More specifically, they show that the landscape generator performs best with low configurationally structured reference projects and performs less with high configurationally structured reference projects.
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The enantiomers are configurationally unstable in vitro or undergo racemization in vivo.
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Studies are therefore being carried out to increase the configurationally stability of such lithium reagents.
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In most cases, the biaryl axis is configurationally stable and represents an additional element of chirality.
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In the past three decades, three methods have emerged for the study of configurationally random alloys.
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These configurationally constrained molecules have led to the design of a novel class of benzodiazepine VLA-4 antagonists.
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Currently, we are studying thiospiropyran and spirooxazine derivatives which should be configurationally much more stable than the corresponding spiropyrans.
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Depending on the size of their receptive field apertures they measure either localized or more global configurationally spatiotemporal information.
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Iron(III) acetylacetonate, Fe(acac)3, is a red high- spin complex that is highly soluble in organic solvents. It is a configurationally labile, high-spin complex with five unpaired electrons. It is occasionally used as a catalyst precursor. Although configurationally labile, Fe(acac)3 has been partially resolved into its Δ and Λ isomers.
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In addition, because the NPs were considerably small so that configurationally entropic losses of the polymer to incorporate the nanoparticles were also significantly small.
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The two main approaches to synthesis of N-H, N-alkyl, and N-aryloxaziridines are oxidation of imines with peracids (A) and amination of carbonyls (B). General oxaziridine synthesis Additionally, oxidation of chiral imines and oxidation of imines with chiral peracids may yield enantiopure oxaziridines. Some oxaziridines have the unique property of configurationally stable nitrogen atoms at room temperature due to an inversion barrier of 100 to 130 kJ/mol. Enantiopure oxaziridines where stereochemistry is entirely due to configurationally stable nitrogen are reported.
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The A/D-part of the B12 structure incorporates the constitutionally and configurationally most intricate part of the vitamin molecule; its synthesis is regarded as the apotheosis of the Woodwardian art in natural product total synthesis.
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The bound BIM1 inhibitor blocks the ATP-binding site and puts the kinase domain into an intermediate open conformation. The value of such calculations lies in understanding a variant was designed which showed improved binding characteristics of configurationally stable atropisomeric bisindolylmaleimides where the two kinase domains, and two different inhibitor conformers bind in different orientations, the hinge region of staurosporine- Pim-1 resembles co-crystallized as an asymmetric pair of biosynthetically 'related' indolocarbazole analogs.
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Hale stipulates that nominals in non-configurational languages are simply optional, which is a result of the nature of the relationship between phrase structure and lexical structure in non- configurational languages. However Jelinek proposes configurationally parameters that are in agreement with the projection principle, with specific reference to Warlpiri data. It is proposed that the AUX not only marks grammatical relations but it also a constituent containing case marked fully referential clitic pronouns that serve as verbal arguments. Since nominals are never verb arguments they can be omitted, without violating the projection principle.
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