylene.
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Bachmann are known for their consistent quality of model trains . Many of their trains include NEM pockets, making it possible to replace standard tension lock coupling with close couplings such as Kadees.
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Forgione, P., Bilodeau, F. et al. reported that heteroatoms containing a carboxylic acid also are tolerated by palladium monometallic systems and undergo decarboxylative cross coupling with aryl halides.Forgione, P., Bilodeau. F. et al.
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It is usually supplied as a calcium salt.K. Hunger. W. Herbst "Pigments, Organic" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2012. It is prepared by azo coupling with 3-hydroxy-2-naphthoic acid.
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Modern retarders are computer controlled to apply a precise amount of pressure on the wheels so that cars rolling down a yard's hump are slowed to a safe speed for coupling with cars already standing on the yard's tracks.
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He was Dio's classmate and Coupling buddy during Couplers Training at Lake Louise. He is also capable of Coupling with Aoba. ; : :A scientist in charge of the Coupling System. Developed the specialized cockpit that is used in Luxon and Braydon.
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This advantage can be translated into practical experiment protocols in the biological community, such as coupling with DNA amplification. This also allows for the chip to be smaller, and to give researchers more freedom in designing platforms for microdroplet analysis.
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Vorbrüggen, H.; Bennua, B. Tetrahedron Lett. 1978, 1339. The combination of trifluoroacetic acid (TFA), trimethylsilyl chloride (TMSCl), and hexamethyldisilazide (HMDS) generates trimethylsilyl trifluoroacetate in situ, which accomplishes both the silylation of the heterocycle and its subsequent coupling with the sugar.Vorbrüggen, H.; Bennua, B. Chem. Ber.
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The stock differed from that for the Southern Region in that each vehicle was long instead of , and the vehicles within the units had screw coupling with two buffers instead of the close-coupled single buffer with chain arrangement used on the Southern multiple units.
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5 round trips operate from to Takayama, and five more continue past to and Toyama. Additionally, one service runs from to . This service runs from to Gifu before coupling with a Hida service from and continuing to . Trains operate at a maximum speed of .
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A Chem. 315 (2010) 108-134 The state-of-the-art TAP installations (TAP-3) do not only provide better signal-to-noise ratio than the first generation TAP machines (TAP-1), but also allow for advanced automation and direct coupling with other techniques.
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Synthesis of the upper part of the NanoPutian chain begins with 1,3-dibromo-2,4-diiodobenzene as the starting material. Sonogashira coupling with 4-oxytrimethylsilylbut-1-yne produces 2,5-bis(4-tert-butyldimethylsiloxy-1′-butynyl)-1,4-di-bromobenzene. One of the bromine substituents is converted to an aldehyde through an SN2 reaction with the strong base, n-BuLi, and THF in the aprotic polar solvent, DMF to produce 2,5-bis(4-tert-butyldimethylsiloxy-1′-butynyl)-4-bromobenzaldehyde. Another Sonogashira coupling with 3,5-(1′-Pentynyl)-1-ethynylbenzene attaches the lower body of the NanoPutian. The conversion of the aldehyde group to a diether “head” occurs in two steps.
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One odd detail was that the door was located in the front. It had a V8 diesel engine, automatic gearbox, and semi-trailer coupling with built-in automatic air and electric connections. At the rear a forklift was mounted, so the truckdriver could load and unload goods from the trailer.
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Rin is reserved and well mannered, but easily irritated when coupling with Ian. He was raised by Jin (see below), who is Rin's primary consultant in several matters. ;Ian Sanders: Seventeen years old, first appearance: Volume 7. Even at the age of seventeen, he is one of the world's most famous super- models.
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The unit is designed to generate a large capacitance, lower the resonant frequency, and concentrate the electric field. Combining units creates a design as a periodic medium. Furthermore, the multiple unit structure has strong magnetic coupling with low radiative losses. Research has also covered variations in magnetic resonances for different SRR configurations.
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The subsidence of the area under the load and the uplift of the forebulge continue until the load is in isostatic equilibrium, a process that takes on the order of 10,000 to 20,000 years. Because of the coupling with the mantle, the rate of forebulge formation and collapse is controlled by mantle viscosity.
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The node graph architecture often allows grouping of nodes inside other group nodes. This hides complexity inside of the group nodes, and limits their coupling with other nodes outside the group. This leads to a hierarchy where smaller graphs are embedded in group nodes. In Nuke the group node is simply called the Group node.
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Ryuhei Maruyama, Shota Yasuda, and Shingo Murakami filmed their scenes first and You Yokoyama, Tadayoshi Ohkura, Subaru Shibutani, and Ryo Nishikido filmed their scenes last. The video was aired on Space Shower TV and m-on. It was released on DVD as a coupling with the Limited Edition A version of the song's release.
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Signal attenuation could be measured as well, as the coupling with the additional surface mass will reduce the wave energy. In the case of mass-sensing, as the change in the signal will always be due to an increase in mass from a reference signal of zero additional mass, signal attenuation can be effectively used.
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Glass flakes may be surface treated by silane coupline agents for better coupling with resin which is a main material of anti-corrosion coating. silane coupline agents include KH-570, KH-560, KH-550, A-174, Z-603, KBM-503, GF-31. Glass flakes with surface treated include C-90E, C-150V and RCF-160T.
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This interaction is responsible for many of the details of atomic structure. In solid-state physics, the spin coupling with the orbital motion can lead to splitting of energy bands due to Dresselhaus or Rashba effects. In the macroscopic world of orbital mechanics, the term spin–orbit coupling is sometimes used in the same sense as spin–orbit resonance.
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Many moths have a frenulum which is a filament arising from the hindwing and coupling (matching up) with barbs on the forewing. The frenulum can be observed only when a specimen is in hand. Some moths have a lobe on the forewing called a jugum that helps in coupling with the hindwing. Butterflies, however, lack these structures.
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PBM coupling with trisubstituted aromatic amine Synthesis of iminodicarboxylic acid derivatives When used as nitrogen nucleophiles, amino acids can furnish various iminodicarboxylic acid derivatives. High diastereoselectivity is usually observed, and the newly formed stereocenter usually share the same configuration with the starting amino acid. This reaction works well in highly polar solvents (ex. water, ethanol, etc.).
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Kleinrock, M. C., and R. T. Bird, "Southeastern boundary of the Juan Fernandez microplate: Braking microplate rotation and deforming the Antarctic plate" J. Geophys. Res., 99, 9237–9261, 1994. Approximately 2.5 Ma ago the JF Microplate began decoupling from the Pacific Plate and coupling with the Antarctic Plate. The latter severely braked the rotational movement of the microplate.
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Anthropogenic pressures regulate benthic–pelagic coupling directly and indirectly through their effects on the physical (e.g., salinity, oxygen, temperature) and biological (e.g., species, communities, functional traits) components of ecosystems. In coastal and estuarine ecosystems, climate change, nutrient loading, and fishing have been shown to have direct effects on benthic–pelagic coupling with clear consequences for ecosystem function.
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A wide range of aryl boronic acids is tolerated, while the usage of vinyl boronic acids is not reported. "N"-unsubstituted indoles react very sluggishly under normal reaction conditions, thus confirming the mechanism below. PBM coupling with N-substituted indole Naskar et al. also proposed the usage of tertiary aromatic amines in Petasis reaction as another equivalent of amine nucleophile.
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OGCMs have many important applications: dynamical coupling with the atmosphere, sea ice, and land run-off that in reality jointly determine the oceanic boundary fluxes; transpire of biogeochemical materials; interpretation of the paleoclimate record;climate prediction for both natural variability and anthropogenic chafes; data assimilation and fisheries and other biospheric management.Chassignet, Eric P., and Jacques Verron, eds. Ocean modeling and parameterization. No. 516.
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Stretch dominated structures such as octet tress structure have reduced density to stiffness coupling with n around 1 over many magnitudes of density. This allows for the creation of structural metamaterials which are both ultralight, strong, and energy-absorbing, with elastic behavior up to and 50% compression strain. Often these structures are highly isotropic, with their behavior constant over different loading directions.
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Theoretical analysis, which followed, closely matched the experimental results. An air gap was built into the structure between the array of copper wires and the YIG. This reduces coupling with the ferrite, YIG material. When negative permeability is achieved across a range of frequencies, the interaction of the ferrite with the wires in close proximity, reduces the net current flow in the wires.
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The majority of motor proteins participating in plasmid segrosomes are Walker-type or ParM type ATPases. Segrosome formation could be a highly regulated and ordered process to ensure its coupling with the other events of the bacterial cell cycle. Recently segrosomal complexes derived from the tubulin family of cytoskeletal proteins, which are GTPases have been discovered in megaplasmids found in Bacillus species.
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Exemplary for the synthesis of arylides by the reaction of diketenes with aromatic amines is: :Acetoacetanilid aus Diketen - Synthese von Aryliden Aromatic diazonium coupling with arylides to form azo dyes, such as Pigment Yellow 74: :File:Synthese von Brilliantgelb.svg The industrial synthesis of the sweetener acesulfam-K is based on the reaction of diketene with sulfamic acid and cyclization by sulfur trioxide (SO3).
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4-Formylphenyl boronic acid crystallizes in colorless needles or is obtained as an odorless, whitish powder, which dissolves little in cold but better in hot water. The compound is quite stable and readily forms dimers and cyclic trimeric anhydrides, which complicate purification and tend to protodeboronize, a secondary reaction that occurs frequently in the Suzuki coupling, with elimination of the boronic acid function.
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A Tesla coil will pass high-frequency current through the tube, and since it has a high voltage as well, the gases within the tube will ionize and emit light. This also works with plasma globes. Capacitive coupling with high-voltage power lines can light a lamp continuously at low intensity, depending on the intensity of the electric field, as shown in the image on the right.
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Disillusioned, Walter takes the dog back to his ranch, and advises Coco to get settled somewhere and return for the dog later on. But Coco feels lost without the dog, and returns to Walter's, only to find the dog has escaped. Upon finding the dog again, coupling with a stray female mutt, Coco sets off into a hopeful future with two young hitchhikers in tow.
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Meanwhile, Kereama, a Maori harpooner on a whaling ship, sleeps with a prostitute in an army stable. A drunk Sergeant-Major Saunders arrives with two of his comrades become angry at the Maori coupling with "pure British women". He and his comrades then beat and taunt Kereama, who fights back; in the confusion Saunders accidentally kills one of his own men. Saunders evades responsibility by blaming Kereama.
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The energy of the system is where is the volume of the magnet, is the saturation magnetization, and is the vacuum permeability. The first term is the magnetic anisotropy and the second the energy of coupling with the applied field (often called the Zeeman energy). Stoner and Wohlfarth normalized this equation: where . A given magnetization direction is in mechanical equilibrium if the forces on it are zero.
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An EMAT ultrasonic transducer (UT) shown with a conventional piezoelectric UT. Electromagnetic acoustic transducer (EMAT) is a transducer for non-contact acoustic wave generation and reception in conducting materials. Its effect is based on electromagnetic mechanisms, which do not need direct coupling with the surface of the material. Due to this couplant-free feature, EMATs are particularly useful in harsh, i.e., hot, cold, clean, or dry environments.
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The resulting bead-DNA complexes are then analyzed using flow cytometry. This technique is able to capture allele and mutation frequencies due to coupling with ddPCR. However, unlike with ddPCR, a larger number of DNA sequences can be interrogated due to the flexibility of using fluorescently bound probes. Another advantage of this system is that the DNA isolated can also be used for downstream sequencing.
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The Takai olefination based on an organochromium intermediate also delivers E-products. A titanium compound, Tebbe's reagent, is useful for the synthesis of methylene compounds; in this case, even esters and amides react. A pair of ketones or aldehydes can be deoxygenated to generate an alkene. Symmetrical alkenes can be prepared from a single aldehyde or ketone coupling with itself, using titanium metal reduction (the McMurry reaction).
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Unlike ACD, which is more of a distributed system which acts independently, the TCAS will be more of a centralized system where TCAS controls communication between trains and with trains with the TDMA protocol. The TCAS under development is meant to be a vital safety system. TCAS has a deep coupling with the railway signalling system so ACD systems do not depend on the railway signalling system.
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ARM seeks to provide the climate research community with strategically located in situ and remote sensing observatories designed to improve the understanding and representation, in climate and earth system models, of clouds and aerosols as well as their interactions and coupling with the Earth’s surface. ARM focuses on obtaining continuous measurements—supplemented by field campaigns—and providing data products that promote the advancement of climate models.
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Kanamienamides is a complex enol ether containing enamide that is currently undergoing research in regards to its inhibitory activity towards cancer cells. The synthesis of kanamienamide consists of several chemical techniques, including CBS asymmetric reduction, Stork-Zhao-Wittig olefination, Cu-mediated amide coupling with vinyl iodide, Evans asymmetric alkylation, and ring- closing metathesis. Kanamienamide is a natural product found in Moorea bouillonii which is a cyanobacterium.
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The show was made into a three-part TV miniseries in 1997. Mohammed Fairouz set the words of Alma Mahler in his song cycle Jeder Mensch. It premiered in a coupling with songs of Alma Mahler by mezzo-soprano Kate Lindsey in 2011. A treatment of Mahler-Werfel's life was presented in the 2001 Bruce Beresford film Bride of the Wind, in which Alma was played by Australian actress Sarah Wynter.
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It is possible that these unions never occurred but were embellishments to the image of the king; hymns which praise Middle Eastern kings for coupling with the goddess Ishtar often speak of him as running 320 kilometres, offering sacrifices, feasting with the sun-god Utu, and receiving a royal crown from An, all in a single day. Some modern historians argue in the same direction, though their posture has been disputed.
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The performance concerns are reduced due to tight coupling with operating system internals. To overcome these limitations, ASICs and Multi-Core processors have traditionally been used with IPS applications. This luxury is not available in virtualized environments because virtualization technologies typically do not allow direct hardware access to the underlying application-specific hardware. Virtualization is well suited for general purpose applications which would otherwise be underutilized on dedicated hosting hardware.
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Capacitive coupling with high-voltage power lines can light a lamp continuously at low intensity. Fluorescent lamps can be illuminated by means other than a proper electrical connection. These other methods, however, result in very dim or very short-lived illumination, and so are seen mostly in science demonstrations. Static electricity or a Van de Graaff generator will cause a lamp to flash momentarily as it discharges a high voltage capacitance.
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Weak coupling with monotonic (bistable) dynamical regimes demonstrate spatial chaos phenomena and are popular in neural models. Weak coupling unimodal maps are characterized by their stable periodic points and are used by gene regulatory network models. Space-time chaotic phenomena can be demonstrated from chaotic mappings subject to weak coupling coefficients and are popular in phase transition phenomena models. Intermediate and strong coupling interactions are less prolific areas of study.
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Kane's proposal for readout was to apply an electric field to encourage spin- dependent tunneling of an electron to transform two neutral donors to a D+-D- state, that is, one where two electrons orbit the same donor. The charge excess is then detected using a single-electron transistor. This method has two major difficulties. Firstly, the D- state has strong coupling with the environment and hence a short decoherence time.
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The SSC allows for direct light coupling with no air gap, sub-0.5 dB loss, and extinction ratios of >20 dB for use in silicon photonics and other applications. Chiral Photonics also offers twisted capillary tubes for proteomic analysis. The protein unfolds as it passes through the channel allowing for imaging. In other uses the rotation of the protein as it passes through the channel facilitates 360° imaging.
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A floating PV plant equipped with a tracking system has a limited additional cost while the energy gain can range from 15 to 25%. #Storage opportunity: the presence of water naturally suggests using gravity energy storage mainly in the coupling with hydroelectric basins. However other possibilities has been explored and in particular CAES systems have been suggested. #Environment control: a parallel advantage is the containment of the algae bloom, a serious problem in industrialized countries.
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Tidarren argo is a spider from Yemen. The species is remarkable by its male amputating one of its palps before maturation and entering his adult life with one palp only. It adopts exceptional copulatory behaviour: when the male achieves genitalia coupling with his palp, the latter is torn off by the female. The separated gonopod remains attached to the female's epigynum for approximately 4 hours and continues to function independently, serving as a mating plug.
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In this step, the Sandmeyer reaction converts the primary amino group (NH2) to a diazonium leaving group (N2), which is subsequently replaced by iodine. Iodine serves as an excellent coupling partner for the attachment of the stomach, which is executed through Sonogashira coupling with trimethylsilylacetylene to yield 3,5-dibromo(trimethylsilylethynyl)benzene. Attachment of the legs replaces the Br substituents with 1-pentyne through another Sonogashira coupling to produce 3,5-(1′-Pentynyl)-1-(trimethylsilylethynyl) benzene.
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In cryptography, MULTI-S01 (pronounced multi-ess-zero-one), is an encryption algorithm based on a pseudorandom number generator (PRNG). MULTI-S01 is an encryption scheme preserving both confidentiality and data integrity. The scheme defines a pair of algorithms; the encryption, the corresponding decryption with verification. Coupling with an efficient keystream generator, such as Panama, MUGI, and RC4, the algorithm efficiently encrypts a message in the manner of a single path process, i.e.
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Using a single foot pedal, the ABS SuperSteer allows the tractor to be steered by the brakes. Two orange pedal extensions either side of a single pedal replace the conventional, independent two-pedal arrangement. At low speed, this provides the driver with the same single-wheel steering as a conventional tractor, but automatically disables at higher speeds to prevent accidental application. The ABS SuperSteer function includes tyre slip control and automatic coupling with the steering angle.
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George Raft was meant to star but could not get released from Warner Bros. John Payne was going to star in Song of the Islands but was assigned to this movie instead; Victor Mature replaced Payne on Islands. The original planned ending was a simple romantic coupling with Maureen O'Hara's Navy nurse, but after Pearl Harbor, it switched to John Payne signing up for war. Portions of the film were shot at the Marine Corps Recruit Depot San Diego.
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Gentle chases Pie away, but Pie, who has the ability to change his exterior, later disguises himself as Judith and comes to Gentle's apartment with the intent of having sex with him. During their tryst, Judith calls, alerting Gentle to the fact that he is in fact coupling with the shape-shifting assassin. Gentle is horrified and demands that Pie leave. Meanwhile, the Tabula Rasa meet at Roxborough Tower to discuss the recent events regarding Pie'oh'pah.
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Michael Whitney of The Webcomics Examiner said that, though Bobbinss suffered from Allison's lack of experience at the time, the early strips were well drawn regardless. Whitney stated that Allison incorporated his flaws into a consistent and satisfying style. Allison himself has said that Bobbins was "pretty rough and variable in quality," but that he "learned [his] craft" drawing it.Jon As for the story, Stephen Gerding described Bobbins as similar to Friends, or Coupling with an office atmosphere.
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There were four Nebelwerfers (Smoke Mortars) behind the driver. There was also a rotary coupling with a number of angle mirrors, and a hatch mounted on a pivot mount MG 51. The entry and exit hatch was on the left side of the battle space above the height of the chain guide roller and the first roller. At the front of the vehicle is a hydraulically operated dozer blade attached crane-like and winch-like operations.
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In 1867 the invention of Garcin of wooden wheels was picked up by some Englishmen that the industrial perfected. James Leonard Plinton the patented in New York, but the coupling with a wad of rubber on the front that allowed halt when ibas backward and forward to boot. In 1867 opened the first center in paris skating for the aristocracy. From that time began to have many clues, wood (being the most resistant wooden wheels), across Europe.
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Since the percentage of 13C is so low in natural isotopic abundance samples, the 13C coupling effects on other carbons and on 1H are usually negligible, and for all practical purposes splitting of 1H signals due to coupling with natural isotopic abundance carbon does not show up in 1H NMR spectra. In real life, however, the 13C coupling effect does show up on non-13C decoupled spectra of other magnetic nuclei, causing satellite signals. Similarly for all practical purposes, 13C signal splitting due to coupling with nearby natural isotopic abundance carbons is negligible in 13C NMR spectra. However, practically all hydrogen bonded to carbon atoms is 1H in natural isotopic abundance samples, including any 13C nuclei bonded to H atoms. In a 13C spectrum with no decoupling at all, each of the 13C signals is split according to how many H atoms that C atom is next to. In order to simplify the spectrum, 13C NMR spectroscopy is most often run fully proton decoupled, meaning 1H nuclei in the sample are broadly irradiated to fully decouple them from the 13C nuclei being analyzed.
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For a time Marshal Moncey was simply nowhere to be found; at length his defeat at the gates of Valencia surfaced; some 17,000 Spaniards under the Conde de Cervellón massed victoriously around that city as Moncey gave up in disgust, having lost 1,000 men in a vain attempt to storm the walls.Chandler, p. 614Esdaile (2003), p. 68 Suddenly, all prospects evaporated of Moncey's corps pivoting west from Valencia toward Granada and coupling with Dupont in a two-pronged invasion of Andalusia.
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Moreover, SK2, small-conductance Ca2+-activated K+ channel, changes the shape of excitatory postsynaptic potentials (EPSPs) by coupling with N-methyl D-aspartate receptors (NMDA receptors). The research by Lin MT, et al. was designed to investigate whether SK2 channels participate in synaptic changes when an activity-dependent decrease contributes to LTP. SK2 channels are ion channels that are activated by an increasing in the concentration of intracellular calcium and as a result of allowing K+ cation to cross the cell membrane.
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London Stock Exchange Group acquired Turquoise (TQ), a Pan-European MTF, in 2009 and since coupling with MillenniumIT's software, it currently offers the fastest latency of any in Europe. Currently the speed of latency on Turquoise (as measured at the end of August 2011) is 97 microseconds on average for 99.9% of trades. Initially founded by a consortium of nine banks, it is now majority-owned by the London Stock Exchange Group. Currently shareholders include twelve of the leading investment banks.
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Many decarboxylative cross coupling reactions involve the breaking of sp2C–COOH and spC–COOH bonds, therefore subsequent studies have attempted to enable cross coupling with sp3C carboxylic acids. One such reaction by Shang et al. described a palladium catalyzed cross coupling that enables the formation of functionalized pyridines, pyrazines, quinolines, benzothiazoles, and benzoxazoles. The position of the nitrogen atom in the '2' position relative to the linkage is found to be required, therefore implying its binding to Pd in a transition state.
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1) generates a magnetic dipole moment whose coupling with the electromagnetic field provides the signature of the mode. Scissors Mode in atomic nuclei: the proton (p) and neutron (n) rotors precess around their bisector. Such states have been experimentally observed for the first time by A. Richter and collaborators in a rare earth nucleus, 156Gd, and then systematically investigated experimentally and theoretically in all deformed atomic nuclei. Inspired by this, D. Guéry-Odelin and S. Stringari predicted similar collective excitations in Bose-Einstein condensates in magnetic traps.
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This powerful carbon-carbon bond forming cross-coupling reactions combines an organic halide and an organozinc halide reagent in the presence of a nickel or palladium catalyst. The organic halide reactant can be alkenyl, aryl, allyl, or propargyl. Alkylzinc coupling with alkyl halides such as bromides and chlorides have also been reported with active catalysts such as Pd-PEPPSI precatalysts, which strongly resist beta-hydride elimination (a common occurrence with alkyl substituents).S. Sase, M. Jaric, A. Metzger, V. Malakhov, P. Knochel, J. Org. Chem.
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He have a sharp finishing, great individual skill and great header. Coupling with Zah Rahan Krangar often intimidating opponent. Just before the 2016 season kicked off, Thiago suffered a lengthy injury that sidelined him from then Felda United head coach Irfan Bakti Abu Salim's squad, although the club still kept Thiago under contract. But when the mid-season transfer window opened, Irfan decided against listing him in the competitions squad to avoid disrupting the already- established team dynamics, and loaned him out to Kedah.
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The introduction of a natural semiconductor material within or as part of each metamaterial cell results in a new design flexibility. The incorporation, application, and location of semiconductor material is strategically planned so as to be strongly coupled at the resonance frequency of the metamaterial elements. The hybrid metamaterial composite is still a passive material. However, the coupling with the semiconductor material then allows for external stimulus and control of the hybrid system as a whole, which produces alterations in the passive metamaterial response.
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Part of the rotational spectrum of trifluoroiodomethane, .The spectrum was measured over a couple of hours with the aid of a chirped-pulse Fourier transform microwave spectrometer at the University of Bristol. Each rotational transition is labeled with the quantum numbers, J, of the final and initial states, and is extensively split by the effects of nuclear quadrupole coupling with the 127I nucleus. Rotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase.
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Rather than being grateful, Ixion became lustful toward's Zeus's wife, Hera. Zeus found out about his intentions and created the cloud Nephele in the shape of Hera, and tricked Ixion into coupling with it, fathering the race of Centaurs. For his crimes, Ixion was expelled from Olympus, blasted with a thunderbolt, and bound to a burning solar wheel in the underworld for all eternity. The name for Ixion was suggested by James Elliot, who was involved in its discovery by the Deep Ecliptic Survey team.
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The pattern of a mother-goddess coupling with a young male deity was widespread in the entire pre-Aryan and pre-Semitic cultural zone of Orient from Southwest Asia to the Eastern Mediterranean. In this pattern, the Mother, like a goddess of fertility, was often accompanied by a young male deity who was both her son and later her husband after his father's demise: Astaroth with Tammuz, Kybele with Attis, etc. Often from sexual unions with their son-husbands, some goddesses bore numerous offsprings.
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In contrast to catabolic pathways, anabolic pathways require an energy input to construct macromolecules such as polypeptides, nucleic acids, proteins, polysaccharides, and lipids. The isolated reaction of anabolism is unfavorable in a cell due to a positive Gibbs Free Energy (+ΔG). Thus, an input of chemical energy through a coupling with an exergonic reaction is necessary. The coupled reaction of the catabolic pathway affects the thermodynamics of the reaction by lowering the overall activation energy of an anabolic pathway and allowing the reaction to take place.
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This full proton decoupling eliminates all coupling with H atoms and thus splitting due to H atoms in natural isotopic abundance compounds. Since coupling between other carbons in natural isotopic abundance samples is negligible, signals in fully proton decoupled 13C spectra in hydrocarbons and most signals from other organic compounds are single peaks. This way, the number of equivalent sets of carbon atoms in a chemical structure can be counted by counting singlet peaks, which in 13C spectra tend to be very narrow (thin).
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This reflux releases free energy produced during the generation of the oxidized forms of the electron carriers (NAD+ and Q). The free energy is used to drive ATP synthesis, catalyzed by the F1 component of the complex. Coupling with oxidative phosphorylation is a key step for ATP production. However, in specific cases, uncoupling the two processes may be biologically useful. The uncoupling protein, thermogenin—present in the inner mitochondrial membrane of brown adipose tissue—provides for an alternative flow of protons back to the inner mitochondrial matrix.
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Typical reactions are conducted at 130 °C. This reaction probably proceeds via an SN2 mechanism with primary alcohols but SN1 pathway with secondary alcohols. :300px Zinc chloride also activates benzylic and allylic halides towards substitution by weak nucleophiles such as alkenes: :480px In similar fashion, ZnCl2 promotes selective NaBH3CN reduction of tertiary, allylic or benzylic halides to the corresponding hydrocarbons. Zinc chloride is also a useful starting reagent for the synthesis of many organozinc reagents, such as those used in the palladium catalyzed Negishi coupling with aryl halides or vinyl halides.
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Membranes offer the advantage over rigid structures of being compliant and low mass, which can produce more direct coupling with the wave's energy. Their compliant nature also allows for large changes in the geometry of the working surface, which can be used to tune the response of the converter for specific wave conditions and to protect it from excessive loads in extreme conditions. A submerged converter may be positioned either on the seafloor or in midwater. In both cases, the converter is protected from water impact loads which can occur at the free surface.
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Ideally, the stubs should project on alternate sidesLee, p. 789 to prevent them coupling with each other, taking up further space, although this is not always done for space considerations. More than that, the cascade connected elements that couple together the stubs contribute nothing to the frequency function, they are only there to transform the stubs into the required impedance. Putting it another way, the order of the frequency function is determined solely by the number of stubs, not by the total number of UEs (generally speaking, the higher the order, the better the filter).
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For example, when the rat explores a maze, place cell sequences in the different arms of the maze are replayed either in a forward (as during the experience itself) or reverse order, but compressed in time several-fold. SPW-R are temporally linked to both sleep spindles and slow oscillations of the neocortex. Interfering with SPW-Rs or its coupling with neocortical slow oscillations results in memory impairment, which can be as severe as surgically damaging the hippocampus and/or associated structures. SPW-R is therefore the most prominent physiological biomarker of episodic (i.e.
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Assembled chamber containing the acrylamide gel is exposed to UV light to allow polymerization in only those positions of the chamber that are situated directly under the transparent windows. Oligonucleotides or DNA fragments need to be activated to contain chemically reactive groups to facilitate coupling with the activated gel elements. Probe activation depends on the chemistry of activation of the polyacrylamide gels. Thus to immobilize in the aldehyde-containing gel the probe should have reactive amino group and if the gels are activated by introduction of amino groups, the probes should contain free aldehyde group.
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Coupling with the host is fatal, causing the host's partner to disintegrate into a pile of dust at climax and allowing the alien to absorb the energy from the orgasm. It appeared to know human biology well (or at least just enough), knowing it needed the opposite gender in order to get the energy. It was tricked out of its host and left in a portable energy prison until it expired from being poisoned by the earth's air. The BBC Torchwood website lists it as the "Sex gas".
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Many of the photocatalytic systems can benefit from the coupling with a noble metal; the first Fujishima-Honda cell made use of a co- catalyst plate as well. For instance, the essential design of a disperse photocatalytic reactor for water splitting is that of a water sol in which the dispersed phase is made up of semiconductor quantum dots each coupled to a metallic co-catalyst: the QD converts the incoming electromagnetic radiation into an exciton whilst the co-catalyst acts as an electron scavenger and lowers the overpotential of the electrochemical reaction.
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This results in only the most common optical effects, such as ordinary refraction with common diffraction limitations in lenses and imaging. Since the beginning of optical sciences, centuries ago, the ability to control the light with materials has been limited to these common optical effects. Metamaterials, on the other hand, are capable of a very strong interaction, or coupling, with the magnetic component of light. Therefore, the range of response to radiated light is expanded beyond the ordinary optical limitations that are described by the sciences of physical optics and optical physics.
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GWR Pannier Tank with Autocoach on Bodmin & Wenford Railway One of the earliest remote control locomotives was the GWR Autocoach, which replaced the GWR steam rail motors on both operational cost and maintenance grounds. When running 'autocoach first', the regulator is operated by a linkage to a rotating shaft running the length of the locomotive, passing below the cab floor. This engages (via a telescopic coupling) with another shaft running the full length below the floor of the autocoach. This shaft is turned by a second regulator lever in the cab of the autocoach.
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In the initial synthesis, cycloparaphenylenes with n = 9, 12, and 18 have been synthesized starting from macrocycles containing 1,4-syn-dimethoxy-2,5-cyclohexadiene units as masked aromatic rings. Lithium–halogen exchange with p-diiodobenzene followed by a two-fold nucleophilic addition reaction with 1,4-benzoquinone yielded a syn- cyclohexadiene moiety. Borylation of this material followed macrocyclization under Suzuki–Miyuara cross-coupling with an equivalent of the diiodide produced macrocycles in low yields which could be separated by column chromatography. These macrocycles were then reductively aromatized using sodium naphthalenide to yield [n]cycloparaphenylenes.
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In continuous flow fast atom bombardment (CF-FAB), the sample is introduced into the mass spectrometer insertion probe through a small diameter capillary. (CF)-FAB was developed to minimize the problem of poor detection sensitivity that is caused by an excess of the matrix background that results in a high matrix-to-sample ratio. When a metal frit is used to disperse the liquid on the probe, the technique is known as frit FAB. Samples can be introduced by flow injection, microdialysis, or by coupling with liquid chromatography.
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It is the electrochemical gradient created that drives the synthesis of ATP via coupling with oxidative phosphorylation with ATP synthase. The electron transport chain, and site of oxidative phosphorylation is found on the inner mitochondrial membrane. The energy stored from the process of respiration in reduced compounds (such as NADH and FADH) is used by the electron transport chain to pump protons into the inter membrane space, generating the electrochemical gradient over the inner mitochrondrial membrane. In photosynthetic eukaryotes, the electron transport chain is found on the thylakoid membrane.
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LY-2140023 was identified using the analogous peptide prodrug approach used previously for talaglumetad, the prodrug of eglumetad. Synthesis was the result of preparation of LY-389795 followed by oxidation to LY-404,039 and coupling with L-methionine. LY-2140023 uses a human peptide transporter and hydrolytic pathways to deliver LY-404,039 to systemic circulation in humans.Eli Lilly and Company - Lilly Announces Inconclusive Phase II Study Results for mGlu2/3 at the International Congress on Schizophrenia Research, Eli Lilly, 29 March 2009 It is rapidly absorbed and hydrolyzed to produce active LY-404,039 (~70% conversion), increasing its estimated bioavailability to 49%.
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The interactions of the new fermions are restricted to dimension-four quartic self interaction, and also to a dimension-four coupling with the Higgs. A generalised Yukawa coupling of the new fermions with neutrinos provides an hitherto unsuspected source of lepton-number violation. The new fermions thus present a first- principle dark matter partner to Dirac fermions of the standard model with contrasting mass dimensions — that of three halves for the latter versus one of the former without mutating the statistics from fermionic to bosonic. Mass dimension one fermionic field of spin one half uses ELKO as its expansion coefficients.
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25, PL 145, 975C, Vita Adalberti, ch. 23, MGH, SS 4, 591 Hildegard of Bingen reported seeing visions and recorded them in Scivias (short for Scito vias Domini, "Know the Ways of the Lord"). In Book II Vision Six, she quotes God as condemning same-sex intercourse, including lesbianism; "a woman who takes up devilish ways and plays a male role in coupling with another woman is most vile in My sight, and so is she who subjects herself to such a one in this evil deed"."Scivias", translated by Columba Hart and Jane Bishop, 1990; p. 279.
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Increase in regional cerebral blood flow (rCBF) shows larger activation for direct than averted gaze in this area George, N., Driver, J., & Dolan, R. J. (2001) Seen gaze-direction modulates fusiform activity and its coupling with other brain areas during face processing. NeuroImage, 13(6), 1102-1112.. It has been suggested that this increased activation is related to initial increased face encoding. However, these effects are absent when one has already been presented with a face and its gaze shifts towards the participant. This indicates that when attending to face identity, face encoding effects can be masked.
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Invented early in the 20th century, the fluid coupling was the answer to the question of how to avoid stalling the engine when the vehicle was stopped with the transmission in gear. Chrysler itself never used the fluid coupling with any of its automatic transmissions, but did use it in conjunction with a hybrid manual transmission called "Fluid Drive" (the similar Hy-Drive used a torque converter). These developments in the automatic gearbox and fluid coupling technology eventually culminated in the introduction in 1939 of the General Motors Hydra-Matic, the world's first mass-produced automatic transmission.
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Hiyama Lab Website--About Hiyama In 1992, he re-entered the world of academia at the Tokyo Institute of Technology as a professor of the Research Laboratory of Resources Utilization. He then returned to Kyoto University in 1997 as a professor of engineering, until 2010 when he transferred to Chuo University, where he currently holds tenure. His current research focuses on C-H activation and cross-coupling reactions. In particular, he is interested in ortho and benzylic C-H activation, and C-C, C-N, and C-Si bond formation via cross-coupling with organosilicon reagents.
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The link between engine and coaches would be an automatic coupling with brake and air pipes. On 10 January 1934, when the Reichsbahn locomotive expert, Friedrich Fuchs, met the representatives of Henschel and Wegmann, he confronted them however with a proposal for a train with four eight-wheeled coaches instead of the two-coach train. To meet this new requirement, Henschel designed a 4-6-4 tank engine and presented the resulting project study report on 27 March 1934 to the Reichsbahn head office. On 28 August, the Reichsbahn officially contracted Henschel and Wegmann to build the train.
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Later on, she starts liking him after protecting her against harm. Meanwhile, Koteswara Rao dies out of a heart attack, entrusting the entire property to Amala and assigns her responsibility to his Lawyer friend Chidanandam (Allu Ramalingaiah). Right now, Amala is surrounded by many relatives, her younger maternal uncle Gandabherundam (Gollapudi Maruti Rao) and paternal aunt Kanthamma (Suryakantham) who plot to usurp her wealth by coupling with their sons Prasad (Prasad Babu) & Buchi (Ramana Reddy) respectively. Aside, Bhushaiah looks a match for Gopi when Papa Rao intrigues and spoils it by posing Gopi as a drunkard.
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Inspection robots using other types of sensors have been considered before, such as the European project Robair. Since the launch of the project, other solutions based on image processing began to be developed, such as EasyJet with a drone, the swarm of drones from Toulouse company Donecle and the Aircam project of the aerospace manufacturer Airbus. Since the beginning of the project in 2013, the Air-Cobot robot is dedicated to inspect the lower parts of an aircraft. In the continuation of the project, there is the prospect of coupling with a drone to inspect an aircraft's upper parts.
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One of the earliest serious and large scale attempts at an ICF driver design was the Shiva laser, a 20-beam neodymium doped glass laser system built at the LLNL that started operation in 1978. Shiva was a "proof of concept" design intended to demonstrate compression of fusion fuel capsules to many times the liquid density of hydrogen. In this, Shiva succeeded and compressed its pellets to 100 times the liquid density of deuterium. However, due to the laser's strong coupling with hot electrons, premature heating of the dense plasma (ions) was problematic and fusion yields were low.
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When Zeus had pity on Ixion and brought him to Olympus and introduced him to the gods, instead of being grateful, Ixion grew lustful for Hera. Zeus found out about his intentions and made a cloud in the shape of Hera, who was later named Nephele, and tricked Ixion into coupling with it and from their union came Centaurus. So Ixion was expelled from Olympus and Zeus ordered Hermes to bind Ixion to a winged fiery wheel that was always spinning. Therefore, Ixion was bound to a burning solar wheel for all eternity, at first spinning across the heavens, but in later myth transferred to Tartarus.
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The Denby Eco-Link, with a Ford Mondeo positioned in front of the A-Trailer, which sits between the standard tractor unit and semi-trailer of a full size normal UK articulated lorry. The two middle axles are rigidly attached to the A-Trailer and support the fifth wheel coupling with which the rear trailer is towed. The A-Trailer wheels electronically counter steer with respect to the tractor unit. While the Denby Eco-Link is in the catch all category of a Longer Heavier Vehicle (LHV), in particular, it achieves this using a vehicle configuration known as a "B-Train" or "B-Double".
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Geophone SM-24 A geophone is a seismic receiver that is often chosen in land acquisition to monitor the particle velocity in a certain orientation. A geophone can either be a single-component geophone which is designed to record p-waves (compressional waves), or it can be a multi-component geophone designed to record p-waves and s-waves (shear waves). Geophones require sufficiently strong coupling with the ground to record the true ground motion initiated by the seismic signal. This is of considerable importance for higher frequency components of the seismic signals, which can be altered substantially with respect to their phase and amplitude due to poor coupling.
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Roto Hydramatic (sometimes spelled Roto Hydra-Matic or Roto-Hydramatic) was an automatic transmission built by General Motors and used on some Oldsmobile, Pontiac and Holden models from 1961-1965\. It was based on the earlier, four- speed Hydramatic, but was more compact, providing only three forward speeds plus a small 8" fluid coupling with a stator inside of the fluid coupling (a type of torque converter, only integral with the transmission rather than being an independent unit). Oldsmobile, one of the users of this transmission, called the fluid couplings stator the "Accel-A-Rotor." The lightweight, aluminum-cased transmission was sometimes nicknamed the "Slim Jim.
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Available as an option in 1940 Oldsmobiles and later Cadillacs, the Hydra-Matic combined a fluid coupling with three hydraulically controlled planetary gearsets to produce four forward speeds plus reverse. The transmission was sensitive to engine throttle position and road speed, producing fully automatic up- and down-shifting that varied according to operating conditions. The Hydra-Matic was subsequently adopted by Cadillac and Pontiac, and was sold to various other automakers, including Bentley, Hudson, Kaiser, Nash, and Rolls-Royce. It also found use during World War II in some military vehicles. From 1950 to 1954, Lincoln cars were also available with the Hydra-Matic.
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The main reasons for employing concentrating collectors in solar cooling systems are: high efficient air-conditioning through coupling with double/triple effect chillers; and solar refrigeration serving industrial end-users, possibly in combination with process heat and steam. Concerning industrial applications, several studies in the recent years highlighted that there is a high potential for refrigeration (temperatures below 0 °C) in different areas of the globe (e.g., the Mediterranean, Central America). However, this can be achieved by ammonia/ water absorption chillers requiring high temperature heat input at the generator, in a range (120 ÷ 180 °C) which can only be satisfied by concentrating solar collectors.
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E COSY experiment: A and B are the two parts of the detected signal. Exclusive correlation spectroscopy (ECOSY) is an NMR correlation experiment introduced by O. W. Sørensen, Christian Griesinger, Richard R. Ernst and coworkers for the accurate measurement of small J-couplings. The idea behind the experiment is to measure an unresolved coupling with the help of a larger coupling which is resolved in a dimension orthogonal to the small coupling. Three active nuclei are needed (SXI spin system) and the pulse sequence must be able to transfer magnetization from I to S without changing the spin state of X, otherwise the ECOSY pattern will vanish.
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The "walk through head" in operation The train's name Koploper means "Frontrunner" but the name can also be seen as a reference to "walking through the head" ("Headwalker"(Dutch: "Doorloopkop")). When ICM units joined, the doors at the end of the train would come out, and a walkway would emerge, coupling with the other set and allowing passengers and crew to walk through to the next set. (This makes it easy for conductors to check tickets and check on the security of the passengers. In addition, each set had catering cars before they were abolished in 2003.) However, since 31 October 2005, these were put out of use.
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Resurrection of Eve is a 1973 American feature-length pornographic film produced by the Mitchell brothers and starring Marilyn Chambers, who had become a star in the Mitchell Brothers's previous picture, Behind the Green Door. Resurrection of Eve was directed and written by Jon Fontana and Artie Mitchell. Though less successful commercially and critically than Behind the Green Door, it is considered one of the films of The Golden Age of Porn. Like Behind the Green Door, it featured interracial sex, including a reprise of Chambers' coupling with her Green Door co-star Johnnie Keyes, but broke new ground in a film targeting a heterosexual audience by included shots of gay fellatio.
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Each subsequent reaction in the series increases the number of available surface groups exponentially. Core molecules which give rise to PAMAM dendrimers can vary, but the most basic initiators are ammonia and ethylene diamine. Outward growth of PAMAM dendrimers is accomplished by alternating between two reactions: # Michael addition of the amino-terminated surface onto methyl acrylate, resulting in an ester- terminated outer layer, and # Coupling with ethylene diamine to achieve a new amino-terminated surface. Each round of reactions forms a new "generation", and PAMAM dendrimers are often classified by generation number; the common shorthand for this classification is "GX" or "GX PAMAM", where X is a number referring to the generation number.
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As VNFs replace traditional function-dedicated equipment, there is a shift from equipment-based availability to a service-based, end-to-end, layered approach.'NETWORK FUNCTIONS VIRTUALIZATION CHALLENGES AND SOLUTIONS', TMCNET webpage, Alcatel-Lucent Strategic paper, 2013'NFV: The Myth of Application- Level High Availability ', Wind River White Paper, May 2015 Virtualizing network functions breaks the explicit coupling with specific equipment, therefore availability is defined by the availability of VNF services. Because NFV technology can virtualize a wide range of network function types, each with their own service availability expectations, NFV platforms should support a wide range of fault tolerance options. This flexibility enables CSPs to optimize their NFV solutions to meet any VNF availability requirement.
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Re-qualification of machinery/equipment should also be conducted when replacement of parts, or coupling with another device, or installing a new application software and restructuring of the computer which affects especially the pre-settings, such as on BIOS, registry, disk drive partition table, dynamically-linked (shared) libraries, or an ini file etc., have been necessary. In such a situation, the specifications of the parts/devices/software and restructuring proposals should be appended to the qualification document whether the parts/devices/software are genuine or not. Torres and Hyman have discussed the suitability of non-genuine parts for clinical use and provided guidelines for equipment users to select appropriate substitutes which are capable to avoid adverse effects.
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Arenediazonium salts have been reported as an alternative to aryl halides for the Sonogashira coupling reaction. Gold(I) chloride has been used as co-catalyst combined with palladium(II) chloride in the coupling of arenediazonium salts with terminal alkynes, a process carried out in the presence of bis-2,6-diisopropylphenyl dihydroimidazolium chloride (IPr NHC) (5 mol%) to in situ generate a NHC–palladium complex, and 2,6-di-tert-butyl-4-methylpyridine (DBMP) as base in acetonitrile as solvent at room temperature. This coupling can be carried out starting from anilines by formation of the diazonium salt followed by in situ Sonogashira coupling, where anilines are transformed into diazonium salt and furtherly converted into alkyne by coupling with phenylacetylene.
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Reserves are synthesized from environmental substrates (food) for use by the metabolism for the purpose of somatic maintenance (including protein turnover, maintenance of concentration gradients across membranes, activity and other types of work), growth (increase of structural mass), maturity maintenance (installation of regulation systems, preparation for reproduction, maintenance of defense systems, such as the immune system), maturation (increase of the state of maturity) and reproduction. This organizational position of reserve creates a rather constant internal chemical environment, with only an indirect coupling with the extra-organismal environment. Reserves as well as structure are taken to be generalised compounds, i.e. mixtures of a large number of compounds, which do not change in composition.
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There is no reason to make the chunk larger than the core; a large chunk would not localize the scars sufficiently to provide coupling with the core. There is no reason to localize the scars within an angle smaller than the core: the small derivative to the radius makes the manufacturing less robust; the larger R'(\phi) is, the larger the fluctuations of shape that are allowed without breaking the condition R'(\phi)>0. Therefore, the size of the chunk should be of the same order as the size of the core. More rigorously, the property of the spiral-shaped domain follows from the theorem about boundary behavior of modes of the Dirichlet Laplacian.
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In the early 1990s, Waltham, Massachusetts-based Expressway Technologies, Inc. developed the Expressway 103, a column-based, engine optimized for analytics, that would eventually become Sybase IQ. Sybase acquired Expressway and re-introduced the product in 1995 as IQ Accelerator, then renamed it shortly thereafter to Sybase IQ, giving it version number 11.0. By offering the IQ product as part of a collection of related technologies often found in a data warehouse (including Sybase Adaptive Server Enterprise, Replication Server, PowerDesigner PowerDesigner, and SQL Anywhere), Sybase became one of the first mainstream companies to acknowledge the need for specialized products for the data warehouse market. With version 12.0, Sybase replaced the loosely coupled query interface from Adaptive Server Enterprise with a tight coupling with SQL Anywhere.
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Consequently, most webMethods adapters developed for wM IS 4.6 or wM IS 6.0 should still run on an SAP BC 4.7, with the exception of those adapters that have a tight coupling with the WmPartners package. SAP BC 4.7 was released in June 2003. By that time SAP had already started development of its own integration/middleware product ("Message Broker", later renamed to "Exchange Infrastructure" (SAP XI), nowadays called "Process Integration" (SAP PI)), so the SAP Business Connector product line was frozen at version 4.7 between 2003 and 2007. Then, in summer 2007, it became more and more apparent, that the maintainability of SAP BC 4.7 was endangered, because most operating systems and Java VM versions, on which the BC depended, had gone out of maintenance.
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Later on, he worked with bands led by Phil Napoleon and Pee Wee Erwin before joining the Dukes of Dixieland in 1962. The late 1960s found him freelancing with, among others, Red Allen, Ralph Sutton, Yank Lawson and his lifelong friend Dick Wellstood. At this time, he had also taken up the soprano saxophone, and when a spontaneous coupling with fellow reedman Bob Wilber at Dick Gibson's Colorado Jazz Party turned out be a huge success, one of the most important jazz groups of the 1970s, Soprano Summit, was born. Co-led by Wilber and Davern, both switching between the clarinet and various saxophones, during the next five years Soprano Summit enjoyed a very successful string of record dates and concerts.
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Ecclesia enthroned, 12th century, Prüfening Abbey, Bavaria Parable of the Wise and Foolish Virgins (top registers), Speculum Humanae Salvationis in Darmstadt, c. 1360 The personification of Ecclesia preceded her coupling with Synagoga by several centuries. A number of biblical passages, including those describing Christ as a "bridegroom" led early in the history of the church to the concept of the church as the Bride of Christ, which was shown in art using a queenly personification. The church was in this context sometimes conflated with the Virgin Mary, leading to the concept of Maria Ecclesia, or Mary as the church, which is an element, now usually unrecognised, in the theology behind much of the art showing the Virgin as a queen.
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Reaction of carbon monoxide (CO), hydrogen sulfide (H2S) and methanethiol CH3SH in the presence of nickel sulfide and iron sulfide generates the methyl thioester of acetic acid [CH3-CO-SCH3] and presumably thioacetic acid (CH3-CO-SH) as the simplest activated acetic acid analogues of acetyl-CoA. These activated acetic acid derivatives serve as starting materials for subsequent exergonic synthetic steps. They also serve for energy coupling with endergonic reactions, notably the formation of (phospho)anhydride compounds. However, Huber and Wächtershäuser reported low 0.5% acetate yields based on the input of CH3SH (Methanethiol) (8 mM) in the presence of 350 mM CO. This is about 500 times and 3700 times the highest CH3SH and CO concentrations respectively measured to date in a natural hydrothermal vent fluid.
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Ciri takes a quick shine to Geralt and explains that she is a princess and was going to be married off to Prince Kistrin, son of King Ervyll, but ran away. Braenn, Geralt, and Ciri arrive in Duen Canell, the heart of Brokilon. Freixenet's wounds have been being treated, as the dryads intend for him to impregnate some of them (Geralt was used for the same purpose when he last visited Brokilon, but his coupling with Eithne's daughter failed to produce any offspring). Ciri begins to realize that the dryads plan to keep her--the dryads are fighting an unending war for the forest and bolster their numbers by taking and brainwashing young girls into the dryad culture (of which Braenn once was one).
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Field's list of "Places of Interest to Visit" in South America reflected his interests, including business interests: bridges, volcanoes, waterfalls, and cities, as well as gold mines and the emerald mines of Muzo. Field turned his attention to telegraphy after he was contacted in January 1854 by Frederick Newton Gisborne, a Canadian engineer, who aimed to establish a telegraph connection between St. John's, Newfoundland and New York City, started the work, but failed due to the lack of capital. Later that year he, with Peter Cooper, Abram Stevens Hewitt, Moses Taylor and Samuel F.B. Morse, joined the so-called Cable Cabinet of entrepreneurs, investors and engineers. Through this Cable Cabinet, Field became instrumental in laying a telegraph line connecting St. John's, Newfoundland with Nova Scotia, coupling with telegraph lines from the U.S.Jane A. Stewart.
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Electricity from wood through the combination of gasification and solid oxide fuel cells, Ph.D. Thesis by Florian Nagel, Swiss Federal Institute of Technology Zurich, 2008Characterization of biomass producer gas as fuel for stationary gas engines in combined heat and power production, Ph.D. Thesis by Jesper Ahrenfeldt, Technical University of Denmark March 2007High temperature electrolyte supported Ni-GDC/YSZ/LSM SOFC operation on two-stage Viking gasifier product gas , Ph. Hofmann et al. in Journal of Power Sources 173 (2007) 357–366 Mechanical energy from the engines may be used for e.g. driving water pumps for irrigation or for coupling with an alternator for electrical power generation. While small scale gasifiers have existed for well over 100 years, there have been few sources to obtain a ready to use machine.
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For their first date he escorts her to a party at Bernice's apartment. Complications arise when April discovers she is pregnant, the result of a quick and clumsy coupling with Ben on the kitchen floor just before he left her. April has longed to have a child all her life and is delighted with the news, but is confused and upset by Ben's sudden return, Frank's hasty departure (when he discovers April and Ben had a "quickie" after visiting the gynecologist), and Bernice's insistent attempts to create a bond between them. Not helping the situation is the discovery Bernice voluntarily put her up for adoption a full year after her birth and not three days later at the urging of her parents, according to the scenario she initially presented.
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Titles included "Mariowave", "Nostalgia 64", and "Z E L D A W A V E". Dazed Digitals Evelyn Wang credited Lean with "allowing vaporwave to leak IRL [and] encouraging its unholy coupling with streetwear". She cited their associated fashion staples as "frowny faces, Japanese and Arabic as accessories, sportswear brands, Arizona iced tea, and the uncanny ability to simultaneously communicate in and be a meme." At the end of 2013, Thump published an essay headlined "Is Vaporwave the Next Seapunk?" Although the author prophesied that vaporwave would not end "as a joke" the way seapunk did, the genre came to be largely viewed as a facetious Internet meme based predominately on a retro visual style or "vibe", a notion that frustrated some producers who wished to be recognized as serious artists.
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The reality was one of resentment over a perceived break-down in one-on-one exchanges arising from women being sent to the wrong, rather than the right, clan they were contracted to marry into. A Potaruwutj big man with a repute for powerful magic, Dongaganinj, composed a pelekaw refrain which articulated these feelings of grievance. The neighbouring Meintangk, who sided with the Tanganekeld, on hearing this rude insinuation, composed a slanderous weritjinj variant on the pelekaw song which both slandered the Potaruwutj and challenged them to battle at the traditional combat grounds at Nunukapul (Telauri Flat) near Marcollat station. This song, chanted while men danced imitating their enemies coupling with dogs, rang: A resolutive battle was arranged, and seven warriors were left dead on the Nunukapul field.
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The structure of the norbornylpalladium intermediate does not allow for β-hydride elimination at either of the β-positions due to Bredt's Rule for the bridgehead β-hydrogen and the trans-configuration between palladium and other β-hydrogen. Thereafter, the Pd(II) species undergoes electrophilic cyclopalladation at the ortho position of the aryl group. Subsequently, the palladacyclic intermediate undergoes a second oxidation addition with the alkyl halide coupling partner to form a Pd(IV) intermediate, which undergoes reductive elimination to forge the first C–C bond of the product. After β-carbon elimination of norbornene, the resultant Pd(II) species then undergoes a second C–C bond forming step via a Heck reaction or cross coupling with an organoboron reagent to afford the final organic product and close the catalytic cycle.
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This statement is enhanced by the fact that many linear molecules in nondegenerate states (and hence with no RTE) are, too, bent in the equilibrium configuration. The physical reason for the difference between the PJTE and the RTE in influencing the degenerate term is that while in the former case the vibronic coupling with the excited state produces additional covalent bonding that makes the distorted configuration preferable (see above, section 2.3), the RTE has no such influence; the splitting of the degenerate term in the RTE takes place just because the charge distribution in the two states becomes nonequivalent under the bending distortion. Peierls distortions in linear chains. In linear molecules with three or more atoms there may be PJTE distortions that do not violate the linearity but change the interatomic distances.
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The first full cycle of Michael addition followed by coupling with ethylene diamine forms Generation 0 PAMAM, with subsequent Michael additions giving rise to "half" generations, and subsequent amide coupling giving rise to "full" (integer) generations. With divergent synthesis of dendrimers, it is extremely important to allow each reaction to proceed to completion; any defects caused by incomplete reaction or intramolecular coupling of new surface amines with unreacted methyl ester surface groups could cause "trailing" generations, stunting further growth for certain branches. These impurities are difficult to remove when using the divergent synthetic approach because the molecular weight, physical size, and chemical properties of the defective dendrimers are very similar in nature to the desired product. As generation number increases, it becomes more difficult to produce pure products in a timely fashion due to steric constraints.
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On Pontiacs with the exception 1964 model and all floor shift automatics, the shift indicator reads the same for Roto or the Super HydraMatic (dual coupling) and that is; 'DR' drive left and drive right or fourth range left and drive right 3rd range. Remember Roto HydraMatic is considered by HydraMatic Division as a three speed four range automatic and that is why the shift quadrant is the same between the 4 speed Super HydraMatic and the Four range Roto HydraMatic. The Roto-Hydramatic did not have a conventional fluid coupling or torque converter but had an internal fluid coupling with a torque multiplier (an integral, internal torque converter, as opposed to an external unit). There was no real bell housing; instead, the Roto-Hydramatic had a kind of flange connecting the transmission to the engine.
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For example, hyaluronan helps partition plasma proteins between vascular and extravascular spaces, which affects solubility of macromolecules in the interstitium, changes chemical equilibria, and stabilizes the structure of collagen fibers. :Other functions include matrix interactions with hyaluronan binding proteins such as hyaluronectin, glial hyaluronan binding protein, brain enriched hyaluronan binding protein, collagen VI, TSG-6, and inter-alpha-trypsin inhibitor. Cell surface interactions involving hyaluronan are its well-known coupling with CD44, which may be related to tumor progression, and also with RHAMM (Hyaluronan-mediated motility receptor), which has been implicated in developmental processes, tumor metastasis, and pathological reparative processes. Fibroblasts, mesothelial cells, and certain types of stem cells surround themselves in a pericellular "coat", part of which is constructed from hyaluronan, in order to shield themselves from bacteria, red blood cells, or other matrix molecules.
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Liquid chromatography-mass spectrometry (LC/MS) couples high resolution chromatographic separation with MS detection. As the system adopts the high separation of HPLC, analytes which are in the liquid mobile phase are often ionized by various soft ionization methods including atmospheric pressure chemical ionization (APCI), electrospray ionization (ESI) or matrix-assisted laser desorption/ionization (MALDI), which attains the gas phase ionization required for the coupling with MS. These ionization methods allow the analysis of a wider range of biological molecules, including those with larger masses, thermally unstable or nonvolatile compounds where GC-MS is typically incapable of analyzing. LC-MS provides high selectivity as unresolved peaks can be isolated by selecting a specific mass. Furthermore, better identification is also attained by mass spectra and the user does not have to rely solely on the retention time of analytes.
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With chiral amine nucleophile Generally speaking, when chiral amine is used in Petasis coupling, the stereochemical outcome of Petasis reaction is strongly correlated to the chirality of the amine, and high to excellent diastereoselectivity is observed even without the usage of bulky chiral inducing groups. Chiral benzyl amines, 2-substituted pyrrolidines, and 5-substituted 2-morpholinones have been shown to induce good to excellent diastereomeric excess under different Petasis reaction conditions. diastereoselective PBM coupling with chiral amine With chiral N-acyliminium ions Chiral N-acyliminium ion "starting materials" are generally prepared by in- situ dehydration of cyclic hemiaminal. They also carry a chiral hydroxyl group that is in proximity with the iminium carbon; boronic acids react with such chiral hydroxyl groups to form a chiral and electron-rich boronate species, followed by side-selective and intramolecular boronate vinyl/aryl transfer into the iminium carbon.
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Hildegard of Bingen, born seven years after the death of St. Peter Damian, reported seeing visions and recorded them in Scivias (short for Scito vias Domini, "Know the Ways of the Lord"). In Book II Vision Six, she quotes God as condemning same- sex intercourse, including lesbianism; "a woman who takes up devilish ways and plays a male role in coupling with another woman is most vile in My sight, and so is she who subjects herself to such a one in this evil deed". In the 13th century A.D., the theologian Thomas Aquinas was influential in linking condemnations of homosexuality with the idea of natural law, arguing that "special sins are against nature, as, for instance, those that run counter to the intercourse of male and female natural to animals, and so are peculiarly qualified as unnatural vices."Crompton, Louis, Homosexuality and Civilization, Harvard University, 2003.
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Since a DRFM system is designed to create a false target to a radar system, this technology can be employed to perform hardware in the loop simulation.JJ. Strydom and JE. Cillers, "Advances in the testing and evaluation of airborne radar through realtime simulation of synthetic clutter," 48th Annual AOC International Symposium and Convention, Washington, DC, USA, 13–16 November 2011 JJ. Strydom, E. Pienaar, JE. Cillers and K. Olivier, "Advances in the realtime simulation of synthetic clutter for radar testing and evaluation," 47th Annual AOC International Symposium and Convention, Atlanta, Georgia, USA, 3–7 October 2010 Hardware-in-the-loop simulation is an aid to the development of new radar systems, which allows for testing and evaluation of the radar system earlier in the design cycle. This type of testing reduces the cost of development, for example, expensive initial flight trials for airborne radars can now be moved to the laboratory. The radar can be tested either through direct coupling, or through air coupling with antennas.
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The catalyst is the most important component of ATRP because it determines the equilibrium constant between the active and dormant species. This equilibrium determines the polymerization rate. An equilibrium constant that is too small may inhibit or slow the polymerization while an equilibrium constant that is too large leads to a wide distribution of chain lengths. There are several requirements for the metal catalyst: #There needs to be two accessible oxidation states that are differentiated by one electron #The metal center needs to have reasonable affinity for halogens #The coordination sphere of the metal needs to be expandable when it is oxidized as to accommodate the halogen #The transition metal catalyst should not lead to significant side reactions, such as irreversible coupling with the propagating radicals and catalytic radical termination The most studied catalysts are those that include copper, which has shown the most versatility with successful polymerizations for a wide selection of monomers.
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In 2002 Oberman joined the second and final series of the sketch show Big Train, performing beside comedians Simon Pegg and Catherine Tate. The following year saw the Harringham Harker move from radio to television as part of BBC 2's Autumn line-up alongside The Office and Coupling, with Oberman continuing in her role as lead and writer. She has appeared in many other TV programmes, including; The Way It Is (2000), Bob Martin (2000–2001) opposite Michael Barrymore, Lenny Henry in Pieces (2000–2001), Big Train (2002), SuperTex (2003) and in episodes of Doctors, The Last Detective, Where the Heart Is, The Bill, Casualty. She played the previously unseen character of Marion in a special half-hour episode of the monologue series Marion and Geoff in 2001. In 2004, Oberman moved away from comedy to join the popular BBC soap opera EastEnders, after she was cast as Chrissie Watts, the second wife of "one of the best-loved villains in soap history", "Dirty" Den Watts.
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In the previous process, when the magnetic moments in the hard magnet start to rotate, the intensity of external field is already much higher than the coercivity of the soft phase, but there is still a transition region in soft phase. If the thickness of the soft phase is less than twice as thick as the transition region, the soft phase should have a large effective coercivity, smaller than but comparable to the coercivity of the hard phase. Figure 4: Magnetic moments around thin soft phase In a thin soft phase, it is hard for the external field to rotate the magnetic moments, similar to a hard magnet with high saturation magnetization. After applying a high external field to partially demagnetize the magnetic moments in the hard phase and after subsequently removing the external field, the rotated moments in the soft phase can be rotated back by exchange coupling with the hard phase (Figure 5).
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Okada, F. Oguro, A. Noguchi, Y. Tabuchi, R. Yamazaki, K. Usami, and Y. Nakamura, "Cavity Enhancement of Anti-Stokes Scattering via Optomechanical Coupling with Surface Acoustic Waves", Physical Review Applied 10, 024002 (2018), and an ordered vortex lattice in a Josephson junction array was observed.R. Cosmic, K. Ikegami, Z. Lin, K. Inomata, J. M. Taylor, and Y. Nakamura, "Circuit-QED-based measurement of vortex lattice order in a Josephson junction array", Physical Review B 98, 060501(R) (2018), Nakamura has spoken several times at quantum information science conferences and seminars, including at the University of Vienna, the Institute for Theoretical Atomic Molecular and Optical Physics at Harvard University, the National Center of Competence in Research's Quantum Science and Technology Monte Verità conference, the Institute for Quantum Computing at the University of Waterloo, the Institute for Molecular Engineering at the University of Chicago the Institute for Quantum Optics and Quantum Information (IQOQI), and the Yale Quantum Institute at Yale University.
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The X-Type, codenamed X400,BBC News 6 January 1998 launched in 2001 to compete in the compact executive class dominated by the rear-wheel drive BMW 3 Series and Mercedes C-class despite Ford/Jaguar having no directly competitive platform. Instead, the X-type used a modified version of the front-drive Ford CD132 platform shared with the contemporary Ford Mondeo -- with the addition of all- wheel drive (marketed as Jaguar Traction or Jaguar Traction 4) and handling and steering engineered to minimise front-wheel drive torque-steer. Initially, the X-Type was available only with all wheel drive, using a centre differential and a compact, maintenance-free viscous coupling with a default split of 60 percent torque to the rear wheels, 40 percent to the front wheels. Under loss of traction front or rear, the coupling could vary the front/rear torque split and could fully transfer torque to either front or rear wheels to ensure grip. From 2005-on, X-Types used an electronically controlled transfer cases rather than the centre viscous coupling.
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Hence, the reaction is highly diastereoselective, with cis- boronate aryl/vinyl transfer being the predominant pathway. Hydroxypyrrolidines and Hydroxy-γ- and δ-lactams have been shown to react very diastereoselectively, with good to excellent yield. However, such procedures are limited to the usage of vinyl- or electron-rich aryl- boronic acids only. diastereoselective PBM coupling with chiral N-acyliminium ion Batey and coworkers take advantage of the high diastereoselectivity of this reaction to prepare (±)-6-deoxycastanospermine in 7 steps, with an impressive overall yield of 32% (from the vinyl boronic ester). The key acyclic precursor to deoxycastanospermine (A) is formed first by condensing vinyl boronic ester 1 with Cbz-protected hydroxy-pyrrolidine 2 with a PBM coupling, followed by dihydroxylation and TBS protetction. A then undergo intramolecular cyclization via a one-pot imine formation and reduction sequel, followed by TBS deprotection, to afford (±)-6-deoxycastanospermine. Deoxycastanospermine synthesis (Batey et al.) With thiourea catalyst Takemoto and coworkers of Kyoto University recently reported an enantioselective Petasis-type reaction to transform quinolines into respective chiral 1,2-dihydroquinolines (product) using alkenyl boronic acids and chiral thiourea catalyst. Good yields (59–78%) and excellent enantioselectivities (82–96%) are reported.
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71, No. 2, pp. 209–219, 1999 Link Examples include fullerenes, nanotubes, corannulenes, helicenes and sumanene. The molecular orbitals of the carbon atoms in these systems are to some extent pyramidalized resulting a different pi electron density on either side of the molecule with consequences for reactivity. One member of this group of organic compounds, pentaindenocorannulene (depicted below),Pentaindenocorannulene and Tetraindenocorannulene: New Aromatic Hydrocarbon Systems with Curvatures Surpassing That of C60Edward A. Jackson, Brian D. Steinberg, Mihail Bancu, Atsushi Wakamiya, and Lawrence T. Scott J. Am. Chem. Soc.; 2007; 129(3) pp 484 - 485; (Communication) The two steps in this sequence are a Suzuki-Miyaura coupling with an ionic liquid and Tris(dibenzylideneacetone)dipalladium(0) and a Heck reaction with another palladium catalyst, DBU and DMAC can be considered a large fullerene fragment. The experimentally obtained curvature and degree of pyramidalizion (12.6° for the carbons of the pentagon at the center by a so-called p-orbital axis vector (POAV). The value for fullerene is 11.6° and benzene 0°) are both actually larger than that of fullerene but according to its discoverers, the compound is relatively easy to synthesize starting from corannulene and a way is opened to produce larger such fragments by stitching. Synthesis of Pentaindenocorannulene The crystal structure of pentaindenocorannulene has been obtained.
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